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Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand. / Petrov, Pavel A.; Rogachev, Alexander V.; Sukhikh, Taisiya S. et al.

In: Mendeleev Communications, Vol. 32, No. 5, 01.09.2022, p. 579-581.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Rogachev, AV, Sukhikh, TS, Eltsov, IV, Abramov, PA & Sokolov, MN 2022, 'Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand', Mendeleev Communications, vol. 32, no. 5, pp. 579-581. https://doi.org/10.1016/j.mencom.2022.09.003

APA

Petrov, P. A., Rogachev, A. V., Sukhikh, T. S., Eltsov, I. V., Abramov, P. A., & Sokolov, M. N. (2022). Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand. Mendeleev Communications, 32(5), 579-581. https://doi.org/10.1016/j.mencom.2022.09.003

Vancouver

Petrov PA, Rogachev AV, Sukhikh TS, Eltsov IV, Abramov PA, Sokolov MN. Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand. Mendeleev Communications. 2022 Sept 1;32(5):579-581. doi: 10.1016/j.mencom.2022.09.003

Author

Petrov, Pavel A. ; Rogachev, Alexander V. ; Sukhikh, Taisiya S. et al. / Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand. In: Mendeleev Communications. 2022 ; Vol. 32, No. 5. pp. 579-581.

BibTeX

@article{a50ca06e5c2b45d4bf141e47c733ecca,
title = "Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand",
abstract = "The reaction beetwen tantalum pentakis(3,5-dimethyl-pyrazolate) and CS2 afforded novel complex [Ta(=S)(dmpz)2{(dmpz)3CS}]. In this reaction the molecule of CS2 undergoes scission with the migration of one sulfide to the tantalum atom while three pyrazolate residues migrate to carbon with the formation of unusual (dmpz)3CS– ligand. The structure of the product was established by X-ray diffraction.",
keywords = "amides, carbon disulfide, dithiocarbamates, pyrazolates, sulfides, tantalum complexes",
author = "Petrov, {Pavel A.} and Rogachev, {Alexander V.} and Sukhikh, {Taisiya S.} and Eltsov, {Ilia V.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Funding Information: The research was supported by the Ministry of Science and Higher Education of the Russian Federation (project no. 121031700313-8). Publisher Copyright: {\textcopyright} 2022",
year = "2022",
month = sep,
day = "1",
doi = "10.1016/j.mencom.2022.09.003",
language = "English",
volume = "32",
pages = "579--581",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "5",

}

RIS

TY - JOUR

T1 - Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand

AU - Petrov, Pavel A.

AU - Rogachev, Alexander V.

AU - Sukhikh, Taisiya S.

AU - Eltsov, Ilia V.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Funding Information: The research was supported by the Ministry of Science and Higher Education of the Russian Federation (project no. 121031700313-8). Publisher Copyright: © 2022

PY - 2022/9/1

Y1 - 2022/9/1

N2 - The reaction beetwen tantalum pentakis(3,5-dimethyl-pyrazolate) and CS2 afforded novel complex [Ta(=S)(dmpz)2{(dmpz)3CS}]. In this reaction the molecule of CS2 undergoes scission with the migration of one sulfide to the tantalum atom while three pyrazolate residues migrate to carbon with the formation of unusual (dmpz)3CS– ligand. The structure of the product was established by X-ray diffraction.

AB - The reaction beetwen tantalum pentakis(3,5-dimethyl-pyrazolate) and CS2 afforded novel complex [Ta(=S)(dmpz)2{(dmpz)3CS}]. In this reaction the molecule of CS2 undergoes scission with the migration of one sulfide to the tantalum atom while three pyrazolate residues migrate to carbon with the formation of unusual (dmpz)3CS– ligand. The structure of the product was established by X-ray diffraction.

KW - amides

KW - carbon disulfide

KW - dithiocarbamates

KW - pyrazolates

KW - sulfides

KW - tantalum complexes

UR - http://www.scopus.com/inward/record.url?scp=85139301838&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2022.09.003

DO - 10.1016/j.mencom.2022.09.003

M3 - Article

AN - SCOPUS:85139301838

VL - 32

SP - 579

EP - 581

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 5

ER -

ID: 38158155