Standard

Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals. / Kalinina, Polina P.; Zakharov, Boris A.

In: CrystEngComm, Vol. 36, 2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Kalinina, PP & Zakharov, BA 2024, 'Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals', CrystEngComm, vol. 36. https://doi.org/10.1039/d4ce00734d

APA

Kalinina, P. P., & Zakharov, B. A. (2024). Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals. CrystEngComm, 36. https://doi.org/10.1039/d4ce00734d

Vancouver

Kalinina PP, Zakharov BA. Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals. CrystEngComm. 2024;36. doi: 10.1039/d4ce00734d

Author

Kalinina, Polina P. ; Zakharov, Boris A. / Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals. In: CrystEngComm. 2024 ; Vol. 36.

BibTeX

@article{50600ea2908048c4b4aebbda04887bfa,
title = "Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals",
abstract = " The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure. We report the unusual linkage photoisomerization for [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl. The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ occurs upon irradiation by visible light for complex cations in certain crystallographic positions only. This feature, suggesting “crystallographic control” of reactivity within the same crystal structure, has been analysed via detailed analysis of crystal structures and IR spectra of the reagent and product. ",
author = "Kalinina, {Polina P.} and Zakharov, {Boris A.}",
year = "2024",
doi = "10.1039/d4ce00734d",
language = "English",
volume = "36",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals

AU - Kalinina, Polina P.

AU - Zakharov, Boris A.

PY - 2024

Y1 - 2024

N2 - The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure. We report the unusual linkage photoisomerization for [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl. The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ occurs upon irradiation by visible light for complex cations in certain crystallographic positions only. This feature, suggesting “crystallographic control” of reactivity within the same crystal structure, has been analysed via detailed analysis of crystal structures and IR spectra of the reagent and product.

AB - The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure. We report the unusual linkage photoisomerization for [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl. The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ occurs upon irradiation by visible light for complex cations in certain crystallographic positions only. This feature, suggesting “crystallographic control” of reactivity within the same crystal structure, has been analysed via detailed analysis of crystal structures and IR spectra of the reagent and product.

UR - https://www.mendeley.com/catalogue/f268ce9e-f9db-34f8-9f94-0a7381712d4f/

U2 - 10.1039/d4ce00734d

DO - 10.1039/d4ce00734d

M3 - Article

VL - 36

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

ER -

ID: 60517161