Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals

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Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals. / Kalinina, Polina P.; Zakharov, Boris A.

In: CrystEngComm, Vol. 26, No. 36, 06.09.2024, p. 4958-4963.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{50600ea2908048c4b4aebbda04887bfa,

title = "Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals",

abstract = " The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure. We report the unusual linkage photoisomerization for [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl. The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ occurs upon irradiation by visible light for complex cations in certain crystallographic positions only. This feature, suggesting “crystallographic control” of reactivity within the same crystal structure, has been analysed via detailed analysis of crystal structures and IR spectra of the reagent and product. ",

author = "Kalinina, {Polina P.} and Zakharov, {Boris A.}",

year = "2024",

month = sep,

day = "6",

doi = "10.1039/d4ce00734d",

language = "English",

volume = "26",

pages = "4958--4963",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "36",

}

RIS

TY - JOUR

T1 - Unusual linkage photoisomerization in [Co(NH 3 ) 2 NO 2 ] 2 I 3 Cl single crystals

AU - Kalinina, Polina P.

AU - Zakharov, Boris A.

PY - 2024/9/6

Y1 - 2024/9/6

N2 - The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure. We report the unusual linkage photoisomerization for [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl. The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ occurs upon irradiation by visible light for complex cations in certain crystallographic positions only. This feature, suggesting “crystallographic control” of reactivity within the same crystal structure, has been analysed via detailed analysis of crystal structures and IR spectra of the reagent and product.

AB - The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ proceeds under visible light for cations in certain crystallographic positions only in [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl, that suggests “crystallographic control” of reactivity within the same crystal structure. We report the unusual linkage photoisomerization for [Co(NH 3 ) 5 NO 2 ] 2 I 3 Cl. The reaction [Co(NH 3 ) 5 NO 2 ] 2+ → [Co(NH 3 ) 5 ONO] 2+ occurs upon irradiation by visible light for complex cations in certain crystallographic positions only. This feature, suggesting “crystallographic control” of reactivity within the same crystal structure, has been analysed via detailed analysis of crystal structures and IR spectra of the reagent and product.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85204933568&origin=inward&txGid=55d84e2b0339c1781797c65537aaea07

UR - https://www.mendeley.com/catalogue/f268ce9e-f9db-34f8-9f94-0a7381712d4f/

U2 - 10.1039/d4ce00734d

DO - 10.1039/d4ce00734d

M3 - Article

VL - 26

SP - 4958

EP - 4963

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 36

ER -

ID: 60517161