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Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems. / Khokhryakov, Alexander F.; Nechaev, Denis V.; Palyanov, Yuri N.

In: Journal of Crystal Growth, Vol. 455, 01.12.2016, p. 76-82.

Research output: Contribution to journal › Article › peer-review

Harvard

Khokhryakov, AF, Nechaev, DV & Palyanov, YN 2016, 'Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems', Journal of Crystal Growth, vol. 455, pp. 76-82. https://doi.org/10.1016/j.jcrysgro.2016.10.004

APA

Khokhryakov, A. F., Nechaev, D. V., & Palyanov, Y. N. (2016). Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems. Journal of Crystal Growth, 455, 76-82. https://doi.org/10.1016/j.jcrysgro.2016.10.004

Vancouver

Khokhryakov AF, Nechaev DV, Palyanov YN. Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems. Journal of Crystal Growth. 2016 Dec 1;455:76-82. doi: 10.1016/j.jcrysgro.2016.10.004

Author

Khokhryakov, Alexander F. ; Nechaev, Denis V. ; Palyanov, Yuri N. / Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems. In: Journal of Crystal Growth. 2016 ; Vol. 455. pp. 76-82.

BibTeX

@article{209fd62f1b5142f7bcf79cb32f55a769,
title = "Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems",
abstract = "We studied unusual growth macrolayers on the {100} faces of diamond crystals grown in Mg-C and Mg0.9Ge0.1-C systems at 7.0 GPa and in the temperature range of 1800–1900 °C. The layers were shaped as rectangles highly elongated in one of the [110] directions. The layer elongation (length to width ratio) was different, but did not exceed 23. We found that the ends of the macrolayers in most cases were composed of {111} microfacets, and their growth occurred by layers along these microfacets. Using selective etching, we found that the macrolayers were not associated with outcrops of dislocations and any planar defects on the {100} faces. It is supposed that the formation of these highly elongated layers occurs by two-dimensional nucleation that becomes possible at high carbon supersaturation under conditions of kinetically limited diamond growth in Mg-based systems.",
keywords = "A1.Crystal morphology, A1.Etching, A2.Single crystal growth, B1.Diamond",
author = "Khokhryakov, {Alexander F.} and Nechaev, {Denis V.} and Palyanov, {Yuri N.}",
year = "2016",
month = dec,
day = "1",
doi = "10.1016/j.jcrysgro.2016.10.004",
language = "English",
volume = "455",
pages = "76--82",
journal = "Journal of Crystal Growth",
issn = "0022-0248",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Unusual growth macrolayers on {100} faces of diamond crystals from magnesium-based systems

AU - Khokhryakov, Alexander F.

AU - Nechaev, Denis V.

AU - Palyanov, Yuri N.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - We studied unusual growth macrolayers on the {100} faces of diamond crystals grown in Mg-C and Mg0.9Ge0.1-C systems at 7.0 GPa and in the temperature range of 1800–1900 °C. The layers were shaped as rectangles highly elongated in one of the [110] directions. The layer elongation (length to width ratio) was different, but did not exceed 23. We found that the ends of the macrolayers in most cases were composed of {111} microfacets, and their growth occurred by layers along these microfacets. Using selective etching, we found that the macrolayers were not associated with outcrops of dislocations and any planar defects on the {100} faces. It is supposed that the formation of these highly elongated layers occurs by two-dimensional nucleation that becomes possible at high carbon supersaturation under conditions of kinetically limited diamond growth in Mg-based systems.

AB - We studied unusual growth macrolayers on the {100} faces of diamond crystals grown in Mg-C and Mg0.9Ge0.1-C systems at 7.0 GPa and in the temperature range of 1800–1900 °C. The layers were shaped as rectangles highly elongated in one of the [110] directions. The layer elongation (length to width ratio) was different, but did not exceed 23. We found that the ends of the macrolayers in most cases were composed of {111} microfacets, and their growth occurred by layers along these microfacets. Using selective etching, we found that the macrolayers were not associated with outcrops of dislocations and any planar defects on the {100} faces. It is supposed that the formation of these highly elongated layers occurs by two-dimensional nucleation that becomes possible at high carbon supersaturation under conditions of kinetically limited diamond growth in Mg-based systems.

KW - A1.Crystal morphology

KW - A1.Etching

KW - A2.Single crystal growth

KW - B1.Diamond

UR - http://www.scopus.com/inward/record.url?scp=84990063312&partnerID=8YFLogxK

U2 - 10.1016/j.jcrysgro.2016.10.004

DO - 10.1016/j.jcrysgro.2016.10.004

M3 - Article

AN - SCOPUS:84990063312

VL - 455

SP - 76

EP - 82

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

SN - 0022-0248

ER -

ID: 25724230