Standard

Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP) : A method for preparation of functional surfaces. / Guselnikova, Olga; Marque, Sylvain R.A.; Tretyakov, Evgeny V. et al.

In: Journal of Materials Chemistry A, Vol. 7, No. 20, 28.05.2019, p. 12414-12419.

Research output: Contribution to journal › Article › peer-review

Harvard

Guselnikova, O, Marque, SRA, Tretyakov, EV, Mares, D, Jerabek, V, Audran, G, Joly, JP, Trusova, M, Svorcik, V, Lyutakov, O & Postnikov, P 2019, 'Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): A method for preparation of functional surfaces', Journal of Materials Chemistry A, vol. 7, no. 20, pp. 12414-12419. https://doi.org/10.1039/c9ta01630a

APA

Guselnikova, O., Marque, S. R. A., Tretyakov, E. V., Mares, D., Jerabek, V., Audran, G., Joly, J. P., Trusova, M., Svorcik, V., Lyutakov, O., & Postnikov, P. (2019). Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): A method for preparation of functional surfaces. Journal of Materials Chemistry A, 7(20), 12414-12419. https://doi.org/10.1039/c9ta01630a

Vancouver

Guselnikova O, Marque SRA, Tretyakov EV, Mares D, Jerabek V, Audran G et al. Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): A method for preparation of functional surfaces. Journal of Materials Chemistry A. 2019 May 28;7(20):12414-12419. doi: 10.1039/c9ta01630a

Author

Guselnikova, Olga ; Marque, Sylvain R.A. ; Tretyakov, Evgeny V. et al. / Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP) : A method for preparation of functional surfaces. In: Journal of Materials Chemistry A. 2019 ; Vol. 7, No. 20. pp. 12414-12419.

BibTeX

@article{ac86808924fb44558f402753c7ab86d3,
title = "Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): A method for preparation of functional surfaces",
abstract = "A plasmon as a stimulus opens up new opportunities for selective and regulated {"}from-surface{"} polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4-vinylboronic acid is reported. The growth of a polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of the resulting polymer thickness but also the preparation of a surface-enhanced Raman spectroscopy chip for the detection of glycoproteins as a powerful example of plasmon-assisted NMP potential.",
keywords = "ON BOND HOMOLYSIS, SERS PLATFORM, ALKOXYAMINES, AU, NANOPARTICLES, VERSATILE",
author = "Olga Guselnikova and Marque, {Sylvain R.A.} and Tretyakov, {Evgeny V.} and David Mares and Vitezslav Jerabek and G{\'e}rard Audran and Joly, {Jean Patrick} and Marina Trusova and Vaclav Svorcik and Oleksiy Lyutakov and Pavel Postnikov",
year = "2019",
month = may,
day = "28",
doi = "10.1039/c9ta01630a",
language = "English",
volume = "7",
pages = "12414--12419",
journal = "Journal of Materials Chemistry A",
issn = "2050-7488",
publisher = "Royal Society of Chemistry",
number = "20",

}

RIS

TY - JOUR

T1 - Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP)

T2 - A method for preparation of functional surfaces

AU - Guselnikova, Olga

AU - Marque, Sylvain R.A.

AU - Tretyakov, Evgeny V.

AU - Mares, David

AU - Jerabek, Vitezslav

AU - Audran, Gérard

AU - Joly, Jean Patrick

AU - Trusova, Marina

AU - Svorcik, Vaclav

AU - Lyutakov, Oleksiy

AU - Postnikov, Pavel

PY - 2019/5/28

Y1 - 2019/5/28

N2 - A plasmon as a stimulus opens up new opportunities for selective and regulated "from-surface" polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4-vinylboronic acid is reported. The growth of a polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of the resulting polymer thickness but also the preparation of a surface-enhanced Raman spectroscopy chip for the detection of glycoproteins as a powerful example of plasmon-assisted NMP potential.

AB - A plasmon as a stimulus opens up new opportunities for selective and regulated "from-surface" polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4-vinylboronic acid is reported. The growth of a polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of the resulting polymer thickness but also the preparation of a surface-enhanced Raman spectroscopy chip for the detection of glycoproteins as a powerful example of plasmon-assisted NMP potential.

KW - ON BOND HOMOLYSIS

KW - SERS PLATFORM

KW - ALKOXYAMINES

KW - AU

KW - NANOPARTICLES

KW - VERSATILE

UR - http://www.scopus.com/inward/record.url?scp=85065961412&partnerID=8YFLogxK

U2 - 10.1039/c9ta01630a

DO - 10.1039/c9ta01630a

M3 - Article

AN - SCOPUS:85065961412

VL - 7

SP - 12414

EP - 12419

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

SN - 2050-7488

IS - 20

ER -

ID: 20163463