Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina

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Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina. / Sivcev, V. P.; Volcho, K. P.; Salakhutdinov, N. F. et al.

In: Journal of Supercritical Fluids, Vol. 103, 28.07.2015.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{e808ca37bdbe4409a41c344cbc214966,

title = "Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina",

abstract = "Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine.",

keywords = "Aliphatic amine, Alumina, Hydrogen transfer, Nitro group, Reduction, Supercritical isopropanol",

author = "Sivcev, {V. P.} and Volcho, {K. P.} and Salakhutdinov, {N. F.} and Anikeev, {V. I.}",

year = "2015",

month = jul,

day = "28",

doi = "10.1016/j.supflu.2015.04.029",

language = "English",

volume = "103",

journal = "Journal of Supercritical Fluids",

issn = "0896-8446",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina

AU - Sivcev, V. P.

AU - Volcho, K. P.

AU - Salakhutdinov, N. F.

AU - Anikeev, V. I.

PY - 2015/7/28

Y1 - 2015/7/28

N2 - Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine.

AB - Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine.

KW - Aliphatic amine

KW - Alumina

KW - Hydrogen transfer

KW - Nitro group

KW - Reduction

KW - Supercritical isopropanol

UR - http://www.scopus.com/inward/record.url?scp=84929629404&partnerID=8YFLogxK

U2 - 10.1016/j.supflu.2015.04.029

DO - 10.1016/j.supflu.2015.04.029

M3 - Article

AN - SCOPUS:84929629404

VL - 103

JO - Journal of Supercritical Fluids

JF - Journal of Supercritical Fluids

SN - 0896-8446

ER -

ID: 9560876