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Unexpected structures of the Au17 gold cluster: the stars are shining. / Nhat, Pham Vu; Si, Nguyen Thanh; Kiselev, Vitaly G. et al.

In: Chemical Communications, Vol. 58, No. 38, 10.05.2022, p. 5785-5788.

Research output: Contribution to journal › Article › peer-review

Harvard

Nhat, PV, Si, NT, Kiselev, VG, Fielicke, A, Pham, HT & Nguyen, MT 2022, 'Unexpected structures of the Au17 gold cluster: the stars are shining', Chemical Communications, vol. 58, no. 38, pp. 5785-5788. https://doi.org/10.1039/d2cc00891b

APA

Nhat, P. V., Si, N. T., Kiselev, V. G., Fielicke, A., Pham, H. T., & Nguyen, M. T. (2022). Unexpected structures of the Au17 gold cluster: the stars are shining. Chemical Communications, 58(38), 5785-5788. https://doi.org/10.1039/d2cc00891b

Vancouver

Nhat PV, Si NT, Kiselev VG, Fielicke A, Pham HT, Nguyen MT. Unexpected structures of the Au17 gold cluster: the stars are shining. Chemical Communications. 2022 May 10;58(38):5785-5788. Epub 2022 Apr 4. doi: 10.1039/d2cc00891b

Author

Nhat, Pham Vu ; Si, Nguyen Thanh ; Kiselev, Vitaly G. et al. / Unexpected structures of the Au17 gold cluster: the stars are shining. In: Chemical Communications. 2022 ; Vol. 58, No. 38. pp. 5785-5788.

BibTeX

@article{b4e1279ad0a9494095cd4ba5fe0711b8,
title = "Unexpected structures of the Au17 gold cluster: the stars are shining",
abstract = "The Au17 gold cluster was experimentally produced in the gas phase and characterized by its vibrational spectrum recorded using far-IR multiple photon dissociation (FIR-MPD) of Au17Kr. DFT and coupled-cluster theory PNO-LCCSD(T)-F12 computations reveal that, at odds with most previous reports, Au17 prefers two star-like forms derived from a pentaprism added by two extra Au atoms on both top and bottom surfaces of the pentaprism, along with five other Au atoms each attached on a lateral face. A good agreement between calculated and FIR-MPD spectra indicates a predominant presence of these star-like isomers. Stabilization of a star form arises from strong orbital interactions of an Au12 core with a five-Au-atom string.",
author = "Nhat, {Pham Vu} and Si, {Nguyen Thanh} and Kiselev, {Vitaly G.} and Andr{\'e} Fielicke and Pham, {Hung Tan} and Nguyen, {Minh Tho}",
note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",
year = "2022",
month = may,
day = "10",
doi = "10.1039/d2cc00891b",
language = "English",
volume = "58",
pages = "5785--5788",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - Unexpected structures of the Au17 gold cluster: the stars are shining

AU - Nhat, Pham Vu

AU - Si, Nguyen Thanh

AU - Kiselev, Vitaly G.

AU - Fielicke, André

AU - Pham, Hung Tan

AU - Nguyen, Minh Tho

N1 - Publisher Copyright: © 2022 The Royal Society of Chemistry

PY - 2022/5/10

Y1 - 2022/5/10

N2 - The Au17 gold cluster was experimentally produced in the gas phase and characterized by its vibrational spectrum recorded using far-IR multiple photon dissociation (FIR-MPD) of Au17Kr. DFT and coupled-cluster theory PNO-LCCSD(T)-F12 computations reveal that, at odds with most previous reports, Au17 prefers two star-like forms derived from a pentaprism added by two extra Au atoms on both top and bottom surfaces of the pentaprism, along with five other Au atoms each attached on a lateral face. A good agreement between calculated and FIR-MPD spectra indicates a predominant presence of these star-like isomers. Stabilization of a star form arises from strong orbital interactions of an Au12 core with a five-Au-atom string.

AB - The Au17 gold cluster was experimentally produced in the gas phase and characterized by its vibrational spectrum recorded using far-IR multiple photon dissociation (FIR-MPD) of Au17Kr. DFT and coupled-cluster theory PNO-LCCSD(T)-F12 computations reveal that, at odds with most previous reports, Au17 prefers two star-like forms derived from a pentaprism added by two extra Au atoms on both top and bottom surfaces of the pentaprism, along with five other Au atoms each attached on a lateral face. A good agreement between calculated and FIR-MPD spectra indicates a predominant presence of these star-like isomers. Stabilization of a star form arises from strong orbital interactions of an Au12 core with a five-Au-atom string.

UR - http://www.scopus.com/inward/record.url?scp=85129849384&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/2ff0b18e-d811-30c1-bbff-4d028582b4f7/

U2 - 10.1039/d2cc00891b

DO - 10.1039/d2cc00891b

M3 - Article

C2 - 35451431

AN - SCOPUS:85129849384

VL - 58

SP - 5785

EP - 5788

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 38

ER -

ID: 36108146