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Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]. / Glebov, E. M.; Grivin, V. P.; Vasil’chenko, D. B. et al.

In: High Energy Chemistry, Vol. 51, No. 6, 01.11.2017, p. 409-414.

Research output: Contribution to journal › Article › peer-review

Harvard

Glebov, EM, Grivin, VP, Vasil’chenko, DB, Zadesenets, AV & Plyusnin, VF 2017, 'Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]', High Energy Chemistry, vol. 51, no. 6, pp. 409-414. https://doi.org/10.1134/S0018143917060078

APA

Glebov, E. M., Grivin, V. P., Vasil’chenko, D. B., Zadesenets, A. V., & Plyusnin, V. F. (2017). Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]. High Energy Chemistry, 51(6), 409-414. https://doi.org/10.1134/S0018143917060078

Vancouver

Glebov EM, Grivin VP, Vasil’chenko DB, Zadesenets AV, Plyusnin VF. Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]. High Energy Chemistry. 2017 Nov 1;51(6):409-414. doi: 10.1134/S0018143917060078

Author

Glebov, E. M. ; Grivin, V. P. ; Vasil’chenko, D. B. et al. / Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]. In: High Energy Chemistry. 2017 ; Vol. 51, No. 6. pp. 409-414.

BibTeX

@article{a58673d345cc44a9869b7fb2e31a83e3,
title = "Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]",
abstract = "The two-quantum photochemistry of aqueous solutions of cis,trans-[PtIV(en)(I)2(CH3COO)2] (complex 1) has been studied by laser flash photolysis using an irradiation wavelength of 355 nm. This compound can be considered as a model representative of the mixed-ligand Pt(IV) complexes tested for use in photodynamic therapy. The appearance of transient absorption, presumably due to two consecutively produced Pt(III) complexes, has been revealed. The spectral and kinetic characteristics of the intermediates have been determined. A mechanism of two-quantum photolysis of complex 1 is proposed on the basis of the data obtained.",
keywords = "laser pulsed photolysis, photodynamic therapy, Pt(IV) complexes, two-quantum processes",
author = "Glebov, {E. M.} and Grivin, {V. P.} and Vasil{\textquoteright}chenko, {D. B.} and Zadesenets, {A. V.} and Plyusnin, {V. F.}",
note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",
year = "2017",
month = nov,
day = "1",
doi = "10.1134/S0018143917060078",
language = "English",
volume = "51",
pages = "409--414",
journal = "High Energy Chemistry",
issn = "0018-1439",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "6",

}

RIS

TY - JOUR

T1 - Two-quantum photochemistry of the complex cis,trans-[PtIV(en)(I)2(CH3COO)2]

AU - Glebov, E. M.

AU - Grivin, V. P.

AU - Vasil’chenko, D. B.

AU - Zadesenets, A. V.

AU - Plyusnin, V. F.

N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The two-quantum photochemistry of aqueous solutions of cis,trans-[PtIV(en)(I)2(CH3COO)2] (complex 1) has been studied by laser flash photolysis using an irradiation wavelength of 355 nm. This compound can be considered as a model representative of the mixed-ligand Pt(IV) complexes tested for use in photodynamic therapy. The appearance of transient absorption, presumably due to two consecutively produced Pt(III) complexes, has been revealed. The spectral and kinetic characteristics of the intermediates have been determined. A mechanism of two-quantum photolysis of complex 1 is proposed on the basis of the data obtained.

AB - The two-quantum photochemistry of aqueous solutions of cis,trans-[PtIV(en)(I)2(CH3COO)2] (complex 1) has been studied by laser flash photolysis using an irradiation wavelength of 355 nm. This compound can be considered as a model representative of the mixed-ligand Pt(IV) complexes tested for use in photodynamic therapy. The appearance of transient absorption, presumably due to two consecutively produced Pt(III) complexes, has been revealed. The spectral and kinetic characteristics of the intermediates have been determined. A mechanism of two-quantum photolysis of complex 1 is proposed on the basis of the data obtained.

KW - laser pulsed photolysis

KW - photodynamic therapy

KW - Pt(IV) complexes

KW - two-quantum processes

UR - http://www.scopus.com/inward/record.url?scp=85036653157&partnerID=8YFLogxK

U2 - 10.1134/S0018143917060078

DO - 10.1134/S0018143917060078

M3 - Article

AN - SCOPUS:85036653157

VL - 51

SP - 409

EP - 414

JO - High Energy Chemistry

JF - High Energy Chemistry

SN - 0018-1439

IS - 6

ER -

ID: 9022399