Tundsten peroxopolyoxo complex– promising caralysts for oxidation of organic compounds. II. Structure of the [(n-Oct)3NME]3{PO4[WO(O2)2]4} complex from the small angle X-ray scattering data

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Tundsten peroxopolyoxo complex– promising caralysts for oxidation of organic compounds. II. Structure of the [(n-Oct)₃NME]₃{PO₄[WO(O₂)₂]₄} complex from the small angle X-ray scattering data. / Larichev, Yu V.; Selivanova, N. V.; Berdnikova, P. V. et al.

In: Journal of Structural Chemistry, Vol. 63, No. 8, 08.2022, p. 1215-1223.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{02417b1e3dc046c1aa22443b047db0e8,

title = "Tundsten peroxopolyoxo complex– promising caralysts for oxidation of organic compounds. II. Structure of the [(n-Oct)3NME]3{PO4[WO(O2)2]4} complex from the small angle X-ray scattering data",

abstract = "By small angle X-ray scattering (SAXS) solutions of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} peroxopolyoxo complex are studied using 13 different organic solvents. In solutions of heptane, cyclohexane, and diethyl ether, the peroxo complex is shown to form large aggregates. In a number of other solvents tested, the complex is present as individual molecules in the solution. The size of the molecules is 14.5±1.2 {\AA}. Structural parameters of the complex are found, and a low resolution model of the structure is proposed.",

keywords = "peroxopolyoxo tungstenate complexes, quaternary ammonium cations, small angle X-ray scattering",

author = "Larichev, {Yu V.} and Selivanova, {N. V.} and Berdnikova, {P. V.} and Pai, {Z. P.}",

note = "Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = aug,

doi = "10.1134/S0022476622080029",

language = "English",

volume = "63",

pages = "1215--1223",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "8",

}

RIS

TY - JOUR

T1 - Tundsten peroxopolyoxo complex– promising caralysts for oxidation of organic compounds. II. Structure of the [(n-Oct)3NME]3{PO4[WO(O2)2]4} complex from the small angle X-ray scattering data

AU - Larichev, Yu V.

AU - Selivanova, N. V.

AU - Berdnikova, P. V.

AU - Pai, Z. P.

PY - 2022/8

Y1 - 2022/8

N2 - By small angle X-ray scattering (SAXS) solutions of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} peroxopolyoxo complex are studied using 13 different organic solvents. In solutions of heptane, cyclohexane, and diethyl ether, the peroxo complex is shown to form large aggregates. In a number of other solvents tested, the complex is present as individual molecules in the solution. The size of the molecules is 14.5±1.2 Å. Structural parameters of the complex are found, and a low resolution model of the structure is proposed.

AB - By small angle X-ray scattering (SAXS) solutions of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} peroxopolyoxo complex are studied using 13 different organic solvents. In solutions of heptane, cyclohexane, and diethyl ether, the peroxo complex is shown to form large aggregates. In a number of other solvents tested, the complex is present as individual molecules in the solution. The size of the molecules is 14.5±1.2 Å. Structural parameters of the complex are found, and a low resolution model of the structure is proposed.

KW - peroxopolyoxo tungstenate complexes

KW - quaternary ammonium cations

KW - small angle X-ray scattering

UR - http://www.scopus.com/inward/record.url?scp=85137530417&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/360152ab-4d1a-3e97-a119-5f15b444ef10/

U2 - 10.1134/S0022476622080029

DO - 10.1134/S0022476622080029

M3 - Article

AN - SCOPUS:85137530417

VL - 63

SP - 1215

EP - 1223

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 8

ER -

ID: 37140602