Research output: Contribution to journal › Article › peer-review
Tris(2,6-dimethoxyphenyl)bismuth dibenzoate: synthesis, structure, and properties. / Egorova, I. V.; Grinishak, I. P.; Plankina, E. S. et al.
In: Russian Chemical Bulletin, Vol. 74, No. 11, 11.2025, p. 3429-3435.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Tris(2,6-dimethoxyphenyl)bismuth dibenzoate: synthesis, structure, and properties
AU - Egorova, I. V.
AU - Grinishak, I. P.
AU - Plankina, E. S.
AU - Zhidkov, V. V.
AU - Rodionova, N. A.
AU - Kuratieva, N. V.
AU - Pervukhina, N. V.
AU - Eltsov, I. V.
N1 - Egorova, I.V., Grinishak, I.P., Plankina, E.S. et al. Tris(2,6-dimethoxyphenyl)bismuth dibenzoate: synthesis, structure, and properties. Russ Chem Bull 74, 3429–3435 (2025). https://doi.org/10.1007/s11172-025-4817-x The study was performed within the framework of scientific research of the Blagoveshchensk State Pedagogical University (topic “Synthesis, structure, and properties of antimony and bismuth compounds containing potential coordination sites in organic substituents”) and was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 125021302132-4).
PY - 2025/11
Y1 - 2025/11
N2 - The reaction of tris(2,6-dimethoxyphenyl)bismuth with benzoyl peroxide in benzene affords tris(2,6-dimethoxyphenyl)bismuth dibenzoate Ar3Bi[OC(O)Ph]2, where Ar = 2,6-(MeO)2C6H3, which further reacts with AgNO3 and AgClO4 in chloroform to give Ar3Bi(NO3)2 and Ar3Bi(ClO4)2, respectively. The reduction of Ar3Bi[OC(O)Ph]2 with magnesium produces tris(2,6-dimethoxyphenyl)bismuth. The compounds were characterized by X-ray diffraction analysis, NMR and IR spectroscopy. The bismuth atoms in Ar3Bi[OC(O)Ph]2 (1) and Ar3Bi (3) have a distorted trigonal-bipyramidal coordination (C—Bi—C angles, 117.07(14)—125.49(14)°) and a trigonal-pyramidal coordination (C—Bi—C angles, 95.97(10)—100.90(12)°), respectively. The methoxy oxygen atoms are involved in non-covalent CMe—O⋯Bi interactions with the bismuth atoms (2.962(3)—3.290(3) Å (1), 2.994(2)—3.402(3) Å (3)).
AB - The reaction of tris(2,6-dimethoxyphenyl)bismuth with benzoyl peroxide in benzene affords tris(2,6-dimethoxyphenyl)bismuth dibenzoate Ar3Bi[OC(O)Ph]2, where Ar = 2,6-(MeO)2C6H3, which further reacts with AgNO3 and AgClO4 in chloroform to give Ar3Bi(NO3)2 and Ar3Bi(ClO4)2, respectively. The reduction of Ar3Bi[OC(O)Ph]2 with magnesium produces tris(2,6-dimethoxyphenyl)bismuth. The compounds were characterized by X-ray diffraction analysis, NMR and IR spectroscopy. The bismuth atoms in Ar3Bi[OC(O)Ph]2 (1) and Ar3Bi (3) have a distorted trigonal-bipyramidal coordination (C—Bi—C angles, 117.07(14)—125.49(14)°) and a trigonal-pyramidal coordination (C—Bi—C angles, 95.97(10)—100.90(12)°), respectively. The methoxy oxygen atoms are involved in non-covalent CMe—O⋯Bi interactions with the bismuth atoms (2.962(3)—3.290(3) Å (1), 2.994(2)—3.402(3) Å (3)).
KW - ТРИАРИЛВИСМУТ
KW - БЕНЗОИЛПЕРОКСИД
KW - НИТРАТ СЕРЕБРА
KW - ПЕРХЛОРАТ СЕРЕБРА
KW - МАГНИЙ
KW - РЕНТГЕНОСТРУКТУРНЫЙ АНАЛИЗ
KW - ЯМР
KW - ИК-СПЕКТРОСКОПИЯ
KW - TRIARYLBISMUTH
KW - BENZOYL PEROXIDE
KW - SILVER NITRATE
KW - SILVER PERCHLORATE
KW - MAGNESIUM
KW - X-RAY DIFFRACTION ANALYSIS
KW - NMR
KW - IR SPECTROSCOPY
UR - https://www.scopus.com/pages/publications/105027870218
UR - https://www.elibrary.ru/item.asp?id=87526119
UR - https://www.mendeley.com/catalogue/1347f735-eaa9-3653-a444-5e752bdd79c3/
U2 - 10.1007/s11172-025-4817-x
DO - 10.1007/s11172-025-4817-x
M3 - Article
VL - 74
SP - 3429
EP - 3435
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 11
ER -
ID: 74354353