Research output: Contribution to journal › Article › peer-review
Trigonal Planar Au@Ag3 Clusters Showing Exceptionally Fast and Efficient Phosphorescence in Violet to Deep-Blue Region. / Artem'ev, Alexander V.; Baranov, Andrey Yu; Berezin, Alexey S. et al.
In: Chemistry - A European Journal, Vol. 28, No. 60, e202201563, 26.10.2022.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Trigonal Planar Au@Ag3 Clusters Showing Exceptionally Fast and Efficient Phosphorescence in Violet to Deep-Blue Region
AU - Artem'ev, Alexander V.
AU - Baranov, Andrey Yu
AU - Berezin, Alexey S.
AU - Lapteva, Ulyana A.
AU - Samsonenko, Denis G.
AU - Bagryanskaya, Irina Yu
N1 - Funding Information: This work was supported by Russian Science Foundation (Project N 21‐73‐10110) and the Ministry of Science and Higher Education of the Russian Federation (Projects N 121031700321‐3, N 121031700313‐8 and 1021051503141‐0‐1.4.1). We thank also Dr. Doronina E.P. (A.E. Favorsky Irkutsk Institute of Chemistry, Irkutsk) for running DFT computations, and Dr. Dmitriy Sheven for recording ESI‐MS spectra. o o o Publisher Copyright: © 2022 Wiley-VCH GmbH.
PY - 2022/10/26
Y1 - 2022/10/26
N2 - We report here a series of original ligand-supported trigonal planar Au@Ag3 clusters exhibiting bright solid-state phosphorescence in violet to deep-blue range (λmax=410–442 nm) with remarkably short decay times (0.36–1.36 μs) and up to 96 % emission quantum yield at 298 K.
AB - We report here a series of original ligand-supported trigonal planar Au@Ag3 clusters exhibiting bright solid-state phosphorescence in violet to deep-blue range (λmax=410–442 nm) with remarkably short decay times (0.36–1.36 μs) and up to 96 % emission quantum yield at 298 K.
KW - clusters
KW - metal-metal interactions
KW - phosphine ligands
KW - phosphorescence
KW - photophysics
UR - http://www.scopus.com/inward/record.url?scp=85137199607&partnerID=8YFLogxK
U2 - 10.1002/chem.202201563
DO - 10.1002/chem.202201563
M3 - Article
C2 - 35917219
AN - SCOPUS:85137199607
VL - 28
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 60
M1 - e202201563
ER -
ID: 39139273