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Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate. / Petrov, Pavel A.

In: Journal of Cluster Science, Vol. 28, No. 4, 01.07.2017, p. 1815-1823.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA 2017, 'Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate', Journal of Cluster Science, vol. 28, no. 4, pp. 1815-1823. https://doi.org/10.1007/s10876-017-1202-4

APA

Petrov, P. A. (2017). Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate. Journal of Cluster Science, 28(4), 1815-1823. https://doi.org/10.1007/s10876-017-1202-4

Vancouver

Petrov PA. Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate. Journal of Cluster Science. 2017 Jul 1;28(4):1815-1823. doi: 10.1007/s10876-017-1202-4

Author

Petrov, Pavel A. / Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate. In: Journal of Cluster Science. 2017 ; Vol. 28, No. 4. pp. 1815-1823.

BibTeX

@article{ff097592f6004edf904083e7dd699a75,
title = "Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate",
abstract = "New triangular cluster (Ph4P)2[Mo3S7(TBC)3] (2) (TBC—tetrabromocatecholate) was synthesized by the straightforward reaction of (nBu4N)2[Mo3S7Br6] (1) with tetrabromocatechol in the presence of Et3N, followed by the addition of Ph4PBr. Interaction of 2 with PPh3 leads to the conversion of the bridging disulphide ligands to the bridging sulphides, and (Ph4P)2[Mo3S4(TBC)3(thf)2]·0.5Et2O (3·0.5Et2O) was crystallized out of a THF/Et2O mixture. The main structural feature of 3 is unsymmetrical environment of the Mo3 core derived from the coordination of only two THF molecules per three metals.",
keywords = "Molybdenum, Redox-active ligands, Sulphur, CATECHOLATE, TRANSITION-METAL-COMPLEXES, COMPONENT MOLECULAR CONDUCTORS, REVERSIBLE BINDING, ALLYL HALIDES, MO3S7 CLUSTERS, LIGANDS, BIS-O-AMIDOPHENOLATE, TRINUCLEAR, BOND",
author = "Petrov, {Pavel A.}",
year = "2017",
month = jul,
day = "1",
doi = "10.1007/s10876-017-1202-4",
language = "English",
volume = "28",
pages = "1815--1823",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "4",

}

RIS

TY - JOUR

T1 - Triangular Clusters of Molybdenum Coordinated with Tetrabromocatecholate

AU - Petrov, Pavel A.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - New triangular cluster (Ph4P)2[Mo3S7(TBC)3] (2) (TBC—tetrabromocatecholate) was synthesized by the straightforward reaction of (nBu4N)2[Mo3S7Br6] (1) with tetrabromocatechol in the presence of Et3N, followed by the addition of Ph4PBr. Interaction of 2 with PPh3 leads to the conversion of the bridging disulphide ligands to the bridging sulphides, and (Ph4P)2[Mo3S4(TBC)3(thf)2]·0.5Et2O (3·0.5Et2O) was crystallized out of a THF/Et2O mixture. The main structural feature of 3 is unsymmetrical environment of the Mo3 core derived from the coordination of only two THF molecules per three metals.

AB - New triangular cluster (Ph4P)2[Mo3S7(TBC)3] (2) (TBC—tetrabromocatecholate) was synthesized by the straightforward reaction of (nBu4N)2[Mo3S7Br6] (1) with tetrabromocatechol in the presence of Et3N, followed by the addition of Ph4PBr. Interaction of 2 with PPh3 leads to the conversion of the bridging disulphide ligands to the bridging sulphides, and (Ph4P)2[Mo3S4(TBC)3(thf)2]·0.5Et2O (3·0.5Et2O) was crystallized out of a THF/Et2O mixture. The main structural feature of 3 is unsymmetrical environment of the Mo3 core derived from the coordination of only two THF molecules per three metals.

KW - Molybdenum

KW - Redox-active ligands

KW - Sulphur

KW - CATECHOLATE

KW - TRANSITION-METAL-COMPLEXES

KW - COMPONENT MOLECULAR CONDUCTORS

KW - REVERSIBLE BINDING

KW - ALLYL HALIDES

KW - MO3S7 CLUSTERS

KW - LIGANDS

KW - BIS-O-AMIDOPHENOLATE

KW - TRINUCLEAR

KW - BOND

UR - http://www.scopus.com/inward/record.url?scp=85016131327&partnerID=8YFLogxK

U2 - 10.1007/s10876-017-1202-4

DO - 10.1007/s10876-017-1202-4

M3 - Article

AN - SCOPUS:85016131327

VL - 28

SP - 1815

EP - 1823

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 4

ER -

ID: 10265835