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Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes : Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl. / Vorobyev, Vasily; Emelyanov, Vyacheslav A.; Plusnina, Olga A. et al.

In: European Journal of Inorganic Chemistry, Vol. 2017, No. 5, 03.02.2017, p. 971-978.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorobyev, V, Emelyanov, VA, Plusnina, OA, Makarov, EM, Baidina, IA, Smolentsev, AI, Tkachev, SV & Asanova, TI 2017, 'Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes: Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl', European Journal of Inorganic Chemistry, vol. 2017, no. 5, pp. 971-978. https://doi.org/10.1002/ejic.201601233

APA

Vorobyev, V., Emelyanov, V. A., Plusnina, O. A., Makarov, E. M., Baidina, I. A., Smolentsev, A. I., Tkachev, S. V., & Asanova, T. I. (2017). Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes: Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl. European Journal of Inorganic Chemistry, 2017(5), 971-978. https://doi.org/10.1002/ejic.201601233

Vancouver

Vorobyev V, Emelyanov VA, Plusnina OA, Makarov EM, Baidina IA, Smolentsev AI et al. Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes: Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl. European Journal of Inorganic Chemistry. 2017 Feb 3;2017(5):971-978. doi: 10.1002/ejic.201601233

Author

Vorobyev, Vasily ; Emelyanov, Vyacheslav A. ; Plusnina, Olga A. et al. / Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes : Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl. In: European Journal of Inorganic Chemistry. 2017 ; Vol. 2017, No. 5. pp. 971-978.

BibTeX

@article{d89dd9796ef64f3dbf82892b124cb705,
title = "Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes: Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl",
abstract = "New high-yielding methods for two [RuNO(NH3)3Cl2]Cl complexes are suggested. First, the ammine ligands are arranged facially through the reaction of a concentrated ammonia solution with the ruthenium–hexanitro complex. In the next step, the treatment of the previously unknown fac-Na[Ru(NO2)3(NH3)3]·3H2O with hydrochloric acid leads to the nitrosyl complex. The mer-[RuNO(NH3)3Cl2]Cl·H2O complex is formed from the corresponding aqua complex under reflux in 6 m HCl. The complexes were studied by various methods [FTIR spectroscopy, 14N NMR spectroscopy, extended X-ray absorption fine structure (EXAFS), thermogravimetric analysis (TGA), and X-ray diffraction studies]. Metastable states (Ru–O–N) were observed in mer-[RuNO(NH3)3Cl(H2O)]Cl2, mer-[RuNO(NH3)3Cl2]Cl·H2O, and fac-[RuNO(NH3)3Cl2]Cl under illumination at λ = 443 nm at liquid-nitrogen temperatures.",
keywords = "Ammine complexes, Isomers, Nitrosyl complexes, Nitrosyl ligands, Ruthenium, Structure elucidation, NITROSYLRUTHENIUM COMPLEXES, RU, NITRIC-ACID SOLUTIONS, CRYSTAL-STRUCTURE, NITROSATION, HEXAAMMINERUTHENIUM(II), INDUCED METASTABLE STATES, NMR, SODIUM HEXANITRORUTHENATE(II), MAGNETIC-RESONANCE",
author = "Vasily Vorobyev and Emelyanov, {Vyacheslav A.} and Plusnina, {Olga A.} and Makarov, {Edgar M.} and Baidina, {Iraida A.} and Smolentsev, {Anton I.} and Tkachev, {Sergey V.} and Asanova, {Tatyana I.}",
year = "2017",
month = feb,
day = "3",
doi = "10.1002/ejic.201601233",
language = "English",
volume = "2017",
pages = "971--978",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "5",

}

RIS

TY - JOUR

T1 - Triammine fac and mer Coordination for Ruthenium–Nitrosyl Complexes

T2 - Synthesis and Characterization of [RuNO(NH3)3Cl2]Cl

AU - Vorobyev, Vasily

AU - Emelyanov, Vyacheslav A.

AU - Plusnina, Olga A.

AU - Makarov, Edgar M.

AU - Baidina, Iraida A.

AU - Smolentsev, Anton I.

AU - Tkachev, Sergey V.

AU - Asanova, Tatyana I.

PY - 2017/2/3

Y1 - 2017/2/3

N2 - New high-yielding methods for two [RuNO(NH3)3Cl2]Cl complexes are suggested. First, the ammine ligands are arranged facially through the reaction of a concentrated ammonia solution with the ruthenium–hexanitro complex. In the next step, the treatment of the previously unknown fac-Na[Ru(NO2)3(NH3)3]·3H2O with hydrochloric acid leads to the nitrosyl complex. The mer-[RuNO(NH3)3Cl2]Cl·H2O complex is formed from the corresponding aqua complex under reflux in 6 m HCl. The complexes were studied by various methods [FTIR spectroscopy, 14N NMR spectroscopy, extended X-ray absorption fine structure (EXAFS), thermogravimetric analysis (TGA), and X-ray diffraction studies]. Metastable states (Ru–O–N) were observed in mer-[RuNO(NH3)3Cl(H2O)]Cl2, mer-[RuNO(NH3)3Cl2]Cl·H2O, and fac-[RuNO(NH3)3Cl2]Cl under illumination at λ = 443 nm at liquid-nitrogen temperatures.

AB - New high-yielding methods for two [RuNO(NH3)3Cl2]Cl complexes are suggested. First, the ammine ligands are arranged facially through the reaction of a concentrated ammonia solution with the ruthenium–hexanitro complex. In the next step, the treatment of the previously unknown fac-Na[Ru(NO2)3(NH3)3]·3H2O with hydrochloric acid leads to the nitrosyl complex. The mer-[RuNO(NH3)3Cl2]Cl·H2O complex is formed from the corresponding aqua complex under reflux in 6 m HCl. The complexes were studied by various methods [FTIR spectroscopy, 14N NMR spectroscopy, extended X-ray absorption fine structure (EXAFS), thermogravimetric analysis (TGA), and X-ray diffraction studies]. Metastable states (Ru–O–N) were observed in mer-[RuNO(NH3)3Cl(H2O)]Cl2, mer-[RuNO(NH3)3Cl2]Cl·H2O, and fac-[RuNO(NH3)3Cl2]Cl under illumination at λ = 443 nm at liquid-nitrogen temperatures.

KW - Ammine complexes

KW - Isomers

KW - Nitrosyl complexes

KW - Nitrosyl ligands

KW - Ruthenium

KW - Structure elucidation

KW - NITROSYLRUTHENIUM COMPLEXES

KW - RU

KW - NITRIC-ACID SOLUTIONS

KW - CRYSTAL-STRUCTURE

KW - NITROSATION

KW - HEXAAMMINERUTHENIUM(II)

KW - INDUCED METASTABLE STATES

KW - NMR

KW - SODIUM HEXANITRORUTHENATE(II)

KW - MAGNETIC-RESONANCE

UR - http://www.scopus.com/inward/record.url?scp=85011949656&partnerID=8YFLogxK

U2 - 10.1002/ejic.201601233

DO - 10.1002/ejic.201601233

M3 - Article

AN - SCOPUS:85011949656

VL - 2017

SP - 971

EP - 978

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 5

ER -

ID: 10310739