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Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4. / Mironov, I. V.; Makotchenko, E. V.

In: Russian Journal of Inorganic Chemistry, Vol. 63, No. 12, 01.12.2018, p. 1667-1672.

Research output: Contribution to journal › Article › peer-review

Harvard

Mironov, IV & Makotchenko, EV 2018, 'Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4', Russian Journal of Inorganic Chemistry, vol. 63, no. 12, pp. 1667-1672. https://doi.org/10.1134/S0036023618120161

APA

Mironov, I. V., & Makotchenko, E. V. (2018). Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4. Russian Journal of Inorganic Chemistry, 63(12), 1667-1672. https://doi.org/10.1134/S0036023618120161

Vancouver

Mironov IV, Makotchenko EV. Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4. Russian Journal of Inorganic Chemistry. 2018 Dec 1;63(12):1667-1672. doi: 10.1134/S0036023618120161

Author

Mironov, I. V. ; Makotchenko, E. V. / Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4. In: Russian Journal of Inorganic Chemistry. 2018 ; Vol. 63, No. 12. pp. 1667-1672.

BibTeX

@article{f014121105834bb08b33dead0238262f,
title = "Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4",
abstract = "The interaction of AuCl4 - with thiourea (tu) at various Сtu/СAu ratios and transformations of the bis(thiourea)gold(I) complex in an alkaline aqueous solution have been studied. Both processes lead to a set of products. It has been demonstrated that formamidine disulfide is not the major product of thiourea oxidation. The precipitate forming upon the treatment of AuCl4 - with an alkali contains Au2S and an organic part, which is likely a polymeric compound [Au(tu-H)]n.",
keywords = "gold(I) complexes, gold(III) complexes, thiourea, ACID, FORMAMIDINE DISULFIDE, THIOCARBAMIDE, gold(<bold>III</bold>) complexes, gold(<bold>I</bold>) complexes, GOLD DISSOLUTION",
author = "Mironov, {I. V.} and Makotchenko, {E. V.}",
year = "2018",
month = dec,
day = "1",
doi = "10.1134/S0036023618120161",
language = "English",
volume = "63",
pages = "1667--1672",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "12",

}

RIS

TY - JOUR

T1 - Transformations of the Bis(thiourea)gold(I) Complex in Alkaline Medium and Interaction of Thiourea with HAuCl4

AU - Mironov, I. V.

AU - Makotchenko, E. V.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The interaction of AuCl4 - with thiourea (tu) at various Сtu/СAu ratios and transformations of the bis(thiourea)gold(I) complex in an alkaline aqueous solution have been studied. Both processes lead to a set of products. It has been demonstrated that formamidine disulfide is not the major product of thiourea oxidation. The precipitate forming upon the treatment of AuCl4 - with an alkali contains Au2S and an organic part, which is likely a polymeric compound [Au(tu-H)]n.

AB - The interaction of AuCl4 - with thiourea (tu) at various Сtu/СAu ratios and transformations of the bis(thiourea)gold(I) complex in an alkaline aqueous solution have been studied. Both processes lead to a set of products. It has been demonstrated that formamidine disulfide is not the major product of thiourea oxidation. The precipitate forming upon the treatment of AuCl4 - with an alkali contains Au2S and an organic part, which is likely a polymeric compound [Au(tu-H)]n.

KW - gold(I) complexes

KW - gold(III) complexes

KW - thiourea

KW - ACID

KW - FORMAMIDINE DISULFIDE

KW - THIOCARBAMIDE

KW - gold(<bold>III</bold>) complexes

KW - gold(<bold>I</bold>) complexes

KW - GOLD DISSOLUTION

UR - http://www.scopus.com/inward/record.url?scp=85058971054&partnerID=8YFLogxK

U2 - 10.1134/S0036023618120161

DO - 10.1134/S0036023618120161

M3 - Article

AN - SCOPUS:85058971054

VL - 63

SP - 1667

EP - 1672

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 12

ER -

ID: 18073128