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Thermodynamic Study of Tellurium Polybromide Complexes. / Zelenina, L. N.; Chusova, T. P.; Korobeinikov, N. A. et al.

In: Russian Journal of Physical Chemistry A, Vol. 98, No. 1, 14.06.2024, p. 50-56.

Research output: Contribution to journal › Article › peer-review

Harvard

Zelenina, LN, Chusova, TP, Korobeinikov, NA & Usol’tsev, AN 2024, 'Thermodynamic Study of Tellurium Polybromide Complexes', Russian Journal of Physical Chemistry A, vol. 98, no. 1, pp. 50-56. https://doi.org/10.1134/S003602442401031X

APA

Zelenina, L. N., Chusova, T. P., Korobeinikov, N. A., & Usol’tsev, A. N. (2024). Thermodynamic Study of Tellurium Polybromide Complexes. Russian Journal of Physical Chemistry A, 98(1), 50-56. https://doi.org/10.1134/S003602442401031X

Vancouver

Zelenina LN, Chusova TP, Korobeinikov NA, Usol’tsev AN. Thermodynamic Study of Tellurium Polybromide Complexes. Russian Journal of Physical Chemistry A. 2024 Jun 14;98(1):50-56. doi: 10.1134/S003602442401031X

Author

Zelenina, L. N. ; Chusova, T. P. ; Korobeinikov, N. A. et al. / Thermodynamic Study of Tellurium Polybromide Complexes. In: Russian Journal of Physical Chemistry A. 2024 ; Vol. 98, No. 1. pp. 50-56.

BibTeX

@article{9e28122e9aae48dca544588c77e2ebfe,
title = "Thermodynamic Study of Tellurium Polybromide Complexes",
abstract = "Abstract: The pressure of saturated and unsaturated Br2 vapors over (cation)2{[TeBr6](Br2)} (cation = Me4N+, Et4N+) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (Tdec). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (,, = f(T)) are calculated, and the energies of bonding between [TeBr6] octahedra and Br2 () are determined. Results are compared to others for bismuth polybromide complexes studied earlier.",
keywords = "static tensimetry, tellurium polybromide complexes, thermodynamic characteristics, vapor pressure",
author = "Zelenina, {L. N.} and Chusova, {T. P.} and Korobeinikov, {N. A.} and Usol{\textquoteright}tsev, {A. N.}",
note = "This work was supported by the RF Ministry of Science and Higher Education, project nos. 121031700314-5 and 121031700313-8.",
year = "2024",
month = jun,
day = "14",
doi = "10.1134/S003602442401031X",
language = "English",
volume = "98",
pages = "50--56",
journal = "Russian Journal of Physical Chemistry A",
issn = "0036-0244",
publisher = "PLEIADES PUBLISHING INC",
number = "1",

}

RIS

TY - JOUR

T1 - Thermodynamic Study of Tellurium Polybromide Complexes

AU - Zelenina, L. N.

AU - Chusova, T. P.

AU - Korobeinikov, N. A.

AU - Usol’tsev, A. N.

N1 - This work was supported by the RF Ministry of Science and Higher Education, project nos. 121031700314-5 and 121031700313-8.

PY - 2024/6/14

Y1 - 2024/6/14

N2 - Abstract: The pressure of saturated and unsaturated Br2 vapors over (cation)2{[TeBr6](Br2)} (cation = Me4N+, Et4N+) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (Tdec). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (,, = f(T)) are calculated, and the energies of bonding between [TeBr6] octahedra and Br2 () are determined. Results are compared to others for bismuth polybromide complexes studied earlier.

AB - Abstract: The pressure of saturated and unsaturated Br2 vapors over (cation)2{[TeBr6](Br2)} (cation = Me4N+, Et4N+) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (Tdec). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (,, = f(T)) are calculated, and the energies of bonding between [TeBr6] octahedra and Br2 () are determined. Results are compared to others for bismuth polybromide complexes studied earlier.

KW - static tensimetry

KW - tellurium polybromide complexes

KW - thermodynamic characteristics

KW - vapor pressure

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:001237115500052

UR - https://www.mendeley.com/catalogue/83ac6924-5f69-395a-b192-d5ebc5350cb0/

U2 - 10.1134/S003602442401031X

DO - 10.1134/S003602442401031X

M3 - Article

VL - 98

SP - 50

EP - 56

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 1

ER -

ID: 61165475