Standard

Thermodynamic study of bromine evaporation from solid Bi(III) polybromides. / Zelenina, L. N.; Chusova, T. P.; Isakov, A. V. et al.

In: Journal of Chemical Thermodynamics, Vol. 141, 105958, 01.02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Zelenina, LN, Chusova, TP, Isakov, AV, Adonin, SA & Sokolov, MN 2020, 'Thermodynamic study of bromine evaporation from solid Bi(III) polybromides', Journal of Chemical Thermodynamics, vol. 141, 105958. https://doi.org/10.1016/j.jct.2019.105958

APA

Zelenina, L. N., Chusova, T. P., Isakov, A. V., Adonin, S. A., & Sokolov, M. N. (2020). Thermodynamic study of bromine evaporation from solid Bi(III) polybromides. Journal of Chemical Thermodynamics, 141, [105958]. https://doi.org/10.1016/j.jct.2019.105958

Vancouver

Zelenina LN, Chusova TP, Isakov AV, Adonin SA, Sokolov MN. Thermodynamic study of bromine evaporation from solid Bi(III) polybromides. Journal of Chemical Thermodynamics. 2020 Feb 1;141:105958. doi: 10.1016/j.jct.2019.105958

Author

Zelenina, L. N. ; Chusova, T. P. ; Isakov, A. V. et al. / Thermodynamic study of bromine evaporation from solid Bi(III) polybromides. In: Journal of Chemical Thermodynamics. 2020 ; Vol. 141.

BibTeX

@article{8e33882f0de94a5f8f73d69b76ff0338,
title = "Thermodynamic study of bromine evaporation from solid Bi(III) polybromides",
abstract = "The pressure of saturated and unsaturated bromine vapor over solid Bi(III) polybromides (PyH)3[Bi2Br9(Br2)] and (N-MePy)3[Bi2Br9(Br2)], where Py is pyridinium, N-MePy is N-methil pyridinium, has been measured for the first time in a wide temperature range using a static method with glass membrane-gauge manometers. As a result of this study the thermal stabilities of investigated complexes were established, the temperature dependences of bromine vapor pressure were obtained, the thermodynamic characteristics of bromine evaporation processes (ΔprH°T, ΔprS°T) were calculated and a new possibility for the synthesis of polybromides was proposed.",
keywords = "Bi(III) polybromides, Enthalpy and entropy of bromine evaporation processes, Static method with glass membrane-gauge manometers, Vapor pressure measurements, QUATERNARY AMMONIUM, PHASE, COMPLEXES, BR-2, ZINC",
author = "Zelenina, {L. N.} and Chusova, {T. P.} and Isakov, {A. V.} and Adonin, {S. A.} and Sokolov, {M. N.}",
year = "2020",
month = feb,
day = "1",
doi = "10.1016/j.jct.2019.105958",
language = "English",
volume = "141",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - Thermodynamic study of bromine evaporation from solid Bi(III) polybromides

AU - Zelenina, L. N.

AU - Chusova, T. P.

AU - Isakov, A. V.

AU - Adonin, S. A.

AU - Sokolov, M. N.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - The pressure of saturated and unsaturated bromine vapor over solid Bi(III) polybromides (PyH)3[Bi2Br9(Br2)] and (N-MePy)3[Bi2Br9(Br2)], where Py is pyridinium, N-MePy is N-methil pyridinium, has been measured for the first time in a wide temperature range using a static method with glass membrane-gauge manometers. As a result of this study the thermal stabilities of investigated complexes were established, the temperature dependences of bromine vapor pressure were obtained, the thermodynamic characteristics of bromine evaporation processes (ΔprH°T, ΔprS°T) were calculated and a new possibility for the synthesis of polybromides was proposed.

AB - The pressure of saturated and unsaturated bromine vapor over solid Bi(III) polybromides (PyH)3[Bi2Br9(Br2)] and (N-MePy)3[Bi2Br9(Br2)], where Py is pyridinium, N-MePy is N-methil pyridinium, has been measured for the first time in a wide temperature range using a static method with glass membrane-gauge manometers. As a result of this study the thermal stabilities of investigated complexes were established, the temperature dependences of bromine vapor pressure were obtained, the thermodynamic characteristics of bromine evaporation processes (ΔprH°T, ΔprS°T) were calculated and a new possibility for the synthesis of polybromides was proposed.

KW - Bi(III) polybromides

KW - Enthalpy and entropy of bromine evaporation processes

KW - Static method with glass membrane-gauge manometers

KW - Vapor pressure measurements

KW - QUATERNARY AMMONIUM

KW - PHASE

KW - COMPLEXES

KW - BR-2

KW - ZINC

UR - http://www.scopus.com/inward/record.url?scp=85072544367&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2019.105958

DO - 10.1016/j.jct.2019.105958

M3 - Article

AN - SCOPUS:85072544367

VL - 141

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

M1 - 105958

ER -

ID: 21609623