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Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate. / Uvarov, Nikolai F.; Asanbaeva, Nargiz B.; Ulihin, Artem S. et al.

In: Crystals, Vol. 12, No. 4, 515, 04.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Uvarov, NF, Asanbaeva, NB, Ulihin, AS, Mateyshina, YG & Gerasimov, KB 2022, 'Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate', Crystals, vol. 12, no. 4, 515. https://doi.org/10.3390/cryst12040515

APA

Uvarov, N. F., Asanbaeva, N. B., Ulihin, A. S., Mateyshina, Y. G., & Gerasimov, K. B. (2022). Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate. Crystals, 12(4), [515]. https://doi.org/10.3390/cryst12040515

Vancouver

Uvarov NF, Asanbaeva NB, Ulihin AS, Mateyshina YG, Gerasimov KB. Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate. Crystals. 2022 Apr;12(4):515. doi: 10.3390/cryst12040515

Author

Uvarov, Nikolai F. ; Asanbaeva, Nargiz B. ; Ulihin, Artem S. et al. / Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate. In: Crystals. 2022 ; Vol. 12, No. 4.

BibTeX

@article{faf7180b428d4882b57b1d4b53d05e13,
title = "Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate",
abstract = "The thermal parameters of the phase transitions and transport properties of tetra-n-butylammonium (TBA) perchlorate (n-C4H9 )4NClO4 (TBAClO4 ) were investigated. TBAClO4 has a polymorphous transition at 330 K and melts at 487 K. The structure of the high-temperature (HT) phase belongs to cubic symmetry and is similar to the HT phases of TBABF4 and TBAI salts. The conductivity parameters of the low-temperature and HT phases of TBAClO4 were determined from the Arrhenius plots. The thermodynamic parameters and transport properties of TBAClO4 were compared with those of other TBA salts having isostructural HT phases. The polymorphous phase transition entropy was found to correlate with the conductivity of HT phases of TBA salts; TBAClO4 has the lowest conductivity compared to TBABF4 and TBAI salts.",
keywords = "high-temperature phase, ionic conductivity, polymorphous phase transition and melting, tetra-n-butylammonium perchlorate",
author = "Uvarov, {Nikolai F.} and Asanbaeva, {Nargiz B.} and Ulihin, {Artem S.} and Mateyshina, {Yulia G.} and Gerasimov, {Konstantin B.}",
note = "Funding Information: This research was funded by the Russian Science Foundation, project No. 20-13-00302. Publisher Copyright: {\textcopyright} 2022 by the authors. Licensee MDPI, Basel, Switzerland.",
year = "2022",
month = apr,
doi = "10.3390/cryst12040515",
language = "English",
volume = "12",
journal = "Crystals",
issn = "2073-4352",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "4",

}

RIS

TY - JOUR

T1 - Thermal Properties and Ionic Conductivity of Tetra-n-Butylammonium Perchlorate

AU - Uvarov, Nikolai F.

AU - Asanbaeva, Nargiz B.

AU - Ulihin, Artem S.

AU - Mateyshina, Yulia G.

AU - Gerasimov, Konstantin B.

N1 - Funding Information: This research was funded by the Russian Science Foundation, project No. 20-13-00302. Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2022/4

Y1 - 2022/4

N2 - The thermal parameters of the phase transitions and transport properties of tetra-n-butylammonium (TBA) perchlorate (n-C4H9 )4NClO4 (TBAClO4 ) were investigated. TBAClO4 has a polymorphous transition at 330 K and melts at 487 K. The structure of the high-temperature (HT) phase belongs to cubic symmetry and is similar to the HT phases of TBABF4 and TBAI salts. The conductivity parameters of the low-temperature and HT phases of TBAClO4 were determined from the Arrhenius plots. The thermodynamic parameters and transport properties of TBAClO4 were compared with those of other TBA salts having isostructural HT phases. The polymorphous phase transition entropy was found to correlate with the conductivity of HT phases of TBA salts; TBAClO4 has the lowest conductivity compared to TBABF4 and TBAI salts.

AB - The thermal parameters of the phase transitions and transport properties of tetra-n-butylammonium (TBA) perchlorate (n-C4H9 )4NClO4 (TBAClO4 ) were investigated. TBAClO4 has a polymorphous transition at 330 K and melts at 487 K. The structure of the high-temperature (HT) phase belongs to cubic symmetry and is similar to the HT phases of TBABF4 and TBAI salts. The conductivity parameters of the low-temperature and HT phases of TBAClO4 were determined from the Arrhenius plots. The thermodynamic parameters and transport properties of TBAClO4 were compared with those of other TBA salts having isostructural HT phases. The polymorphous phase transition entropy was found to correlate with the conductivity of HT phases of TBA salts; TBAClO4 has the lowest conductivity compared to TBABF4 and TBAI salts.

KW - high-temperature phase

KW - ionic conductivity

KW - polymorphous phase transition and melting

KW - tetra-n-butylammonium perchlorate

UR - http://www.scopus.com/inward/record.url?scp=85128643369&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/a9cbc5a9-9f48-3b93-9e32-2745cff2a150/

U2 - 10.3390/cryst12040515

DO - 10.3390/cryst12040515

M3 - Article

AN - SCOPUS:85128643369

VL - 12

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 4

M1 - 515

ER -

ID: 36029345