Research output: Contribution to journal › Article › peer-review
Thermal decomposition of solid solutions in systems of Fe(II), Co(II), and Ni(II) hydrogen maleates with the formation of bimetallic nanoparticles. / Yudanova, L. I.; Logvinenko, V. A.; Sheludyakova, L. A. et al.
In: Russian Journal of Physical Chemistry A, Vol. 91, No. 1, 01.01.2017, p. 136-140.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Thermal decomposition of solid solutions in systems of Fe(II), Co(II), and Ni(II) hydrogen maleates with the formation of bimetallic nanoparticles
AU - Yudanova, L. I.
AU - Logvinenko, V. A.
AU - Sheludyakova, L. A.
AU - Ishchenko, A. V.
AU - Rudina, N. A.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - XRD phase analysis and thermal analysis are used to confirm the formation of a continuous series of solid solutions in which one cation is substituted for another in the systems Co(II) hydrogen maleate–Ni(II) hydrogen maleate; Fe(II) hydrogen maleate–Co(II) hydrogen maleate; and Fe(II) hydrogen maleate–Ni(II) hydrogen maleate. The unit cell volume of these solid solutions is shown to depend linearly on their composition. The linear character of changes in the initial temperatures of dehydration and thermal decomposition is established. Using the example of the first of these systems, it is shown that when heated, bimetallic nanoparticles embedded in the polymeric matrix of composites obtained via the thermal decomposition of solid solutions of hydrogen maleates undergo a second-order phase transition, resulting in decomposition of the solid solutions of metals at the Curie temperature.
AB - XRD phase analysis and thermal analysis are used to confirm the formation of a continuous series of solid solutions in which one cation is substituted for another in the systems Co(II) hydrogen maleate–Ni(II) hydrogen maleate; Fe(II) hydrogen maleate–Co(II) hydrogen maleate; and Fe(II) hydrogen maleate–Ni(II) hydrogen maleate. The unit cell volume of these solid solutions is shown to depend linearly on their composition. The linear character of changes in the initial temperatures of dehydration and thermal decomposition is established. Using the example of the first of these systems, it is shown that when heated, bimetallic nanoparticles embedded in the polymeric matrix of composites obtained via the thermal decomposition of solid solutions of hydrogen maleates undergo a second-order phase transition, resulting in decomposition of the solid solutions of metals at the Curie temperature.
KW - bimetallic nanoparticles
KW - dehydration
KW - solid solutions
KW - thermal analysis
KW - XRD phase analysis
UR - http://www.scopus.com/inward/record.url?scp=85012226079&partnerID=8YFLogxK
U2 - 10.1134/S0036024417010320
DO - 10.1134/S0036024417010320
M3 - Article
AN - SCOPUS:85012226079
VL - 91
SP - 136
EP - 140
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 1
ER -
ID: 10311610