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Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones. / Logvinenko, V. A.; Fadeeva, V. P.; Selivanov, B. A. et al.

In: Journal of Thermal Analysis and Calorimetry, Vol. 140, No. 2, 01.04.2020, p. 685-693.

Research output: Contribution to journal › Article › peer-review

Harvard

Logvinenko, VA, Fadeeva, VP, Selivanov, BA, Tikhova, VD, Nefedov, AA & Tikhonov, AY 2020, 'Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones', Journal of Thermal Analysis and Calorimetry, vol. 140, no. 2, pp. 685-693. https://doi.org/10.1007/s10973-019-08868-4

APA

Logvinenko, V. A., Fadeeva, V. P., Selivanov, B. A., Tikhova, V. D., Nefedov, A. A., & Tikhonov, A. Y. (2020). Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones. Journal of Thermal Analysis and Calorimetry, 140(2), 685-693. https://doi.org/10.1007/s10973-019-08868-4

Vancouver

Logvinenko VA, Fadeeva VP, Selivanov BA, Tikhova VD, Nefedov AA, Tikhonov AY. Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones. Journal of Thermal Analysis and Calorimetry. 2020 Apr 1;140(2):685-693. doi: 10.1007/s10973-019-08868-4

Author

Logvinenko, V. A. ; Fadeeva, V. P. ; Selivanov, B. A. et al. / Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones. In: Journal of Thermal Analysis and Calorimetry. 2020 ; Vol. 140, No. 2. pp. 685-693.

BibTeX

@article{72e4ba858ce24d4397a5c5172f4ded1b,
title = "Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones",
abstract = "N,N′-Bis(2-hydroxyiminoalkyl)-α,α′-dinitrones are of interest for the synthesis of 1,1′-dihydroxy-2,2′-biimidazoles. Thermal decomposition of two these dinitrones was studied in helium atmosphere. Thermal decomposition of the studied dinitrones at temperature interval 20–500 °C consists of several steps, the first step accompanying with significant exothermic effect (700–1000 J g−1). The first step has been shown to be a two-stage process, and decomposition products have been determined using chromatography–mass spectrometry. Thermogravimetric curves were used for the kinetic studies. Kinetic parameters of decomposition are estimated within the approaches of non-isothermal kinetics (“model-free” kinetics and nonlinear regression methods), with the computer program Netzsch Thermokinetics 2.",
keywords = "Dinitrones, Kinetic stability, Non-isothermal kinetics, Organic compounds, APPROXIMATION, COMPLEXES, KINETIC-ANALYSIS, DEGRADATION, ACTIVATION-ENERGY, DERIVATIVES",
author = "Logvinenko, {V. A.} and Fadeeva, {V. P.} and Selivanov, {B. A.} and Tikhova, {V. D.} and Nefedov, {A. A.} and Tikhonov, {A. Ya}",
note = "Funding Information: This work was partially supported by the Russian Foundation for Basic Research (Grant 14–03–00291). Publisher Copyright: {\textcopyright} 2019, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = apr,
day = "1",
doi = "10.1007/s10973-019-08868-4",
language = "English",
volume = "140",
pages = "685--693",
journal = "Journal of Thermal Analysis and Calorimetry",
issn = "1388-6150",
publisher = "Springer Nature",
number = "2",

}

RIS

TY - JOUR

T1 - Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones

AU - Logvinenko, V. A.

AU - Fadeeva, V. P.

AU - Selivanov, B. A.

AU - Tikhova, V. D.

AU - Nefedov, A. A.

AU - Tikhonov, A. Ya

N1 - Funding Information: This work was partially supported by the Russian Foundation for Basic Research (Grant 14–03–00291). Publisher Copyright: © 2019, Akadémiai Kiadó, Budapest, Hungary. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/4/1

Y1 - 2020/4/1

N2 - N,N′-Bis(2-hydroxyiminoalkyl)-α,α′-dinitrones are of interest for the synthesis of 1,1′-dihydroxy-2,2′-biimidazoles. Thermal decomposition of two these dinitrones was studied in helium atmosphere. Thermal decomposition of the studied dinitrones at temperature interval 20–500 °C consists of several steps, the first step accompanying with significant exothermic effect (700–1000 J g−1). The first step has been shown to be a two-stage process, and decomposition products have been determined using chromatography–mass spectrometry. Thermogravimetric curves were used for the kinetic studies. Kinetic parameters of decomposition are estimated within the approaches of non-isothermal kinetics (“model-free” kinetics and nonlinear regression methods), with the computer program Netzsch Thermokinetics 2.

AB - N,N′-Bis(2-hydroxyiminoalkyl)-α,α′-dinitrones are of interest for the synthesis of 1,1′-dihydroxy-2,2′-biimidazoles. Thermal decomposition of two these dinitrones was studied in helium atmosphere. Thermal decomposition of the studied dinitrones at temperature interval 20–500 °C consists of several steps, the first step accompanying with significant exothermic effect (700–1000 J g−1). The first step has been shown to be a two-stage process, and decomposition products have been determined using chromatography–mass spectrometry. Thermogravimetric curves were used for the kinetic studies. Kinetic parameters of decomposition are estimated within the approaches of non-isothermal kinetics (“model-free” kinetics and nonlinear regression methods), with the computer program Netzsch Thermokinetics 2.

KW - Dinitrones

KW - Kinetic stability

KW - Non-isothermal kinetics

KW - Organic compounds

KW - APPROXIMATION

KW - COMPLEXES

KW - KINETIC-ANALYSIS

KW - DEGRADATION

KW - ACTIVATION-ENERGY

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85074560639&partnerID=8YFLogxK

U2 - 10.1007/s10973-019-08868-4

DO - 10.1007/s10973-019-08868-4

M3 - Article

AN - SCOPUS:85074560639

VL - 140

SP - 685

EP - 693

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

SN - 1388-6150

IS - 2

ER -

ID: 22361464