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Theoretical model for forbidden ortho-para absorption in nuclear spin isomers of molecules. / Chapovsky, P. L.

In: Physical Review A, Vol. 98, No. 5, 052501, 02.11.2018.

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Chapovsky PL. Theoretical model for forbidden ortho-para absorption in nuclear spin isomers of molecules. Physical Review A. 2018 Nov 2;98(5):052501. doi: 10.1103/PhysRevA.98.052501

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Chapovsky, P. L. / Theoretical model for forbidden ortho-para absorption in nuclear spin isomers of molecules. In: Physical Review A. 2018 ; Vol. 98, No. 5.

BibTeX

@article{b195692185c143e99fc0d9da0f55f8ef,
title = "Theoretical model for forbidden ortho-para absorption in nuclear spin isomers of molecules",
abstract = "A theoretical model for forbidden ortho-para absorption in molecules having weak intramolecular mixing of spin isomers is developed. The model is based on the quantum kinetic equation for the density matrix and uses the particular case of CH313F nuclear-spin isomers for numerical calculations. Forbidden ortho-para absorption appears to be very small, making its detection difficult in a standard approach. Two alternative methods for detection of forbidden ortho-para absorption are proposed. The methods use microwave enrichment of spin isomers and microwave speed up of the isomer conversion.",
keywords = "ORTHO-PARA TRANSITIONS, CONVERSION",
author = "Chapovsky, {P. L.}",
year = "2018",
month = nov,
day = "2",
doi = "10.1103/PhysRevA.98.052501",
language = "English",
volume = "98",
journal = "Physical Review A",
issn = "2469-9926",
publisher = "American Physical Society",
number = "5",

}

RIS

TY - JOUR

T1 - Theoretical model for forbidden ortho-para absorption in nuclear spin isomers of molecules

AU - Chapovsky, P. L.

PY - 2018/11/2

Y1 - 2018/11/2

N2 - A theoretical model for forbidden ortho-para absorption in molecules having weak intramolecular mixing of spin isomers is developed. The model is based on the quantum kinetic equation for the density matrix and uses the particular case of CH313F nuclear-spin isomers for numerical calculations. Forbidden ortho-para absorption appears to be very small, making its detection difficult in a standard approach. Two alternative methods for detection of forbidden ortho-para absorption are proposed. The methods use microwave enrichment of spin isomers and microwave speed up of the isomer conversion.

AB - A theoretical model for forbidden ortho-para absorption in molecules having weak intramolecular mixing of spin isomers is developed. The model is based on the quantum kinetic equation for the density matrix and uses the particular case of CH313F nuclear-spin isomers for numerical calculations. Forbidden ortho-para absorption appears to be very small, making its detection difficult in a standard approach. Two alternative methods for detection of forbidden ortho-para absorption are proposed. The methods use microwave enrichment of spin isomers and microwave speed up of the isomer conversion.

KW - ORTHO-PARA TRANSITIONS

KW - CONVERSION

UR - http://www.scopus.com/inward/record.url?scp=85056303932&partnerID=8YFLogxK

U2 - 10.1103/PhysRevA.98.052501

DO - 10.1103/PhysRevA.98.052501

M3 - Article

AN - SCOPUS:85056303932

VL - 98

JO - Physical Review A

JF - Physical Review A

SN - 2469-9926

IS - 5

M1 - 052501

ER -

ID: 17413477