Theoretical Description of Pulsed RYDMR

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Theoretical Description of Pulsed RYDMR : Refocusing Zero-Quantum and Single Quantum Coherences. / Nasibulov, Egor A.; Behrends, Jan; Kulik, Leonid V. et al.

In: Zeitschrift fur Physikalische Chemie, Vol. 231, No. 2, 01.02.2017, p. 269-291.

Research output: Contribution to journal › Article › peer-review

Harvard

Nasibulov, EA, Behrends, J, Kulik, LV & Ivanov, KL 2017, 'Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences', Zeitschrift fur Physikalische Chemie, vol. 231, no. 2, pp. 269-291. https://doi.org/10.1515/zpch-2016-0817

APA

Nasibulov, E. A., Behrends, J., Kulik, L. V., & Ivanov, K. L. (2017). Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences. Zeitschrift fur Physikalische Chemie, 231(2), 269-291. https://doi.org/10.1515/zpch-2016-0817

Vancouver

Nasibulov EA, Behrends J, Kulik LV, Ivanov KL. Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences. Zeitschrift fur Physikalische Chemie. 2017 Feb 1;231(2):269-291. doi: 10.1515/zpch-2016-0817

Author

Nasibulov, Egor A. ; Behrends, Jan ; Kulik, Leonid V. et al. / Theoretical Description of Pulsed RYDMR : Refocusing Zero-Quantum and Single Quantum Coherences. In: Zeitschrift fur Physikalische Chemie. 2017 ; Vol. 231, No. 2. pp. 269-291.

BibTeX

@article{7e9b96da3c87402db8546d72d6bee96d,

title = "Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences",

abstract = "A theoretical description of pulsed reaction yield detected magnetic resonance (RYDMR) is proposed. In RYDMR, magnetic resonance spectra of radical pairs (RPs) are indirectly detected by monitoring their recombination yield. Such a detection method is significantly more sensitive than conventional electron paramagnetic resonance (EPR), but design of appropriate pulse sequences for RYDMR requires additional effort because of a different observable. In this work various schemes for generating spin-echo like signals and detecting them by RYDMR are treated. Specifically, we consider refocusing of zero-quantum coherences (ZQCs) and single-quantum coherences (SQCs) by selective as well as by non-selective pulses and formulate a general analytical approach to pulsed RYDMR, which makes an efficient use of the product operator formalism. We anticipate that these results are of importance for RYDMR studies of elusive paramagnetic particles, notably, in organic semiconductors.",

keywords = "Organic semiconductors, RYDMR, spin chemistry, spin echo",

author = "Nasibulov, {Egor A.} and Jan Behrends and Kulik, {Leonid V.} and Ivanov, {Konstantin L.}",

note = "Publisher Copyright: {\textcopyright} 2017 Walter de Gruyter GmbH.",

year = "2017",

month = feb,

day = "1",

doi = "10.1515/zpch-2016-0817",

language = "English",

volume = "231",

pages = "269--291",

journal = "Zeitschrift fur Physikalische Chemie",

issn = "0942-9352",

publisher = "Walter de Gruyter GmbH",

number = "2",

}

RIS

TY - JOUR

T1 - Theoretical Description of Pulsed RYDMR

T2 - Refocusing Zero-Quantum and Single Quantum Coherences

AU - Nasibulov, Egor A.

AU - Behrends, Jan

AU - Kulik, Leonid V.

AU - Ivanov, Konstantin L.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - A theoretical description of pulsed reaction yield detected magnetic resonance (RYDMR) is proposed. In RYDMR, magnetic resonance spectra of radical pairs (RPs) are indirectly detected by monitoring their recombination yield. Such a detection method is significantly more sensitive than conventional electron paramagnetic resonance (EPR), but design of appropriate pulse sequences for RYDMR requires additional effort because of a different observable. In this work various schemes for generating spin-echo like signals and detecting them by RYDMR are treated. Specifically, we consider refocusing of zero-quantum coherences (ZQCs) and single-quantum coherences (SQCs) by selective as well as by non-selective pulses and formulate a general analytical approach to pulsed RYDMR, which makes an efficient use of the product operator formalism. We anticipate that these results are of importance for RYDMR studies of elusive paramagnetic particles, notably, in organic semiconductors.

AB - A theoretical description of pulsed reaction yield detected magnetic resonance (RYDMR) is proposed. In RYDMR, magnetic resonance spectra of radical pairs (RPs) are indirectly detected by monitoring their recombination yield. Such a detection method is significantly more sensitive than conventional electron paramagnetic resonance (EPR), but design of appropriate pulse sequences for RYDMR requires additional effort because of a different observable. In this work various schemes for generating spin-echo like signals and detecting them by RYDMR are treated. Specifically, we consider refocusing of zero-quantum coherences (ZQCs) and single-quantum coherences (SQCs) by selective as well as by non-selective pulses and formulate a general analytical approach to pulsed RYDMR, which makes an efficient use of the product operator formalism. We anticipate that these results are of importance for RYDMR studies of elusive paramagnetic particles, notably, in organic semiconductors.

KW - Organic semiconductors

KW - RYDMR

KW - spin chemistry

KW - spin echo

UR - http://www.scopus.com/inward/record.url?scp=85012195395&partnerID=8YFLogxK

U2 - 10.1515/zpch-2016-0817

DO - 10.1515/zpch-2016-0817

M3 - Article

AN - SCOPUS:85012195395

VL - 231

SP - 269

EP - 291

JO - Zeitschrift fur Physikalische Chemie

JF - Zeitschrift fur Physikalische Chemie

SN - 0942-9352

IS - 2

ER -

ID: 9032976