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Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane. / Shelepova, E.; Vedyagin, A.; Sadykov, V. et al.

In: Catalysis Today, Vol. 268, 15.06.2016, p. 103-110.

Research output: Contribution to journal › Article › peer-review

Harvard

Shelepova, E, Vedyagin, A, Sadykov, V, Mezentseva, N, Fedorova, Y, Smorygo, O, Klenov, O & Mishakov, I 2016, 'Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane', Catalysis Today, vol. 268, pp. 103-110. https://doi.org/10.1016/j.cattod.2016.01.005

APA

Shelepova, E., Vedyagin, A., Sadykov, V., Mezentseva, N., Fedorova, Y., Smorygo, O., Klenov, O., & Mishakov, I. (2016). Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane. Catalysis Today, 268, 103-110. https://doi.org/10.1016/j.cattod.2016.01.005

Vancouver

Shelepova E, Vedyagin A, Sadykov V, Mezentseva N, Fedorova Y, Smorygo O et al. Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane. Catalysis Today. 2016 Jun 15;268:103-110. doi: 10.1016/j.cattod.2016.01.005

Author

Shelepova, E. ; Vedyagin, A. ; Sadykov, V. et al. / Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane. In: Catalysis Today. 2016 ; Vol. 268. pp. 103-110.

BibTeX

@article{0c7cf539f8fb489cb6c62a916d3c7890,
title = "Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane",
abstract = "This paper presents results of theoretical and experimental research concerning synthesis of multilayer asymmetric oxygen-permeable membrane and its application for partial oxidation of methane. The membrane is based on macroporous Ni-Al foam substrate with three layers of perovskite-fluorite nanocomposites with graded (meso-micro) porosity, thin dense MnFe2O4-Ce0.9Gd0.1O2 layer and porous layer of LaNi0.9Pt0.1O3/Pr0.3Ce0.35Zr0.35O2-x catalyst. Testing of membrane in methane partial oxidation process demonstrates a good and stable performance. The mathematical modeling of the methane partial oxidation process in the catalytic membrane reactor has been provided. The developed model was applied to find the process (temperature, gas flow rates, etc.) and membrane (pore diameter of porous layer, thickness of porous layer) parameters corresponding to highest methane conversion and syngas selectivity.",
keywords = "Catalytic membrane reactor, Mathematical modeling, Mixed ionic-electronic conductivity, Nanocomposites, Oxygen-permeable membrane, Partial oxidation of methane, Syngas production",
author = "E. Shelepova and A. Vedyagin and V. Sadykov and N. Mezentseva and Y. Fedorova and O. Smorygo and O. Klenov and I. Mishakov",
year = "2016",
month = jun,
day = "15",
doi = "10.1016/j.cattod.2016.01.005",
language = "English",
volume = "268",
pages = "103--110",
journal = "Catalysis Today",
issn = "0920-5861",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Theoretical and experimental study of methane partial oxidation to syngas in catalytic membrane reactor with asymmetric oxygen-permeable membrane

AU - Shelepova, E.

AU - Vedyagin, A.

AU - Sadykov, V.

AU - Mezentseva, N.

AU - Fedorova, Y.

AU - Smorygo, O.

AU - Klenov, O.

AU - Mishakov, I.

PY - 2016/6/15

Y1 - 2016/6/15

N2 - This paper presents results of theoretical and experimental research concerning synthesis of multilayer asymmetric oxygen-permeable membrane and its application for partial oxidation of methane. The membrane is based on macroporous Ni-Al foam substrate with three layers of perovskite-fluorite nanocomposites with graded (meso-micro) porosity, thin dense MnFe2O4-Ce0.9Gd0.1O2 layer and porous layer of LaNi0.9Pt0.1O3/Pr0.3Ce0.35Zr0.35O2-x catalyst. Testing of membrane in methane partial oxidation process demonstrates a good and stable performance. The mathematical modeling of the methane partial oxidation process in the catalytic membrane reactor has been provided. The developed model was applied to find the process (temperature, gas flow rates, etc.) and membrane (pore diameter of porous layer, thickness of porous layer) parameters corresponding to highest methane conversion and syngas selectivity.

AB - This paper presents results of theoretical and experimental research concerning synthesis of multilayer asymmetric oxygen-permeable membrane and its application for partial oxidation of methane. The membrane is based on macroporous Ni-Al foam substrate with three layers of perovskite-fluorite nanocomposites with graded (meso-micro) porosity, thin dense MnFe2O4-Ce0.9Gd0.1O2 layer and porous layer of LaNi0.9Pt0.1O3/Pr0.3Ce0.35Zr0.35O2-x catalyst. Testing of membrane in methane partial oxidation process demonstrates a good and stable performance. The mathematical modeling of the methane partial oxidation process in the catalytic membrane reactor has been provided. The developed model was applied to find the process (temperature, gas flow rates, etc.) and membrane (pore diameter of porous layer, thickness of porous layer) parameters corresponding to highest methane conversion and syngas selectivity.

KW - Catalytic membrane reactor

KW - Mathematical modeling

KW - Mixed ionic-electronic conductivity

KW - Nanocomposites

KW - Oxygen-permeable membrane

KW - Partial oxidation of methane

KW - Syngas production

UR - http://www.scopus.com/inward/record.url?scp=85027921639&partnerID=8YFLogxK

U2 - 10.1016/j.cattod.2016.01.005

DO - 10.1016/j.cattod.2016.01.005

M3 - Article

AN - SCOPUS:85027921639

VL - 268

SP - 103

EP - 110

JO - Catalysis Today

JF - Catalysis Today

SN - 0920-5861

ER -

ID: 25389959