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The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis. / Smirnova, M. Yu; Pavlova, S. N.; Krieger, T. A. et al.

In: Russian Journal of Physical Chemistry B, Vol. 11, No. 8, 01.12.2017, p. 1312-1321.

Research output: Contribution to journal › Article › peer-review

Harvard

Smirnova, MY, Pavlova, SN, Krieger, TA, Bespalko, YN, Anikeev, VI, Chesalov, YA, Kaichev, VV, Mezentseva, NV & Sadykov, VA 2017, 'The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis', Russian Journal of Physical Chemistry B, vol. 11, no. 8, pp. 1312-1321. https://doi.org/10.1134/S1990793117080103

APA

Smirnova, M. Y., Pavlova, S. N., Krieger, T. A., Bespalko, Y. N., Anikeev, V. I., Chesalov, Y. A., Kaichev, V. V., Mezentseva, N. V., & Sadykov, V. A. (2017). The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis. Russian Journal of Physical Chemistry B, 11(8), 1312-1321. https://doi.org/10.1134/S1990793117080103

Vancouver

Smirnova MY, Pavlova SN, Krieger TA, Bespalko YN, Anikeev VI, Chesalov YA et al. The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis. Russian Journal of Physical Chemistry B. 2017 Dec 1;11(8):1312-1321. doi: 10.1134/S1990793117080103

Author

Smirnova, M. Yu ; Pavlova, S. N. ; Krieger, T. A. et al. / The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis. In: Russian Journal of Physical Chemistry B. 2017 ; Vol. 11, No. 8. pp. 1312-1321.

BibTeX

@article{978d041fdac5404895013fd78c3e0cc1,
title = "The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis",
abstract = "The effect of the features of starting zirconium compounds on the solvothermal synthesis of mixed Ce–Zr oxides in a flow reactor using ethanol and isopropanol as a supercritical medium was studied. The phase composition and structural properties of the synthesized samples were investigated using X-ray diffraction analysis (XRD) and Raman spectroscopy. The morphology and textural properties were studied by transmission electron microscopy (TEM) and thermal desorption of nitrogen. It was found that the use of zirconium oxychloride or acetate as the starting substances results in the formation of a mixture of phases enriched with cerium or zirconium, whereas the use of zirconium butoxide with acetylacetone as a complexing agent allows obtaining a homogeneous solid solution. The catalytic properties of the synthesized oxides with supported Ni were tested in methane dry reforming (MDR). The catalyst containing a single-phase oxide synthesized in the presence of acetylacetone exhibited much higher activity, selectivity and coking stability.",
keywords = "acetylacetone, carbon dioxide reforming of methane, Ce–Zr mixed oxides, supercritical synthesis",
author = "Smirnova, {M. Yu} and Pavlova, {S. N.} and Krieger, {T. A.} and Bespalko, {Yu N.} and Anikeev, {V. I.} and Chesalov, {Yu A.} and Kaichev, {V. V.} and Mezentseva, {N. V.} and Sadykov, {V. A.}",
note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",
year = "2017",
month = dec,
day = "1",
doi = "10.1134/S1990793117080103",
language = "English",
volume = "11",
pages = "1312--1321",
journal = "Russian Journal of Physical Chemistry B",
issn = "1990-7931",
publisher = "PLEIADES PUBLISHING INC",
number = "8",

}

RIS

TY - JOUR

T1 - The Synthesis of Ce1 – xZrxO2 Oxides in Supercritical Alcohols and Catalysts for Carbon Dioxide Reforming of Methane on Their Basis

AU - Smirnova, M. Yu

AU - Pavlova, S. N.

AU - Krieger, T. A.

AU - Bespalko, Yu N.

AU - Anikeev, V. I.

AU - Chesalov, Yu A.

AU - Kaichev, V. V.

AU - Mezentseva, N. V.

AU - Sadykov, V. A.

N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - The effect of the features of starting zirconium compounds on the solvothermal synthesis of mixed Ce–Zr oxides in a flow reactor using ethanol and isopropanol as a supercritical medium was studied. The phase composition and structural properties of the synthesized samples were investigated using X-ray diffraction analysis (XRD) and Raman spectroscopy. The morphology and textural properties were studied by transmission electron microscopy (TEM) and thermal desorption of nitrogen. It was found that the use of zirconium oxychloride or acetate as the starting substances results in the formation of a mixture of phases enriched with cerium or zirconium, whereas the use of zirconium butoxide with acetylacetone as a complexing agent allows obtaining a homogeneous solid solution. The catalytic properties of the synthesized oxides with supported Ni were tested in methane dry reforming (MDR). The catalyst containing a single-phase oxide synthesized in the presence of acetylacetone exhibited much higher activity, selectivity and coking stability.

AB - The effect of the features of starting zirconium compounds on the solvothermal synthesis of mixed Ce–Zr oxides in a flow reactor using ethanol and isopropanol as a supercritical medium was studied. The phase composition and structural properties of the synthesized samples were investigated using X-ray diffraction analysis (XRD) and Raman spectroscopy. The morphology and textural properties were studied by transmission electron microscopy (TEM) and thermal desorption of nitrogen. It was found that the use of zirconium oxychloride or acetate as the starting substances results in the formation of a mixture of phases enriched with cerium or zirconium, whereas the use of zirconium butoxide with acetylacetone as a complexing agent allows obtaining a homogeneous solid solution. The catalytic properties of the synthesized oxides with supported Ni were tested in methane dry reforming (MDR). The catalyst containing a single-phase oxide synthesized in the presence of acetylacetone exhibited much higher activity, selectivity and coking stability.

KW - acetylacetone

KW - carbon dioxide reforming of methane

KW - Ce–Zr mixed oxides

KW - supercritical synthesis

UR - http://www.scopus.com/inward/record.url?scp=85043471584&partnerID=8YFLogxK

U2 - 10.1134/S1990793117080103

DO - 10.1134/S1990793117080103

M3 - Article

AN - SCOPUS:85043471584

VL - 11

SP - 1312

EP - 1321

JO - Russian Journal of Physical Chemistry B

JF - Russian Journal of Physical Chemistry B

SN - 1990-7931

IS - 8

ER -

ID: 10521761