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The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations. / Pronin, Aleksei S.; Gayfulin, Yakov M.; Smolentsev, Anton I. et al.

In: Inorganic Chemistry, Vol. 59, No. 14, 20.07.2020, p. 9710–9717.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronin, AS, Gayfulin, YM, Smolentsev, AI, Kozlova, SG, Yanshole, VV & Mironov, YV 2020, 'The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations', Inorganic Chemistry, vol. 59, no. 14, pp. 9710–9717. https://doi.org/10.1021/acs.inorgchem.0c00956

APA

Pronin, A. S., Gayfulin, Y. M., Smolentsev, A. I., Kozlova, S. G., Yanshole, V. V., & Mironov, Y. V. (2020). The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations. Inorganic Chemistry, 59(14), 9710–9717. https://doi.org/10.1021/acs.inorgchem.0c00956

Vancouver

Pronin AS, Gayfulin YM, Smolentsev AI, Kozlova SG, Yanshole VV, Mironov YV. The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations. Inorganic Chemistry. 2020 Jul 20;59(14):9710–9717. doi: 10.1021/acs.inorgchem.0c00956

Author

Pronin, Aleksei S. ; Gayfulin, Yakov M. ; Smolentsev, Anton I. et al. / The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations. In: Inorganic Chemistry. 2020 ; Vol. 59, No. 14. pp. 9710–9717.

BibTeX

@article{c69248078cb24c73a5e0c3b31cb6e2bf,
title = "The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations",
abstract = "A reaction between ReI3 and KCN at elevated temperature led to the formation of the new cyanometalate cluster anion [{Re4(μ3-CCN)4}(CN)12]8- (1). The anion contains μ3-CCN3- ligands, which are stabilized by the coordination to the triangular faces of the tetrahedral {Re4} metallocluster in a μ3 mode. The compound crystallized as a potassium salt, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It was shown that μ3-CCN3- ligands are ambidentate and can interact with transition-metal cations similarly to terminal CN groups, resulting in the polymer framework formation.",
keywords = "ORDER REGULAR APPROXIMATION, CRYSTAL-STRUCTURE, STATISTICAL AVERAGE, ELECTRON-DENSITY, ENERGY, COMPLEXES, POLYMERS, MODEL, CORE, CHAIN",
author = "Pronin, {Aleksei S.} and Gayfulin, {Yakov M.} and Smolentsev, {Anton I.} and Kozlova, {Svetlana G.} and Yanshole, {Vadim V.} and Mironov, {Yuri V.}",
year = "2020",
month = jul,
day = "20",
doi = "10.1021/acs.inorgchem.0c00956",
language = "English",
volume = "59",
pages = "9710–9717",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "14",

}

RIS

TY - JOUR

T1 - The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8-with Inner (μ3-CCN)3-Ligands and Its Features in Coordination of Cu2+Cations

AU - Pronin, Aleksei S.

AU - Gayfulin, Yakov M.

AU - Smolentsev, Anton I.

AU - Kozlova, Svetlana G.

AU - Yanshole, Vadim V.

AU - Mironov, Yuri V.

PY - 2020/7/20

Y1 - 2020/7/20

N2 - A reaction between ReI3 and KCN at elevated temperature led to the formation of the new cyanometalate cluster anion [{Re4(μ3-CCN)4}(CN)12]8- (1). The anion contains μ3-CCN3- ligands, which are stabilized by the coordination to the triangular faces of the tetrahedral {Re4} metallocluster in a μ3 mode. The compound crystallized as a potassium salt, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It was shown that μ3-CCN3- ligands are ambidentate and can interact with transition-metal cations similarly to terminal CN groups, resulting in the polymer framework formation.

AB - A reaction between ReI3 and KCN at elevated temperature led to the formation of the new cyanometalate cluster anion [{Re4(μ3-CCN)4}(CN)12]8- (1). The anion contains μ3-CCN3- ligands, which are stabilized by the coordination to the triangular faces of the tetrahedral {Re4} metallocluster in a μ3 mode. The compound crystallized as a potassium salt, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It was shown that μ3-CCN3- ligands are ambidentate and can interact with transition-metal cations similarly to terminal CN groups, resulting in the polymer framework formation.

KW - ORDER REGULAR APPROXIMATION

KW - CRYSTAL-STRUCTURE

KW - STATISTICAL AVERAGE

KW - ELECTRON-DENSITY

KW - ENERGY

KW - COMPLEXES

KW - POLYMERS

KW - MODEL

KW - CORE

KW - CHAIN

UR - http://www.scopus.com/inward/record.url?scp=85088495671&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.0c00956

DO - 10.1021/acs.inorgchem.0c00956

M3 - Article

C2 - 32644787

AN - SCOPUS:85088495671

VL - 59

SP - 9710

EP - 9717

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 14

ER -

ID: 24868367