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The oxidative dehydrogenation of ethane : Convectional vs microwave heating of Ba - containing catalysts. / Bolotov, Vasiliy A.; Chesnokov, Vladimir V.; Tanashev, Yuriy Y. et al.

In: Chemical Engineering and Processing - Process Intensification, Vol. 129, 01.07.2018, p. 103-108.

Research output: Contribution to journal › Article › peer-review

Harvard

Bolotov, VA, Chesnokov, VV, Tanashev, YY & Parmon, VN 2018, 'The oxidative dehydrogenation of ethane: Convectional vs microwave heating of Ba - containing catalysts', Chemical Engineering and Processing - Process Intensification, vol. 129, pp. 103-108. https://doi.org/10.1016/j.cep.2018.05.006

APA

Bolotov, V. A., Chesnokov, V. V., Tanashev, Y. Y., & Parmon, V. N. (2018). The oxidative dehydrogenation of ethane: Convectional vs microwave heating of Ba - containing catalysts. Chemical Engineering and Processing - Process Intensification, 129, 103-108. https://doi.org/10.1016/j.cep.2018.05.006

Vancouver

Bolotov VA, Chesnokov VV, Tanashev YY, Parmon VN. The oxidative dehydrogenation of ethane: Convectional vs microwave heating of Ba - containing catalysts. Chemical Engineering and Processing - Process Intensification. 2018 Jul 1;129:103-108. doi: 10.1016/j.cep.2018.05.006

Author

Bolotov, Vasiliy A. ; Chesnokov, Vladimir V. ; Tanashev, Yuriy Y. et al. / The oxidative dehydrogenation of ethane : Convectional vs microwave heating of Ba - containing catalysts. In: Chemical Engineering and Processing - Process Intensification. 2018 ; Vol. 129. pp. 103-108.

BibTeX

@article{2632e368ed554a34b9525c11b65e33ed,
title = "The oxidative dehydrogenation of ethane: Convectional vs microwave heating of Ba - containing catalysts",
abstract = "The influence of heating method on oxidative dehydrogenation of ethane (ODE) over BaO–CeO2–ZrO2 and BaCl2–TiO2–SnO2 catalysts was studied. Noticeable differences were observed at the ODE under conventional heating and microwave (MW) heating when only the granules of catalyst but not the surrounding gas mixture are heated. The MW heating of the BaO–CeO2–ZrO2 catalyst resulted in a decrease in selectivity to carbon dioxide and in an increase in selectivity to carbon monoxide. Supposedly, the conventional heating led to gas-phase complete oxidation of carbon monoxide to carbon dioxide. The MW heating of the BaCl2–TiO2–SnO2 catalyst suppressed almost completely parallel and consecutive deep oxidation of ethylene but selectivity to ethylene increased remarkably. The study demonstrates potentialities of the MW heating in enhancing the efficiency of ODE. The observed phenomena can be accounted for the effective “quenching” of the target ODE product via inhibiting undesirable homogeneous reactions in the gas phase.",
keywords = "Catalyst, Ethane, Microwave heating, Oxidative dehydrogenation",
author = "Bolotov, {Vasiliy A.} and Chesnokov, {Vladimir V.} and Tanashev, {Yuriy Y.} and Parmon, {Valentin N.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = jul,
day = "1",
doi = "10.1016/j.cep.2018.05.006",
language = "English",
volume = "129",
pages = "103--108",
journal = "Chemical Engineering and Processing - Process Intensification",
issn = "0255-2701",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - The oxidative dehydrogenation of ethane

T2 - Convectional vs microwave heating of Ba - containing catalysts

AU - Bolotov, Vasiliy A.

AU - Chesnokov, Vladimir V.

AU - Tanashev, Yuriy Y.

AU - Parmon, Valentin N.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - The influence of heating method on oxidative dehydrogenation of ethane (ODE) over BaO–CeO2–ZrO2 and BaCl2–TiO2–SnO2 catalysts was studied. Noticeable differences were observed at the ODE under conventional heating and microwave (MW) heating when only the granules of catalyst but not the surrounding gas mixture are heated. The MW heating of the BaO–CeO2–ZrO2 catalyst resulted in a decrease in selectivity to carbon dioxide and in an increase in selectivity to carbon monoxide. Supposedly, the conventional heating led to gas-phase complete oxidation of carbon monoxide to carbon dioxide. The MW heating of the BaCl2–TiO2–SnO2 catalyst suppressed almost completely parallel and consecutive deep oxidation of ethylene but selectivity to ethylene increased remarkably. The study demonstrates potentialities of the MW heating in enhancing the efficiency of ODE. The observed phenomena can be accounted for the effective “quenching” of the target ODE product via inhibiting undesirable homogeneous reactions in the gas phase.

AB - The influence of heating method on oxidative dehydrogenation of ethane (ODE) over BaO–CeO2–ZrO2 and BaCl2–TiO2–SnO2 catalysts was studied. Noticeable differences were observed at the ODE under conventional heating and microwave (MW) heating when only the granules of catalyst but not the surrounding gas mixture are heated. The MW heating of the BaO–CeO2–ZrO2 catalyst resulted in a decrease in selectivity to carbon dioxide and in an increase in selectivity to carbon monoxide. Supposedly, the conventional heating led to gas-phase complete oxidation of carbon monoxide to carbon dioxide. The MW heating of the BaCl2–TiO2–SnO2 catalyst suppressed almost completely parallel and consecutive deep oxidation of ethylene but selectivity to ethylene increased remarkably. The study demonstrates potentialities of the MW heating in enhancing the efficiency of ODE. The observed phenomena can be accounted for the effective “quenching” of the target ODE product via inhibiting undesirable homogeneous reactions in the gas phase.

KW - Catalyst

KW - Ethane

KW - Microwave heating

KW - Oxidative dehydrogenation

UR - http://www.scopus.com/inward/record.url?scp=85047152308&partnerID=8YFLogxK

U2 - 10.1016/j.cep.2018.05.006

DO - 10.1016/j.cep.2018.05.006

M3 - Article

AN - SCOPUS:85047152308

VL - 129

SP - 103

EP - 108

JO - Chemical Engineering and Processing - Process Intensification

JF - Chemical Engineering and Processing - Process Intensification

SN - 0255-2701

ER -

ID: 13488101