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The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass. / Adonin, Nicolay Yu; Prikhod'ko, Sergey A.; Shabalin, Anton Yu et al.

In: Journal of Catalysis, Vol. 338, 2016, p. 143-153.

Research output: Contribution to journal › Article › peer-review

Harvard

Adonin, NY, Prikhod'ko, SA, Shabalin, AY, Prosvirin, IP, Zaikovskii, VI, Kochubey, DI, Zyuzin, DA, Parmon, VN, Monin, EA, Bykova, IA, Martynov, PO, Rusakov, SL & Storozhenko, PA 2016, 'The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass', Journal of Catalysis, vol. 338, pp. 143-153. https://doi.org/10.1016/j.jcat.2016.03.012

APA

Adonin, N. Y., Prikhod'ko, S. A., Shabalin, A. Y., Prosvirin, I. P., Zaikovskii, V. I., Kochubey, D. I., Zyuzin, D. A., Parmon, V. N., Monin, E. A., Bykova, I. A., Martynov, P. O., Rusakov, S. L., & Storozhenko, P. A. (2016). The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass. Journal of Catalysis, 338, 143-153. https://doi.org/10.1016/j.jcat.2016.03.012

Vancouver

Adonin NY, Prikhod'ko SA, Shabalin AY, Prosvirin IP, Zaikovskii VI, Kochubey DI et al. The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass. Journal of Catalysis. 2016;338:143-153. doi: 10.1016/j.jcat.2016.03.012

Author

Adonin, Nicolay Yu ; Prikhod'ko, Sergey A. ; Shabalin, Anton Yu et al. / The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass. In: Journal of Catalysis. 2016 ; Vol. 338. pp. 143-153.

BibTeX

@article{5703b6b5bf5141f8be7aa0b49118b51c,
title = "The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass",
abstract = "The paper presents comprehensive studies on the process of the copper-containing active sites formation which are needed for the “direct” synthesis of trialkoxysilanes at the interaction of alcohols with a silicon-based contact mass. These sites are formed during a two step consequent pretreatment of the initial contact mass by hydrogen and argon flow. The so activated samples of contact mass were investigated using HAADF-STEM EDX, EXAFS, XPS and XRD methods. The role of each step of the activation is disclosed. Participation of topochemical and heterogeneous chemical reactions as well as processes of diffusion and sorption–desorption during the active sites formation was found. Based on the retrieved data a new mechanism for the formation of the active sites on the surface of silicon during the activation of the contact mass for the “direct” synthesis of trialkoxysilanes is suggested.",
keywords = "Active sites formation, Copper catalyst, Direct synthesis, Mechanism of active sites formation, Silane, Silicon",
author = "Adonin, {Nicolay Yu} and Prikhod'ko, {Sergey A.} and Shabalin, {Anton Yu} and Prosvirin, {Igor P.} and Zaikovskii, {Vladimir I.} and Kochubey, {Dmitry I.} and Zyuzin, {Dmitry A.} and Parmon, {Valentin N.} and Monin, {Evgeny A.} and Bykova, {Irina A.} and Martynov, {Petr O.} and Rusakov, {Sergey L.} and Storozhenko, {Pavel A.}",
year = "2016",
doi = "10.1016/j.jcat.2016.03.012",
language = "English",
volume = "338",
pages = "143--153",
journal = "Journal of Catalysis",
issn = "0021-9517",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass

AU - Adonin, Nicolay Yu

AU - Prikhod'ko, Sergey A.

AU - Shabalin, Anton Yu

AU - Prosvirin, Igor P.

AU - Zaikovskii, Vladimir I.

AU - Kochubey, Dmitry I.

AU - Zyuzin, Dmitry A.

AU - Parmon, Valentin N.

AU - Monin, Evgeny A.

AU - Bykova, Irina A.

AU - Martynov, Petr O.

AU - Rusakov, Sergey L.

AU - Storozhenko, Pavel A.

PY - 2016

Y1 - 2016

N2 - The paper presents comprehensive studies on the process of the copper-containing active sites formation which are needed for the “direct” synthesis of trialkoxysilanes at the interaction of alcohols with a silicon-based contact mass. These sites are formed during a two step consequent pretreatment of the initial contact mass by hydrogen and argon flow. The so activated samples of contact mass were investigated using HAADF-STEM EDX, EXAFS, XPS and XRD methods. The role of each step of the activation is disclosed. Participation of topochemical and heterogeneous chemical reactions as well as processes of diffusion and sorption–desorption during the active sites formation was found. Based on the retrieved data a new mechanism for the formation of the active sites on the surface of silicon during the activation of the contact mass for the “direct” synthesis of trialkoxysilanes is suggested.

AB - The paper presents comprehensive studies on the process of the copper-containing active sites formation which are needed for the “direct” synthesis of trialkoxysilanes at the interaction of alcohols with a silicon-based contact mass. These sites are formed during a two step consequent pretreatment of the initial contact mass by hydrogen and argon flow. The so activated samples of contact mass were investigated using HAADF-STEM EDX, EXAFS, XPS and XRD methods. The role of each step of the activation is disclosed. Participation of topochemical and heterogeneous chemical reactions as well as processes of diffusion and sorption–desorption during the active sites formation was found. Based on the retrieved data a new mechanism for the formation of the active sites on the surface of silicon during the activation of the contact mass for the “direct” synthesis of trialkoxysilanes is suggested.

KW - Active sites formation

KW - Copper catalyst

KW - Direct synthesis

KW - Mechanism of active sites formation

KW - Silane

KW - Silicon

UR - http://www.scopus.com/inward/record.url?scp=85015618977&partnerID=8YFLogxK

U2 - 10.1016/j.jcat.2016.03.012

DO - 10.1016/j.jcat.2016.03.012

M3 - Article

AN - SCOPUS:85015618977

VL - 338

SP - 143

EP - 153

JO - Journal of Catalysis

JF - Journal of Catalysis

SN - 0021-9517

ER -

ID: 25412688