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Template technique for synthesis of CaO-based sorbents with designed macroporous structure. / Derevschikov, Vladimir; Semeykina, Victoria; Bitar, Jasmine et al.

In: Microporous and Mesoporous Materials, Vol. 238, 01.01.2017, p. 56-61.

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Derevschikov V, Semeykina V, Bitar J, Parkhomchuk E, Okunev A. Template technique for synthesis of CaO-based sorbents with designed macroporous structure. Microporous and Mesoporous Materials. 2017 Jan 1;238:56-61. doi: 10.1016/j.micromeso.2016.02.032

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Derevschikov, Vladimir ; Semeykina, Victoria ; Bitar, Jasmine et al. / Template technique for synthesis of CaO-based sorbents with designed macroporous structure. In: Microporous and Mesoporous Materials. 2017 ; Vol. 238. pp. 56-61.

BibTeX

@article{5f1deb72ef1d449fbe99ee4c5cfb958f,
title = "Template technique for synthesis of CaO-based sorbents with designed macroporous structure",
abstract = "A polymeric template consisting of polystyrene microbeads was used to provide the macroporous structure of synthesized CaO-based sorbents. It was found that the pore size distribution of prepared and calcined sorbents drastically depends on the amount and particle size of the template used, as well as on the sorbent preparation conditions. The macroporous structure formed after the template removal significantly increases the rate of both recarbonation and decomposition reactions. The decomposition rate of the sorbent produced from a 40% templated composite was an order of magnitude higher than the rate of a reference sample produced in the absence of the template. In this way, the template approach seems to be a perspective technique to prepare CaO-based sorbents with enhanced recarbonation/decomposition performance.",
keywords = "Calcium oxide, Carbon capture, Porous structure, Regenerable sorbent, Template, CAPACITY, POSTCOMBUSTION CO2 CAPTURE, PERFORMANCE, BIOMASS, CALCIUM-OXIDE, SORPTION, DECOMPOSITION",
author = "Vladimir Derevschikov and Victoria Semeykina and Jasmine Bitar and Ekaterina Parkhomchuk and Alexey Okunev",
year = "2017",
month = jan,
day = "1",
doi = "10.1016/j.micromeso.2016.02.032",
language = "English",
volume = "238",
pages = "56--61",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Template technique for synthesis of CaO-based sorbents with designed macroporous structure

AU - Derevschikov, Vladimir

AU - Semeykina, Victoria

AU - Bitar, Jasmine

AU - Parkhomchuk, Ekaterina

AU - Okunev, Alexey

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A polymeric template consisting of polystyrene microbeads was used to provide the macroporous structure of synthesized CaO-based sorbents. It was found that the pore size distribution of prepared and calcined sorbents drastically depends on the amount and particle size of the template used, as well as on the sorbent preparation conditions. The macroporous structure formed after the template removal significantly increases the rate of both recarbonation and decomposition reactions. The decomposition rate of the sorbent produced from a 40% templated composite was an order of magnitude higher than the rate of a reference sample produced in the absence of the template. In this way, the template approach seems to be a perspective technique to prepare CaO-based sorbents with enhanced recarbonation/decomposition performance.

AB - A polymeric template consisting of polystyrene microbeads was used to provide the macroporous structure of synthesized CaO-based sorbents. It was found that the pore size distribution of prepared and calcined sorbents drastically depends on the amount and particle size of the template used, as well as on the sorbent preparation conditions. The macroporous structure formed after the template removal significantly increases the rate of both recarbonation and decomposition reactions. The decomposition rate of the sorbent produced from a 40% templated composite was an order of magnitude higher than the rate of a reference sample produced in the absence of the template. In this way, the template approach seems to be a perspective technique to prepare CaO-based sorbents with enhanced recarbonation/decomposition performance.

KW - Calcium oxide

KW - Carbon capture

KW - Porous structure

KW - Regenerable sorbent

KW - Template

KW - CAPACITY

KW - POSTCOMBUSTION CO2 CAPTURE

KW - PERFORMANCE

KW - BIOMASS

KW - CALCIUM-OXIDE

KW - SORPTION

KW - DECOMPOSITION

UR - http://www.scopus.com/inward/record.url?scp=84993960706&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2016.02.032

DO - 10.1016/j.micromeso.2016.02.032

M3 - Article

AN - SCOPUS:84993960706

VL - 238

SP - 56

EP - 61

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

SN - 1387-1811

ER -

ID: 10321027