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Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n. / Muravieva, Viktoria K.; Loginov, Ivan P.; Sukhikh, Taisiya S. et al.

In: Inorganic Chemistry, Vol. 60, No. 12, 21.06.2021, p. 8838-8850.

Research output: Contribution to journal › Article › peer-review

Harvard

Muravieva, VK, Loginov, IP, Sukhikh, TS, Ryzhikov, MR, Yanshole, VV, Nadolinny, VA, Dorcet, V, Cordier, S & Naumov, NG 2021, 'Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n', Inorganic Chemistry, vol. 60, no. 12, pp. 8838-8850. https://doi.org/10.1021/acs.inorgchem.1c00763

APA

Muravieva, V. K., Loginov, I. P., Sukhikh, T. S., Ryzhikov, M. R., Yanshole, V. V., Nadolinny, V. A., Dorcet, V., Cordier, S., & Naumov, N. G. (2021). Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n. Inorganic Chemistry, 60(12), 8838-8850. https://doi.org/10.1021/acs.inorgchem.1c00763

Vancouver

Muravieva VK, Loginov IP, Sukhikh TS, Ryzhikov MR, Yanshole VV, Nadolinny VA et al. Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n. Inorganic Chemistry. 2021 Jun 21;60(12):8838-8850. doi: 10.1021/acs.inorgchem.1c00763

Author

Muravieva, Viktoria K. ; Loginov, Ivan P. ; Sukhikh, Taisiya S. et al. / Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n. In: Inorganic Chemistry. 2021 ; Vol. 60, No. 12. pp. 8838-8850.

BibTeX

@article{aca96d05f60048e8b640f8cb189761e1,
title = "Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n",
abstract = "The heterometallic cluster-based compound K5[Re5MoSe8(CN)6] was obtained by high-temperature reaction from a mixture of ReSe2 and MoSe2 in molten potassium cyanide. The redox behavior of the [Re5MoSe8(CN)6]5- cluster anion was studied by cyclic voltammetry in aqueous and organic media showing two reversible one-electron-redox transitions with E1/2 of -0.462 and 0.357 V versus Ag/AgCl in CH3CN. Aqueous media potentials were found to be noticeably shifted to higher values because of solvation. Chemically accessible potentials allowed us to structurally isolate and characterize the [Re5MoSe8(CN)6]n (n = 3-, 4-, and 5-) cluster complex in several charge states with corresponding cluster skeletal electron (CSE) numbers ranging from 24 to 22. The electronic absorption of the [Re5MoSe8(CN)6]n cluster complex varies significantly upon a change of the CSE number, especially in the visible and near-IR regions. The local cluster core distortion upon electron removal was confirmed by density functional theory calculation, while the overall geometry of the cluster anion remained practically unaltered. ",
author = "Muravieva, {Viktoria K.} and Loginov, {Ivan P.} and Sukhikh, {Taisiya S.} and Ryzhikov, {Maxim R.} and Yanshole, {Vadim V.} and Nadolinny, {Vladimir A.} and Vincent Dorcet and St{\'e}phane Cordier and Naumov, {Nikolay G.}",
note = "Funding Information: This work was supported by a grant from the Russian Science Foundation (Grant 20-73-00339). The authors thank the Collective Usage Center and XRD Facility of NIIC SB RAS for data collection. The authors acknowledge the International Research Project CLUSPOM between France and Russia and the “Centre de Diffractom{\'e}trie X” of the Institute of Chemical Science of Rennes. The authors collective greatly thank A. A. Ulantikov and I. V. Ushina (NIIC) for measurements and analysis of CV and DRS. V.Y. thanks the Ministry of Science and Higher Education of the Russian Foundation for access to MS equipment. Funding Information: This work was supported by a grant from the Russian Science Foundation (Grant 20-73-00339). The authors thank the Collective Usage Center and XRD Facility of NIIC SB RAS for data collection. The authors acknowledge the International Research Project CLUSPOM between France and Russia and the {"}Centre de Diffractome?trie X{"} of the Institute of Chemical Science of Rennes. The authors collective greatly thank A. A. Ulantikov and I. V. Ushina (NIIC) for measurements and analysis of CV and DRS. V.Y. thanks the Ministry of Science and Higher Education of the Russian Foundation for access to MS equipment. Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",
year = "2021",
month = jun,
day = "21",
doi = "10.1021/acs.inorgchem.1c00763",
language = "English",
volume = "60",
pages = "8838--8850",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "12",

}

RIS

TY - JOUR

T1 - Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n

AU - Muravieva, Viktoria K.

AU - Loginov, Ivan P.

AU - Sukhikh, Taisiya S.

AU - Ryzhikov, Maxim R.

AU - Yanshole, Vadim V.

AU - Nadolinny, Vladimir A.

AU - Dorcet, Vincent

AU - Cordier, Stéphane

AU - Naumov, Nikolay G.

N1 - Funding Information: This work was supported by a grant from the Russian Science Foundation (Grant 20-73-00339). The authors thank the Collective Usage Center and XRD Facility of NIIC SB RAS for data collection. The authors acknowledge the International Research Project CLUSPOM between France and Russia and the “Centre de Diffractométrie X” of the Institute of Chemical Science of Rennes. The authors collective greatly thank A. A. Ulantikov and I. V. Ushina (NIIC) for measurements and analysis of CV and DRS. V.Y. thanks the Ministry of Science and Higher Education of the Russian Foundation for access to MS equipment. Funding Information: This work was supported by a grant from the Russian Science Foundation (Grant 20-73-00339). The authors thank the Collective Usage Center and XRD Facility of NIIC SB RAS for data collection. The authors acknowledge the International Research Project CLUSPOM between France and Russia and the "Centre de Diffractome?trie X" of the Institute of Chemical Science of Rennes. The authors collective greatly thank A. A. Ulantikov and I. V. Ushina (NIIC) for measurements and analysis of CV and DRS. V.Y. thanks the Ministry of Science and Higher Education of the Russian Foundation for access to MS equipment. Publisher Copyright: © 2021 American Chemical Society.

PY - 2021/6/21

Y1 - 2021/6/21

N2 - The heterometallic cluster-based compound K5[Re5MoSe8(CN)6] was obtained by high-temperature reaction from a mixture of ReSe2 and MoSe2 in molten potassium cyanide. The redox behavior of the [Re5MoSe8(CN)6]5- cluster anion was studied by cyclic voltammetry in aqueous and organic media showing two reversible one-electron-redox transitions with E1/2 of -0.462 and 0.357 V versus Ag/AgCl in CH3CN. Aqueous media potentials were found to be noticeably shifted to higher values because of solvation. Chemically accessible potentials allowed us to structurally isolate and characterize the [Re5MoSe8(CN)6]n (n = 3-, 4-, and 5-) cluster complex in several charge states with corresponding cluster skeletal electron (CSE) numbers ranging from 24 to 22. The electronic absorption of the [Re5MoSe8(CN)6]n cluster complex varies significantly upon a change of the CSE number, especially in the visible and near-IR regions. The local cluster core distortion upon electron removal was confirmed by density functional theory calculation, while the overall geometry of the cluster anion remained practically unaltered.

AB - The heterometallic cluster-based compound K5[Re5MoSe8(CN)6] was obtained by high-temperature reaction from a mixture of ReSe2 and MoSe2 in molten potassium cyanide. The redox behavior of the [Re5MoSe8(CN)6]5- cluster anion was studied by cyclic voltammetry in aqueous and organic media showing two reversible one-electron-redox transitions with E1/2 of -0.462 and 0.357 V versus Ag/AgCl in CH3CN. Aqueous media potentials were found to be noticeably shifted to higher values because of solvation. Chemically accessible potentials allowed us to structurally isolate and characterize the [Re5MoSe8(CN)6]n (n = 3-, 4-, and 5-) cluster complex in several charge states with corresponding cluster skeletal electron (CSE) numbers ranging from 24 to 22. The electronic absorption of the [Re5MoSe8(CN)6]n cluster complex varies significantly upon a change of the CSE number, especially in the visible and near-IR regions. The local cluster core distortion upon electron removal was confirmed by density functional theory calculation, while the overall geometry of the cluster anion remained practically unaltered.

UR - http://www.scopus.com/inward/record.url?scp=85108372060&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.1c00763

DO - 10.1021/acs.inorgchem.1c00763

M3 - Article

C2 - 34056900

AN - SCOPUS:85108372060

VL - 60

SP - 8838

EP - 8850

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 12

ER -

ID: 34030602