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Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane. / Tuscher, Lars; Helling, Christoph; Ganesamoorthy, Chelladurai et al.

In: Chemistry - A European Journal, Vol. 23, No. 50, 07.09.2017, p. 12297-12304.

Research output: Contribution to journal › Article › peer-review

Harvard

Tuscher, L, Helling, C, Ganesamoorthy, C, Krüger, J, Wölper, C, Frank, W, Nizovtsev, AS & Schulz, S 2017, 'Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane', Chemistry - A European Journal, vol. 23, no. 50, pp. 12297-12304. https://doi.org/10.1002/chem.201701248

APA

Tuscher, L., Helling, C., Ganesamoorthy, C., Krüger, J., Wölper, C., Frank, W., Nizovtsev, A. S., & Schulz, S. (2017). Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane. Chemistry - A European Journal, 23(50), 12297-12304. https://doi.org/10.1002/chem.201701248

Vancouver

Tuscher L, Helling C, Ganesamoorthy C, Krüger J, Wölper C, Frank W et al. Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane. Chemistry - A European Journal. 2017 Sept 7;23(50):12297-12304. doi: 10.1002/chem.201701248

Author

Tuscher, Lars ; Helling, Christoph ; Ganesamoorthy, Chelladurai et al. / Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane. In: Chemistry - A European Journal. 2017 ; Vol. 23, No. 50. pp. 12297-12304.

BibTeX

@article{1db8832c55294482a513d1c5bfa68c5d,
title = "Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane",
abstract = "Monovalent gallanediyl LGa {L=HC[C(Me)N(2,6-iPr2C6H3)]2} reacts with SbX3 to form the Ga-substituted distibenes [(LGaX)2Sb2] (X=NMeEt 1, Cl 2). Upon heating, 2 reacts to the bicyclo[1.1.0]butane analogue [(LGaCl)2(μ,η1:1-Sb4)] 3 containing a [Sb4]2− dianion. Moreover, 2 reacts with Li amides LiNR2 in salt elimination reactions that form the corresponding amido-substituted compounds 1 and [(LGaNMe2)2Sb2] 4, whereas reactions of 4 and [(LGaNMe2)2(μ,η1:1-Sb4)] 5 with two equivalents of GaCl3 resulted in the formation of 2 and 3, respectively. 1, 2 and 3 were characterized by 1H and 13C NMR spectroscopy, elemental analysis, and single crystal X-ray diffraction. In addition, their bonding situation was analyzed by quantum chemical calculations.",
keywords = "cluster compounds, main-group elements, polystibide, subvalent compounds, PHOSPHORUS, ACTIVATION, APPROXIMATION, STABILIZATION, ELECTRON LOCALIZATION, FUNCTIONALIZATION, ELEMENTS, CAGE COMPOUNDS, P-4, BOND",
author = "Lars Tuscher and Christoph Helling and Chelladurai Ganesamoorthy and Julia Kr{\"u}ger and Christoph W{\"o}lper and Walter Frank and Nizovtsev, {Anton S.} and Stephan Schulz",
note = "{\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2017",
month = sep,
day = "7",
doi = "10.1002/chem.201701248",
language = "English",
volume = "23",
pages = "12297--12304",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "50",

}

RIS

TY - JOUR

T1 - Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane

AU - Tuscher, Lars

AU - Helling, Christoph

AU - Ganesamoorthy, Chelladurai

AU - Krüger, Julia

AU - Wölper, Christoph

AU - Frank, Walter

AU - Nizovtsev, Anton S.

AU - Schulz, Stephan

N1 - © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2017/9/7

Y1 - 2017/9/7

N2 - Monovalent gallanediyl LGa {L=HC[C(Me)N(2,6-iPr2C6H3)]2} reacts with SbX3 to form the Ga-substituted distibenes [(LGaX)2Sb2] (X=NMeEt 1, Cl 2). Upon heating, 2 reacts to the bicyclo[1.1.0]butane analogue [(LGaCl)2(μ,η1:1-Sb4)] 3 containing a [Sb4]2− dianion. Moreover, 2 reacts with Li amides LiNR2 in salt elimination reactions that form the corresponding amido-substituted compounds 1 and [(LGaNMe2)2Sb2] 4, whereas reactions of 4 and [(LGaNMe2)2(μ,η1:1-Sb4)] 5 with two equivalents of GaCl3 resulted in the formation of 2 and 3, respectively. 1, 2 and 3 were characterized by 1H and 13C NMR spectroscopy, elemental analysis, and single crystal X-ray diffraction. In addition, their bonding situation was analyzed by quantum chemical calculations.

AB - Monovalent gallanediyl LGa {L=HC[C(Me)N(2,6-iPr2C6H3)]2} reacts with SbX3 to form the Ga-substituted distibenes [(LGaX)2Sb2] (X=NMeEt 1, Cl 2). Upon heating, 2 reacts to the bicyclo[1.1.0]butane analogue [(LGaCl)2(μ,η1:1-Sb4)] 3 containing a [Sb4]2− dianion. Moreover, 2 reacts with Li amides LiNR2 in salt elimination reactions that form the corresponding amido-substituted compounds 1 and [(LGaNMe2)2Sb2] 4, whereas reactions of 4 and [(LGaNMe2)2(μ,η1:1-Sb4)] 5 with two equivalents of GaCl3 resulted in the formation of 2 and 3, respectively. 1, 2 and 3 were characterized by 1H and 13C NMR spectroscopy, elemental analysis, and single crystal X-ray diffraction. In addition, their bonding situation was analyzed by quantum chemical calculations.

KW - cluster compounds

KW - main-group elements

KW - polystibide

KW - subvalent compounds

KW - PHOSPHORUS

KW - ACTIVATION

KW - APPROXIMATION

KW - STABILIZATION

KW - ELECTRON LOCALIZATION

KW - FUNCTIONALIZATION

KW - ELEMENTS

KW - CAGE COMPOUNDS

KW - P-4

KW - BOND

UR - http://www.scopus.com/inward/record.url?scp=85021345078&partnerID=8YFLogxK

U2 - 10.1002/chem.201701248

DO - 10.1002/chem.201701248

M3 - Article

C2 - 28497647

AN - SCOPUS:85021345078

VL - 23

SP - 12297

EP - 12304

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 50

ER -

ID: 9982248