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Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py). / Kostin, Gennadiy A.; Borodin, Alexander O.; Kuratieva, Natalia V. et al.

In: Journal of Molecular Structure, Vol. 1176, 15.01.2019, p. 402-407.

Research output: Contribution to journal › Article › peer-review

Harvard

Kostin, GA, Borodin, AO, Kuratieva, NV, Mikhailov, AA & Plusnin, PE 2019, 'Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py)', Journal of Molecular Structure, vol. 1176, pp. 402-407. https://doi.org/10.1016/j.molstruc.2018.08.105

APA

Kostin, G. A., Borodin, A. O., Kuratieva, N. V., Mikhailov, A. A., & Plusnin, P. E. (2019). Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py). Journal of Molecular Structure, 1176, 402-407. https://doi.org/10.1016/j.molstruc.2018.08.105

Vancouver

Kostin GA, Borodin AO, Kuratieva NV, Mikhailov AA, Plusnin PE. Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py). Journal of Molecular Structure. 2019 Jan 15;1176:402-407. doi: 10.1016/j.molstruc.2018.08.105

Author

Kostin, Gennadiy A. ; Borodin, Alexander O. ; Kuratieva, Natalia V. et al. / Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py). In: Journal of Molecular Structure. 2019 ; Vol. 1176. pp. 402-407.

BibTeX

@article{94fb391542b64b4196c4f67e321f5e7c,
title = "Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py)",
abstract = "The ammonium salt (NH4)2[RuNO(NO2)4OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using 15N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO2)3(Py)OH]- anion with good yield (60%). Crystal structures of the two products (NH4)[RuNO(NO2)3(Py)OH] and NH4[RuNO(NO2)3(NH3)OH] were determined. Both (NH4)2[RuNO(NO2)4OH] and (NH4)[RuNO(NO2)3(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.",
keywords = "Crystal structure, Isomerization, Nitro complexes, Pyridine, Ruthenium nitrosyl, NO, SUBSTITUTION, RU, REACTIVITY, RUTHENIUM NITROSYL, NITROSYL COMPLEXES, LIGANDS, CHEMISTRY, NITRITE, BIOLOGICAL-PROPERTIES",
author = "Kostin, {Gennadiy A.} and Borodin, {Alexander O.} and Kuratieva, {Natalia V.} and Mikhailov, {Artem A.} and Plusnin, {Pavel E.}",
note = "Publisher Copyright: {\textcopyright} 2018",
year = "2019",
month = jan,
day = "15",
doi = "10.1016/j.molstruc.2018.08.105",
language = "English",
volume = "1176",
pages = "402--407",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis, structure and properties of (NH4)2[RuNO(NO2)4OH] and NH4[RuNO(L)(NO2)3OH] (L=NH3, Py)

AU - Kostin, Gennadiy A.

AU - Borodin, Alexander O.

AU - Kuratieva, Natalia V.

AU - Mikhailov, Artem A.

AU - Plusnin, Pavel E.

N1 - Publisher Copyright: © 2018

PY - 2019/1/15

Y1 - 2019/1/15

N2 - The ammonium salt (NH4)2[RuNO(NO2)4OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using 15N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO2)3(Py)OH]- anion with good yield (60%). Crystal structures of the two products (NH4)[RuNO(NO2)3(Py)OH] and NH4[RuNO(NO2)3(NH3)OH] were determined. Both (NH4)2[RuNO(NO2)4OH] and (NH4)[RuNO(NO2)3(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.

AB - The ammonium salt (NH4)2[RuNO(NO2)4OH] was prepared, characterized by thermogravimetric analysis, IR spectroscopy and its molecular and crystal structures were determined. Heating of the salt was investigated in organic solvents (pyridine and acetonitrile) using 15N-NMR spectroscopy and the reaction led to the preparation of the [RuNO(NO2)3(Py)OH]- anion with good yield (60%). Crystal structures of the two products (NH4)[RuNO(NO2)3(Py)OH] and NH4[RuNO(NO2)3(NH3)OH] were determined. Both (NH4)2[RuNO(NO2)4OH] and (NH4)[RuNO(NO2)3(Py)OH] underwent photo-induced (445 nm) linkage isomerization (RueNO to Ru–ON) but the population of the metastable isomer did not exceed 5–7%.

KW - Crystal structure

KW - Isomerization

KW - Nitro complexes

KW - Pyridine

KW - Ruthenium nitrosyl

KW - NO

KW - SUBSTITUTION

KW - RU

KW - REACTIVITY

KW - RUTHENIUM NITROSYL

KW - NITROSYL COMPLEXES

KW - LIGANDS

KW - CHEMISTRY

KW - NITRITE

KW - BIOLOGICAL-PROPERTIES

UR - http://www.scopus.com/inward/record.url?scp=85053770207&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2018.08.105

DO - 10.1016/j.molstruc.2018.08.105

M3 - Article

AN - SCOPUS:85053770207

VL - 1176

SP - 402

EP - 407

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 16703363