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SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE. / Demakov, P. A.; Ovchinnikova, A. A.; Fedin, V. P.

In: Journal of Structural Chemistry, Vol. 64, No. 2, 02.2023, p. 199-207.

Research output: Contribution to journal › Article › peer-review

Harvard

Demakov, PA, Ovchinnikova, AA & Fedin, VP 2023, 'SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE', Journal of Structural Chemistry, vol. 64, no. 2, pp. 199-207. https://doi.org/10.1134/S002247662302004X

APA

Demakov, P. A., Ovchinnikova, A. A., & Fedin, V. P. (2023). SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE. Journal of Structural Chemistry, 64(2), 199-207. https://doi.org/10.1134/S002247662302004X

Vancouver

Demakov PA, Ovchinnikova AA, Fedin VP. SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE. Journal of Structural Chemistry. 2023 Feb;64(2):199-207. doi: 10.1134/S002247662302004X

Author

Demakov, P. A. ; Ovchinnikova, A. A. ; Fedin, V. P. / SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE. In: Journal of Structural Chemistry. 2023 ; Vol. 64, No. 2. pp. 199-207.

BibTeX

@article{51ac9c0aca87459e90e781655542901c,
title = "SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE",
abstract = "The first example of a coordination polymer with a triply charged metal ion is obtained based on the conformationally mobile bridging ligand 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco). Its structure is characterized by single crystal X-ray diffraction. The compound has the formula [La(odabco)3]Cl3·xH2O (1) with a variable hydration number and is composed of six-coordinated octahedral La3+ sites. The 3D cationic coordination lattice of 1 has a primitive cubic (pcu) topology and contains isolated voids with a total specific volume of 28% filled with chloride anions and water molecules. The compound is characterized by powder XRD and elemental analysis. The absence of absorption maxima in the visible and UV ranges up to 270 nm is shown by diffuse reflectance spectroscopy for 1.",
keywords = "N-oxides, lanthanum(III) complexes, metal-organic frameworks, optical properties, single crystal X-ray diffraction analysis, synthesis",
author = "Demakov, {P. A.} and Ovchinnikova, {A. A.} and Fedin, {V. P.}",
note = "The study was carried out within Russian Science Foundation project No. 22-23-20179, https://rscf.ru/project/22-23-20179/ and Project No. r-22 of the Government of the Novosibirsk Oblast{\textquoteright}. Публикация для корректировки.",
year = "2023",
month = feb,
doi = "10.1134/S002247662302004X",
language = "English",
volume = "64",
pages = "199--207",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE

AU - Demakov, P. A.

AU - Ovchinnikova, A. A.

AU - Fedin, V. P.

N1 - The study was carried out within Russian Science Foundation project No. 22-23-20179, https://rscf.ru/project/22-23-20179/ and Project No. r-22 of the Government of the Novosibirsk Oblast’. Публикация для корректировки.

PY - 2023/2

Y1 - 2023/2

N2 - The first example of a coordination polymer with a triply charged metal ion is obtained based on the conformationally mobile bridging ligand 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco). Its structure is characterized by single crystal X-ray diffraction. The compound has the formula [La(odabco)3]Cl3·xH2O (1) with a variable hydration number and is composed of six-coordinated octahedral La3+ sites. The 3D cationic coordination lattice of 1 has a primitive cubic (pcu) topology and contains isolated voids with a total specific volume of 28% filled with chloride anions and water molecules. The compound is characterized by powder XRD and elemental analysis. The absence of absorption maxima in the visible and UV ranges up to 270 nm is shown by diffuse reflectance spectroscopy for 1.

AB - The first example of a coordination polymer with a triply charged metal ion is obtained based on the conformationally mobile bridging ligand 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco). Its structure is characterized by single crystal X-ray diffraction. The compound has the formula [La(odabco)3]Cl3·xH2O (1) with a variable hydration number and is composed of six-coordinated octahedral La3+ sites. The 3D cationic coordination lattice of 1 has a primitive cubic (pcu) topology and contains isolated voids with a total specific volume of 28% filled with chloride anions and water molecules. The compound is characterized by powder XRD and elemental analysis. The absence of absorption maxima in the visible and UV ranges up to 270 nm is shown by diffuse reflectance spectroscopy for 1.

KW - N-oxides

KW - lanthanum(III) complexes

KW - metal-organic frameworks

KW - optical properties

KW - single crystal X-ray diffraction analysis

KW - synthesis

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85149836523&origin=inward&txGid=460d8cad00396a191e6f136826f1d47e

UR - https://www.mendeley.com/catalogue/88f43d63-7e24-3290-b77f-b06be3301b24/

U2 - 10.1134/S002247662302004X

DO - 10.1134/S002247662302004X

M3 - Article

VL - 64

SP - 199

EP - 207

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 59235178