Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol. / Burlov, Anatolii S.; Koshchienko, Yurii V.; Vlasenko, Valery G. et al.
In: ChemistrySelect, Vol. 4, No. 29, 07.08.2019, p. 8652-8654.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol
AU - Burlov, Anatolii S.
AU - Koshchienko, Yurii V.
AU - Vlasenko, Valery G.
AU - Bogomyakov, Artem S.
AU - Kolodina, Alexandra A.
AU - Zubavichus, Yan V.
AU - Lazarenko, Vladimir A.
AU - Khrustalev, Victor N.
N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2019/8/7
Y1 - 2019/8/7
N2 - Two types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.
AB - Two types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.
KW - antiferromagnetic exchange interaction
KW - benzimidazole
KW - binuclear copper complex
KW - X-ray diffraction
KW - CRYSTAL-STRUCTURE
UR - http://www.scopus.com/inward/record.url?scp=85070192055&partnerID=8YFLogxK
U2 - 10.1002/slct.201901186
DO - 10.1002/slct.201901186
M3 - Article
AN - SCOPUS:85070192055
VL - 4
SP - 8652
EP - 8654
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 29
ER -
ID: 25464400