Synthesis, Structure, and Luminescent Properties of a Metal-Organic Framework of Zinc with 1,3-(1,2,4-triazole-1-yl)Adamantane

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Synthesis, Structure, and Luminescent Properties of a Metal-Organic Framework of Zinc with 1,3-(1,2,4-triazole-1-yl)Adamantane. / Makogon, U. A.; Marchenko, R. D.; Pavlov, D. I. et al.

In: Journal of Structural Chemistry, Vol. 66, No. 11, 05.12.2025, p. 2348-2354.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{bd8a839b3f054afc85f3c47c7925a4ac,

title = "Synthesis, Structure, and Luminescent Properties of a Metal-Organic Framework of Zinc with 1,3-(1,2,4-triazole-1-yl)Adamantane",

abstract = "A new [Zn(tr2ad)2(NO3)2]n (I) (tr2ad = 1,3-bis(1,2,4-triazole-1-yl)adamantane) metal-organic framework (MOF) is prepared by solvothermal synthesis. According to the XRD data, this MOF is formed by spiral chains, left- and right-handed ones present in equal amounts in the structure. Compound I is studied by powder XRD, elemental analysis, and thermogravimetry. Its photoluminescent properties are considered. It is shown that I exhibits emission with a maximum at 448 nm and a luminescence quantum yield of 7%.",

keywords = "metal-organic frameworks, zinc, adamantane, luminescence, crystal structure, МЕТАЛЛ-ОРГАНИЧЕСКИЕ КООРДИНАЦИОННЫЕ ПОЛИМЕРЫ, ЦИНК, АДАМАНТАН, ЛЮМИНЕСЦЕНЦИЯ, КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА",

author = "Makogon, {U. A.} and Marchenko, {R. D.} and Pavlov, {D. I.} and Ryadun, {A. A.} and Potapov, {A. S.}",

note = "Makogon, U.A., Marchenko, R.D., Pavlov, D.I. et al. Synthesis, Structure, and Luminescent Properties of a Metal-Organic Framework of Zinc with 1,3-(1,2,4-triazole-1-yl)Adamantane. J. Struct. Chem. 66, 2348–2354 (2025). https://doi.org/10.1134/S0022476625110095 The work was supported by the Ministry of Science and Higher Education of the Russian Federation.",

year = "2025",

month = dec,

day = "5",

doi = "10.1134/S0022476625110095",

language = "English",

volume = "66",

pages = "2348--2354",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer",

number = "11",

}

RIS

TY - JOUR

T1 - Synthesis, Structure, and Luminescent Properties of a Metal-Organic Framework of Zinc with 1,3-(1,2,4-triazole-1-yl)Adamantane

AU - Makogon, U. A.

AU - Marchenko, R. D.

AU - Pavlov, D. I.

AU - Ryadun, A. A.

AU - Potapov, A. S.

N1 - Makogon, U.A., Marchenko, R.D., Pavlov, D.I. et al. Synthesis, Structure, and Luminescent Properties of a Metal-Organic Framework of Zinc with 1,3-(1,2,4-triazole-1-yl)Adamantane. J. Struct. Chem. 66, 2348–2354 (2025). https://doi.org/10.1134/S0022476625110095 The work was supported by the Ministry of Science and Higher Education of the Russian Federation.

PY - 2025/12/5

Y1 - 2025/12/5

N2 - A new [Zn(tr2ad)2(NO3)2]n (I) (tr2ad = 1,3-bis(1,2,4-triazole-1-yl)adamantane) metal-organic framework (MOF) is prepared by solvothermal synthesis. According to the XRD data, this MOF is formed by spiral chains, left- and right-handed ones present in equal amounts in the structure. Compound I is studied by powder XRD, elemental analysis, and thermogravimetry. Its photoluminescent properties are considered. It is shown that I exhibits emission with a maximum at 448 nm and a luminescence quantum yield of 7%.

AB - A new [Zn(tr2ad)2(NO3)2]n (I) (tr2ad = 1,3-bis(1,2,4-triazole-1-yl)adamantane) metal-organic framework (MOF) is prepared by solvothermal synthesis. According to the XRD data, this MOF is formed by spiral chains, left- and right-handed ones present in equal amounts in the structure. Compound I is studied by powder XRD, elemental analysis, and thermogravimetry. Its photoluminescent properties are considered. It is shown that I exhibits emission with a maximum at 448 nm and a luminescence quantum yield of 7%.

KW - metal-organic frameworks

KW - zinc

KW - adamantane

KW - luminescence

KW - crystal structure

KW - МЕТАЛЛ-ОРГАНИЧЕСКИЕ КООРДИНАЦИОННЫЕ ПОЛИМЕРЫ

KW - ЦИНК

KW - АДАМАНТАН

KW - ЛЮМИНЕСЦЕНЦИЯ

KW - КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА

UR - https://www.scopus.com/pages/publications/105024089873

UR - https://elibrary.ru/item.asp?id=83257183

UR - https://www.mendeley.com/catalogue/f895a918-b4d7-32c7-904f-4b89d6568a90/

U2 - 10.1134/S0022476625110095

DO - 10.1134/S0022476625110095

M3 - Article

VL - 66

SP - 2348

EP - 2354

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 72578368