Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane

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Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane. / Vosmerikova, L. N.; Vosmerikov, A. V.; Zaikovskii, V. I. et al.

In: Russian Journal of Physical Chemistry A, Vol. 96, No. 3, 03.2022, p. 535-541.

Research output: Contribution to journal › Article › peer-review

Harvard

Vosmerikova, LN, Vosmerikov, AV, Zaikovskii, VI & Vosmerikov, AV 2022, 'Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane', Russian Journal of Physical Chemistry A, vol. 96, no. 3, pp. 535-541. https://doi.org/10.1134/S0036024422030268

APA

Vosmerikova, L. N., Vosmerikov, A. V., Zaikovskii, V. I., & Vosmerikov, A. V. (2022). Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane. Russian Journal of Physical Chemistry A, 96(3), 535-541. https://doi.org/10.1134/S0036024422030268

Vancouver

Vosmerikova LN, Vosmerikov AV, Zaikovskii VI, Vosmerikov AV. Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane. Russian Journal of Physical Chemistry A. 2022 Mar;96(3):535-541. doi: 10.1134/S0036024422030268

Author

Vosmerikova, L. N. ; Vosmerikov, A. V. ; Zaikovskii, V. I. et al. / Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane. In: Russian Journal of Physical Chemistry A. 2022 ; Vol. 96, No. 3. pp. 535-541.

BibTeX

@article{54b03fd7cc1e484d8fe267c1b9324523,

title = "Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane",

abstract = "Zn aluminosilicates of a ZSM-5 zeolite structural type are synthesized from alkaline alumino-silica gels via hydrothermal crystallization. Structural and morphological data on the samples show that incorporating zinc into the zeolite structure leads to the formation of the particles of different morphology and elemental composition. Data from EDX analysis show that the distribution of elements throughout the zeolite catalyst is almost uniform, due to the morphology of the crystals that form. It is found that Zn aluminosilicates have high catalytic activity in the conversion of propane into aromatic hydrocarbons. A 0.81% Zn-AC sample exhibits the greatest selectivity toward aromatic compounds, due to the specific distribution and state of Zn in the zeolite and its acidic properties.",

keywords = "active centers, aggregates, aromatization, clusters, crystals, morphology, propane, zinc aluminosilicate",

author = "Vosmerikova, {L. N.} and Vosmerikov, {A. V.} and Zaikovskii, {V. I.} and Vosmerikov, {A. V.}",

note = "Funding Information: This work was supported by the RF Ministry of Higher Education and Science. Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = mar,

doi = "10.1134/S0036024422030268",

language = "English",

volume = "96",

pages = "535--541",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "PLEIADES PUBLISHING INC",

number = "3",

}

RIS

TY - JOUR

T1 - Synthesis of Zn Aluminosilicates and Their Physicochemical and Catalytic Properties in the Aromatization of Propane

AU - Vosmerikova, L. N.

AU - Vosmerikov, A. V.

AU - Zaikovskii, V. I.

AU - Vosmerikov, A. V.

PY - 2022/3

Y1 - 2022/3

N2 - Zn aluminosilicates of a ZSM-5 zeolite structural type are synthesized from alkaline alumino-silica gels via hydrothermal crystallization. Structural and morphological data on the samples show that incorporating zinc into the zeolite structure leads to the formation of the particles of different morphology and elemental composition. Data from EDX analysis show that the distribution of elements throughout the zeolite catalyst is almost uniform, due to the morphology of the crystals that form. It is found that Zn aluminosilicates have high catalytic activity in the conversion of propane into aromatic hydrocarbons. A 0.81% Zn-AC sample exhibits the greatest selectivity toward aromatic compounds, due to the specific distribution and state of Zn in the zeolite and its acidic properties.

AB - Zn aluminosilicates of a ZSM-5 zeolite structural type are synthesized from alkaline alumino-silica gels via hydrothermal crystallization. Structural and morphological data on the samples show that incorporating zinc into the zeolite structure leads to the formation of the particles of different morphology and elemental composition. Data from EDX analysis show that the distribution of elements throughout the zeolite catalyst is almost uniform, due to the morphology of the crystals that form. It is found that Zn aluminosilicates have high catalytic activity in the conversion of propane into aromatic hydrocarbons. A 0.81% Zn-AC sample exhibits the greatest selectivity toward aromatic compounds, due to the specific distribution and state of Zn in the zeolite and its acidic properties.

KW - active centers

KW - aggregates

KW - aromatization

KW - clusters

KW - crystals

KW - morphology

KW - propane

KW - zinc aluminosilicate

UR - http://www.scopus.com/inward/record.url?scp=85127359180&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/4ac80311-a382-3a89-b9c6-c0353830a1f2/

U2 - 10.1134/S0036024422030268

DO - 10.1134/S0036024422030268

M3 - Article

AN - SCOPUS:85127359180

VL - 96

SP - 535

EP - 541

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 3

ER -

ID: 35826272