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Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor. / Nuzhdin, Alexey L.; Artiukha, Ekaterina A.; Bukhtiyarova, Galina A. et al.

In: Catalysis Communications, Vol. 102, 12.2017, p. 108-113.

Research output: Contribution to journal › Article › peer-review

Harvard

Nuzhdin, AL, Artiukha, EA, Bukhtiyarova, GA, Derevyannikova, EA & Bukhtiyarov, VI 2017, 'Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor', Catalysis Communications, vol. 102, pp. 108-113. https://doi.org/10.1016/j.catcom.2017.09.001

APA

Nuzhdin, A. L., Artiukha, E. A., Bukhtiyarova, G. A., Derevyannikova, E. A., & Bukhtiyarov, V. I. (2017). Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor. Catalysis Communications, 102, 108-113. https://doi.org/10.1016/j.catcom.2017.09.001

Vancouver

Nuzhdin AL, Artiukha EA, Bukhtiyarova GA, Derevyannikova EA, Bukhtiyarov VI. Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor. Catalysis Communications. 2017 Dec;102:108-113. doi: 10.1016/j.catcom.2017.09.001

Author

Nuzhdin, Alexey L. ; Artiukha, Ekaterina A. ; Bukhtiyarova, Galina A. et al. / Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor. In: Catalysis Communications. 2017 ; Vol. 102. pp. 108-113.

BibTeX

@article{e341fa6494094ae1bcc52888f3f5cd2f,
title = "Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor",
abstract = "Supported copper catalysts were investigated for the one-pot reductive amination of aldehydes with nitroarenes in a continuous flow reactor. This process is considered advantageous compared to current traditional methods, which present several drawbacks, such as toxicity of reducing or alkylation agent, lack of monoalkylation selectivity and large amounts of waste produced. Various secondary amines were synthesized in good to excellent yields in the reactions of aliphatic aldehydes with nitroarenes using molecular hydrogen as a reducing agent. It was found that the yield of secondary amine depends on the rate of formation of intermediate imine.",
keywords = "Aldehyde, Continuous flow reactor, Molecular hydrogen, Nitroarene, One-pot reductive amination, Supported copper catalyst, LIQUID-PHASE HYDROGENATION, ONE-POT SYNTHESIS, CARBONYL-COMPOUNDS, NANOPARTICLES, CU, NITRO-COMPOUNDS, RECOVERABLE CATALYST, AU/AL2O3 CATALYST",
author = "Nuzhdin, {Alexey L.} and Artiukha, {Ekaterina A.} and Bukhtiyarova, {Galina A.} and Derevyannikova, {Elizaveta A.} and Bukhtiyarov, {Valerii I.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2017",
month = dec,
doi = "10.1016/j.catcom.2017.09.001",
language = "English",
volume = "102",
pages = "108--113",
journal = "Catalysis Communications",
issn = "1566-7367",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis of secondary amines by reductive amination of aldehydes with nitroarenes over supported copper catalysts in a flow reactor

AU - Nuzhdin, Alexey L.

AU - Artiukha, Ekaterina A.

AU - Bukhtiyarova, Galina A.

AU - Derevyannikova, Elizaveta A.

AU - Bukhtiyarov, Valerii I.

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017/12

Y1 - 2017/12

N2 - Supported copper catalysts were investigated for the one-pot reductive amination of aldehydes with nitroarenes in a continuous flow reactor. This process is considered advantageous compared to current traditional methods, which present several drawbacks, such as toxicity of reducing or alkylation agent, lack of monoalkylation selectivity and large amounts of waste produced. Various secondary amines were synthesized in good to excellent yields in the reactions of aliphatic aldehydes with nitroarenes using molecular hydrogen as a reducing agent. It was found that the yield of secondary amine depends on the rate of formation of intermediate imine.

AB - Supported copper catalysts were investigated for the one-pot reductive amination of aldehydes with nitroarenes in a continuous flow reactor. This process is considered advantageous compared to current traditional methods, which present several drawbacks, such as toxicity of reducing or alkylation agent, lack of monoalkylation selectivity and large amounts of waste produced. Various secondary amines were synthesized in good to excellent yields in the reactions of aliphatic aldehydes with nitroarenes using molecular hydrogen as a reducing agent. It was found that the yield of secondary amine depends on the rate of formation of intermediate imine.

KW - Aldehyde

KW - Continuous flow reactor

KW - Molecular hydrogen

KW - Nitroarene

KW - One-pot reductive amination

KW - Supported copper catalyst

KW - LIQUID-PHASE HYDROGENATION

KW - ONE-POT SYNTHESIS

KW - CARBONYL-COMPOUNDS

KW - NANOPARTICLES

KW - CU

KW - NITRO-COMPOUNDS

KW - RECOVERABLE CATALYST

KW - AU/AL2O3 CATALYST

UR - http://www.scopus.com/inward/record.url?scp=85029178266&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2017.09.001

DO - 10.1016/j.catcom.2017.09.001

M3 - Article

AN - SCOPUS:85029178266

VL - 102

SP - 108

EP - 113

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -

ID: 9915253