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Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion. / Gavrilov, I. N.; Orlova, N. A.; Vasilyev, E. V. et al.

In: Russian Journal of Organic Chemistry, Vol. 61, No. 10, 2, 10.2025, p. 1789-1800.

Research output: Contribution to journal › Article › peer-review

Harvard

Gavrilov, IN, Orlova, NA, Vasilyev, EV, Shelkovnikov, VV, Kargapolova, IY, Ishchenko, AV & Bayrash, AS 2025, 'Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion', Russian Journal of Organic Chemistry, vol. 61, no. 10, 2, pp. 1789-1800. https://doi.org/10.1134/S1070428025603267

APA

Gavrilov, I. N., Orlova, N. A., Vasilyev, E. V., Shelkovnikov, V. V., Kargapolova, I. Y., Ishchenko, A. V., & Bayrash, A. S. (2025). Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion. Russian Journal of Organic Chemistry, 61(10), 1789-1800. [2]. https://doi.org/10.1134/S1070428025603267

Vancouver

Gavrilov IN, Orlova NA, Vasilyev EV, Shelkovnikov VV, Kargapolova IY, Ishchenko AV et al. Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion. Russian Journal of Organic Chemistry. 2025 Oct;61(10):1789-1800. 2. doi: 10.1134/S1070428025603267

Author

Gavrilov, I. N. ; Orlova, N. A. ; Vasilyev, E. V. et al. / Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion. In: Russian Journal of Organic Chemistry. 2025 ; Vol. 61, No. 10. pp. 1789-1800.

BibTeX

@article{8edc4d9595634f338b05d7c23f98fc90,
title = "Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion",
abstract = "A series of polyfluorinated triarylpyrazolines containing cationic piperazinium fragments in the fluorinated rings have been synthesized by substitution of para-fluorine atoms by 1-methylpiperazine and subsequent quaternization of the piperazine nitrogen atom. The relation between the structure of the obtained salts and their spectral characteristics has been studied, and photobleaching quantum yields in the presence of tetrabutylammonium butyl(triphenyl)borate have been measured.",
keywords = "1-methylpiperazine, absorption spectra, arenethiols, nucleophilic substitution of fluorine, piperazinium salts, polyfluorinated chalcones, polyfluorinated triarylpyrazolines, quantum yield, ПОЛИФТОРХАЛКОНЫ, ПОЛИФТОРИРОВАННЫЕ ТРИАРИЛПИРАЗОЛИНЫ, НУКЛЕОФИЛЬНОЕ ЗАМЕЩЕНИЕ ФТОРА, 1-МЕТИЛПИПЕРАЗИН, СОЛИ ПИПЕРАЗИНИЯ, АРИЛТИОЛЫ, СПЕКТРЫ ПОГЛОЩЕНИЯ, КВАНТОВЫЙ ВЫХОД",
author = "Gavrilov, {I. N.} and Orlova, {N. A.} and Vasilyev, {E. V.} and Shelkovnikov, {V. V.} and Kargapolova, {I. Yu} and Ishchenko, {A. V.} and Bayrash, {A. S.}",
note = "Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion / I.N. Gavrilov, N.A. Orlova, E.V. Vasilyev [et al.] // Russian Journal of Organic Chemistry. – 2025. – Vol. 61. - No. 10. – P. 1789-1800. – DOI 10.1134/S1070428025603267. – EDN ONNZQU. This work was supported by basic budgetary funding from the Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences (project no. FWUE-2025-0013).",
year = "2025",
month = oct,
doi = "10.1134/S1070428025603267",
language = "English",
volume = "61",
pages = "1789--1800",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion

AU - Gavrilov, I. N.

AU - Orlova, N. A.

AU - Vasilyev, E. V.

AU - Shelkovnikov, V. V.

AU - Kargapolova, I. Yu

AU - Ishchenko, A. V.

AU - Bayrash, A. S.

N1 - Synthesis of Polyfluorinated Triphenylpyrazolines Containing Cationic Centers and Efficiency of Their Photodecomposition in the Presence of Borate Anion / I.N. Gavrilov, N.A. Orlova, E.V. Vasilyev [et al.] // Russian Journal of Organic Chemistry. – 2025. – Vol. 61. - No. 10. – P. 1789-1800. – DOI 10.1134/S1070428025603267. – EDN ONNZQU. This work was supported by basic budgetary funding from the Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences (project no. FWUE-2025-0013).

PY - 2025/10

Y1 - 2025/10

N2 - A series of polyfluorinated triarylpyrazolines containing cationic piperazinium fragments in the fluorinated rings have been synthesized by substitution of para-fluorine atoms by 1-methylpiperazine and subsequent quaternization of the piperazine nitrogen atom. The relation between the structure of the obtained salts and their spectral characteristics has been studied, and photobleaching quantum yields in the presence of tetrabutylammonium butyl(triphenyl)borate have been measured.

AB - A series of polyfluorinated triarylpyrazolines containing cationic piperazinium fragments in the fluorinated rings have been synthesized by substitution of para-fluorine atoms by 1-methylpiperazine and subsequent quaternization of the piperazine nitrogen atom. The relation between the structure of the obtained salts and their spectral characteristics has been studied, and photobleaching quantum yields in the presence of tetrabutylammonium butyl(triphenyl)borate have been measured.

KW - 1-methylpiperazine

KW - absorption spectra

KW - arenethiols

KW - nucleophilic substitution of fluorine

KW - piperazinium salts

KW - polyfluorinated chalcones

KW - polyfluorinated triarylpyrazolines

KW - quantum yield

KW - ПОЛИФТОРХАЛКОНЫ

KW - ПОЛИФТОРИРОВАННЫЕ ТРИАРИЛПИРАЗОЛИНЫ

KW - НУКЛЕОФИЛЬНОЕ ЗАМЕЩЕНИЕ ФТОРА

KW - 1-МЕТИЛПИПЕРАЗИН

KW - СОЛИ ПИПЕРАЗИНИЯ

KW - АРИЛТИОЛЫ

KW - СПЕКТРЫ ПОГЛОЩЕНИЯ

KW - КВАНТОВЫЙ ВЫХОД

UR - https://www.scopus.com/pages/publications/105025352269

UR - https://www.elibrary.ru/item.asp?id=87370553

UR - https://www.elibrary.ru/item.asp?id=88869412

UR - https://www.mendeley.com/catalogue/850755eb-b452-33ee-9f0c-c4dcd641415b/

U2 - 10.1134/S1070428025603267

DO - 10.1134/S1070428025603267

M3 - Article

VL - 61

SP - 1789

EP - 1800

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 10

M1 - 2

ER -

ID: 74616549