TY - JOUR

T1 - Synthesis of Nitro-Octaaza Derivatives of Reduced Anthracene

AU - Il'yasov, Sergey G.

AU - Glukhacheva, Vera S.

AU - Yermoshina, Valentina A.

AU - Eltsov, Ilia V.

PY - 2019/6/14

Y1 - 2019/6/14

N2 - Nitro compounds of octaaza derivatives of reduced anthracene were synthesized for the first time by reaction of 2,3,4a,6,7,8a,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8a,9,9a,10,10a-decahydroanthracene with nitric acid, mixed nitric acid/sulfuric acid, and nitric acid/acetic anhydride at between –20 and –30 °C. In addition, 1,2,4,5-tetrazine azido derivatives were obtained by hydrolytic decomposition of the starting compound by nitrous acid. All the resultant compounds exhibit high thermal stability.

AB - Nitro compounds of octaaza derivatives of reduced anthracene were synthesized for the first time by reaction of 2,3,4a,6,7,8a,9,10-octaaza-4,8-dioxo-3,4,4a,7,8,8a,9,9a,10,10a-decahydroanthracene with nitric acid, mixed nitric acid/sulfuric acid, and nitric acid/acetic anhydride at between –20 and –30 °C. In addition, 1,2,4,5-tetrazine azido derivatives were obtained by hydrolytic decomposition of the starting compound by nitrous acid. All the resultant compounds exhibit high thermal stability.

KW - 1,4-Diformyl-1,2,4,5-tetrazinane-3,6-dicarbonyl diazide

KW - 2,3,4a,6,7,8a,9,10-Octaaza-4,8-dioxo-3,4,4a,7,8,8a,9,9a,10,10a-decahydroanthracene

KW - Heterocycles

KW - Nitration

KW - Nitrosation

KW - 6-dicarbonyl diazide

KW - NITRAMIDE

KW - 10-Octaaza-4

KW - 5-tetrazinane-3

KW - 9a

KW - 8a

KW - 4a

KW - 8-dioxo-3

KW - 4-Diformyl-1

KW - 1

KW - 2

KW - 3

KW - 4

KW - 6

KW - 7

KW - 8

KW - 9

KW - 10

KW - 10a-decahydroanthracene

UR - http://www.scopus.com/inward/record.url?scp=85066144264&partnerID=8YFLogxK

U2 - 10.1002/zaac.201900091

DO - 10.1002/zaac.201900091

M3 - Article

AN - SCOPUS:85066144264

VL - 645

SP - 792

EP - 796

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 11

ER -