Research output: Contribution to journal › Article › peer-review
Synthesis of NH 4-substituted muscovite at 6.3 GPa and 1000°C : Implications for Nitrogen Transport to the Earth's Mantle. / Sokol, A. G.; Sokol, E. V.; Kupriyanov, I. N. et al.
In: Doklady Earth Sciences, Vol. 479, No. 1, 01.01.2018, p. 404-407.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis of NH 4-substituted muscovite at 6.3 GPa and 1000°C
T2 - Implications for Nitrogen Transport to the Earth's Mantle
AU - Sokol, A. G.
AU - Sokol, E. V.
AU - Kupriyanov, I. N.
AU - Sobolev, N. V.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - The synthesis of NH4-bearing muscovite at P = 6.3 GPa and T = 1000A degrees C in equilibrium with NH3-H2O fluid is performed. It is determined that the newly formed muscovite is enriched in celadonite minal and contains similar to 370 ppm of NH4. The obtained data make it possible to conclude that ammonium-bearing micas have sufficient thermal stability and can transport crustal nitrogen to the mantle in the presence of a reduced water-ammonia fluid at fO(2) less than the values of IW + 2 log units even in the regime of "hot" subduction. The key parameter that determines the efficiency of this mechanism for the deep nitrogen cycle is redox stability of NH4-bearing muscovite at the mantle PT-parameters.
AB - The synthesis of NH4-bearing muscovite at P = 6.3 GPa and T = 1000A degrees C in equilibrium with NH3-H2O fluid is performed. It is determined that the newly formed muscovite is enriched in celadonite minal and contains similar to 370 ppm of NH4. The obtained data make it possible to conclude that ammonium-bearing micas have sufficient thermal stability and can transport crustal nitrogen to the mantle in the presence of a reduced water-ammonia fluid at fO(2) less than the values of IW + 2 log units even in the regime of "hot" subduction. The key parameter that determines the efficiency of this mechanism for the deep nitrogen cycle is redox stability of NH4-bearing muscovite at the mantle PT-parameters.
KW - ATMOSPHERE
KW - DIAMONDS
KW - ISOTOPES
KW - AMMONIUM
KW - CRUST
UR - http://www.scopus.com/inward/record.url?scp=85063890607&partnerID=8YFLogxK
U2 - 10.1134/S1028334X18030315
DO - 10.1134/S1028334X18030315
M3 - Article
VL - 479
SP - 404
EP - 407
JO - Doklady Earth Sciences
JF - Doklady Earth Sciences
SN - 1028-334X
IS - 1
ER -
ID: 18649259