Research output: Contribution to journal › Article › peer-review
SYNTHESIS OF FLUORINATED BENZOTHIAZOLES, STUDY OF THEIR LITHIATION SITES AND SUBSEQUENT INTERACTION WITH DIMETHYLFORMAMIDE. / V.E., ROMANOV; E.V., PANTELEEVA.
In: Chemistry for Sustainable Development, Vol. 31, No. 6, 2023, p. 673-680.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - SYNTHESIS OF FLUORINATED BENZOTHIAZOLES, STUDY OF THEIR LITHIATION SITES AND SUBSEQUENT INTERACTION WITH DIMETHYLFORMAMIDE
AU - V.E., ROMANOV
AU - E.V., PANTELEEVA
N1 - Romanov, V. E. Synthesis of Fluorinated Benzothiazoles, Study of Their Lithiation Sites and Subsequent Interaction with Dimethylformamide / V. E. Romanov, E. V. Panteleeva // Chemistry for Sustainable Development. – 2023. – Vol. 31, No. 6. – P. 673-680. – DOI 10.15372/CSD2023516.
PY - 2023
Y1 - 2023
N2 - The interaction of 4,6-difluoro-, 4-fluoro-, and 2-bromo-4,6-difluorobenzothiazole with BuLi and LiN[(CH3)3Si]2 in THF, followed by the treatment with dimethylformamide or MeI, revealed the main metalation sites in these model mono- and difluorinated benzothiazoles. The reactivity of the resulting Li-derivatives with respect to formylation and methylation was also described.
AB - The interaction of 4,6-difluoro-, 4-fluoro-, and 2-bromo-4,6-difluorobenzothiazole with BuLi and LiN[(CH3)3Si]2 in THF, followed by the treatment with dimethylformamide or MeI, revealed the main metalation sites in these model mono- and difluorinated benzothiazoles. The reactivity of the resulting Li-derivatives with respect to formylation and methylation was also described.
KW - FLUORINATED BENZOTHIAZOLES
KW - LITHIUM DERIVATIVES OF BENZOTHIAZOLES
KW - FORMYLATION
KW - METHYLATION
UR - https://www.mendeley.com/catalogue/e4938720-662a-3adc-a898-63fdf2e0c183/
UR - https://www.elibrary.ru/item.asp?id=59461433
U2 - 10.15372/csd2023516
DO - 10.15372/csd2023516
M3 - Article
VL - 31
SP - 673
EP - 680
JO - Chemistry for Sustainable Development
JF - Chemistry for Sustainable Development
SN - 1817-1818
IS - 6
ER -
ID: 68316343