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Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds. / Ozerova, Anna M.; Potylitsyna, Arina R.; Bauman, Yury I. et al.

In: Materials, Vol. 15, No. 23, 8414, 12.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Ozerova, AM, Potylitsyna, AR, Bauman, YI, Tayban, ES, Lipatnikova, IL, Nartova, AV, Vedyagin, AA, Mishakov, IV, Shubin, YV & Netskina, OV 2022, 'Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds', Materials, vol. 15, no. 23, 8414. https://doi.org/10.3390/ma15238414

APA

Ozerova, A. M., Potylitsyna, A. R., Bauman, Y. I., Tayban, E. S., Lipatnikova, I. L., Nartova, A. V., Vedyagin, A. A., Mishakov, I. V., Shubin, Y. V., & Netskina, O. V. (2022). Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds. Materials, 15(23), [8414]. https://doi.org/10.3390/ma15238414

Vancouver

Ozerova AM, Potylitsyna AR, Bauman YI, Tayban ES, Lipatnikova IL, Nartova AV et al. Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds. Materials. 2022 Dec;15(23):8414. doi: 10.3390/ma15238414

Author

Ozerova, Anna M. ; Potylitsyna, Arina R. ; Bauman, Yury I. et al. / Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds. In: Materials. 2022 ; Vol. 15, No. 23.

BibTeX

@article{4dbda7285ec043eb8d79a1e094c762c7,
title = "Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds",
abstract = "Chlorine- and nitrogen-containing carbon nanofibers (CNFs) were obtained by combined catalytic pyrolysis of trichloroethylene (C2HCl3) and acetonitrile (CH3CN). Their efficiency in the adsorption of 1,2-dichlorobenzene (1,2-DCB) from water has been studied. The synthesis of CNFs was carried out over self-dispersing nickel catalyst at 600 °C. The produced CNFs possess a well-defined segmented structure, high specific surface area (~300 m2/g) and high porosity (0.5–0.7 cm3/g). The addition of CH3CN into the reaction mixture allows the introduction of nitrogen into the CNF structure and increases the volume of mesopores. As a result, the capacity of CNF towards adsorption of 1,2-DCB from its aqueous solution increased from 0.41 to 0.57 cm3/g. Regardless of the presence of N, the CNF samples exhibited a degree of 1,2-DCB adsorption from water–organic emulsion exceeding 90%. The adsorption process was shown to be well described by the Dubinin–Astakhov equation. The regeneration of the used CNF adsorbent through liquid-phase hydrodechlorination was also investigated. For this purpose, Pd nanoparticles (1.5 wt%) were deposited on the CNF surface to form the adsorbent with catalytic function. The presence of palladium was found to have a slight effect on the adsorption capacity of CNF. Further regeneration of the adsorbent-catalyst via hydrodechlorination of adsorbed 1,2-DCB was completed within 1 h with 100% conversion. The repeated use of regenerated adsorbent-catalysts for purification of solutions after the first cycle of adsorption ensures almost complete removal of 1,2-DCB.",
keywords = "adsorption, chloroaromatics, hydrodechlorination, N-containing carbon nanofibers, nickel catalyst, trichloroethylene",
author = "Ozerova, {Anna M.} and Potylitsyna, {Arina R.} and Bauman, {Yury I.} and Tayban, {Elena S.} and Lipatnikova, {Inna L.} and Nartova, {Anna V.} and Vedyagin, {Aleksey A.} and Mishakov, {Ilya V.} and Shubin, {Yury V.} and Netskina, {Olga V.}",
note = "Funding Information: This work was financially supported by the Russian Science Foundation (project No. 22-13-00406, https://rscf.ru/en/project/22-13-00406/, accessed on 21 November 2022, BIC SB RAS). Publisher Copyright: {\textcopyright} 2022 by the authors.",
year = "2022",
month = dec,
doi = "10.3390/ma15238414",
language = "English",
volume = "15",
journal = "Materials",
issn = "1996-1944",
publisher = "MDPI AG",
number = "23",

}

RIS

TY - JOUR

T1 - Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds

AU - Ozerova, Anna M.

AU - Potylitsyna, Arina R.

AU - Bauman, Yury I.

AU - Tayban, Elena S.

AU - Lipatnikova, Inna L.

AU - Nartova, Anna V.

AU - Vedyagin, Aleksey A.

AU - Mishakov, Ilya V.

AU - Shubin, Yury V.

AU - Netskina, Olga V.

N1 - Funding Information: This work was financially supported by the Russian Science Foundation (project No. 22-13-00406, https://rscf.ru/en/project/22-13-00406/, accessed on 21 November 2022, BIC SB RAS). Publisher Copyright: © 2022 by the authors.

PY - 2022/12

Y1 - 2022/12

N2 - Chlorine- and nitrogen-containing carbon nanofibers (CNFs) were obtained by combined catalytic pyrolysis of trichloroethylene (C2HCl3) and acetonitrile (CH3CN). Their efficiency in the adsorption of 1,2-dichlorobenzene (1,2-DCB) from water has been studied. The synthesis of CNFs was carried out over self-dispersing nickel catalyst at 600 °C. The produced CNFs possess a well-defined segmented structure, high specific surface area (~300 m2/g) and high porosity (0.5–0.7 cm3/g). The addition of CH3CN into the reaction mixture allows the introduction of nitrogen into the CNF structure and increases the volume of mesopores. As a result, the capacity of CNF towards adsorption of 1,2-DCB from its aqueous solution increased from 0.41 to 0.57 cm3/g. Regardless of the presence of N, the CNF samples exhibited a degree of 1,2-DCB adsorption from water–organic emulsion exceeding 90%. The adsorption process was shown to be well described by the Dubinin–Astakhov equation. The regeneration of the used CNF adsorbent through liquid-phase hydrodechlorination was also investigated. For this purpose, Pd nanoparticles (1.5 wt%) were deposited on the CNF surface to form the adsorbent with catalytic function. The presence of palladium was found to have a slight effect on the adsorption capacity of CNF. Further regeneration of the adsorbent-catalyst via hydrodechlorination of adsorbed 1,2-DCB was completed within 1 h with 100% conversion. The repeated use of regenerated adsorbent-catalysts for purification of solutions after the first cycle of adsorption ensures almost complete removal of 1,2-DCB.

AB - Chlorine- and nitrogen-containing carbon nanofibers (CNFs) were obtained by combined catalytic pyrolysis of trichloroethylene (C2HCl3) and acetonitrile (CH3CN). Their efficiency in the adsorption of 1,2-dichlorobenzene (1,2-DCB) from water has been studied. The synthesis of CNFs was carried out over self-dispersing nickel catalyst at 600 °C. The produced CNFs possess a well-defined segmented structure, high specific surface area (~300 m2/g) and high porosity (0.5–0.7 cm3/g). The addition of CH3CN into the reaction mixture allows the introduction of nitrogen into the CNF structure and increases the volume of mesopores. As a result, the capacity of CNF towards adsorption of 1,2-DCB from its aqueous solution increased from 0.41 to 0.57 cm3/g. Regardless of the presence of N, the CNF samples exhibited a degree of 1,2-DCB adsorption from water–organic emulsion exceeding 90%. The adsorption process was shown to be well described by the Dubinin–Astakhov equation. The regeneration of the used CNF adsorbent through liquid-phase hydrodechlorination was also investigated. For this purpose, Pd nanoparticles (1.5 wt%) were deposited on the CNF surface to form the adsorbent with catalytic function. The presence of palladium was found to have a slight effect on the adsorption capacity of CNF. Further regeneration of the adsorbent-catalyst via hydrodechlorination of adsorbed 1,2-DCB was completed within 1 h with 100% conversion. The repeated use of regenerated adsorbent-catalysts for purification of solutions after the first cycle of adsorption ensures almost complete removal of 1,2-DCB.

KW - adsorption

KW - chloroaromatics

KW - hydrodechlorination

KW - N-containing carbon nanofibers

KW - nickel catalyst

KW - trichloroethylene

UR - http://www.scopus.com/inward/record.url?scp=85143765442&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/d58e9d17-95aa-3214-86c3-530286267ece/

U2 - 10.3390/ma15238414

DO - 10.3390/ma15238414

M3 - Article

C2 - 36499909

AN - SCOPUS:85143765442

VL - 15

JO - Materials

JF - Materials

SN - 1996-1944

IS - 23

M1 - 8414

ER -

ID: 40846648