Synthesis, crystal structure and electrocatalytic activity of discrete and polymeric copper(II) complexes with bitopic bis(pyrazol-1-yl) methane ligands. / Potapov, Andrei S.; Nudnova, Eugenia A.; Khlebnikov, Andrei I. et al.
In: Inorganic Chemistry Communications, Vol. 53, 03.2015, p. 72-75.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis, crystal structure and electrocatalytic activity of discrete and polymeric copper(II) complexes with bitopic bis(pyrazol-1-yl) methane ligands
AU - Potapov, Andrei S.
AU - Nudnova, Eugenia A.
AU - Khlebnikov, Andrei I.
AU - Ogorodnikov, Vladimir D.
AU - Petrenko, Tatiana V.
PY - 2015/3
Y1 - 2015/3
N2 - New coordination copper(II) compounds containing bitopic bis(pyrazol-1-yl)methane ligands, namely 1,1,2,2- tetrakis(pyrazol-1-yl)ethane, 1,4-bis[bis(pyrazol-1-yl)methyl]benzene and 1,4-bis[bis(3,5-dimethylpyrazol-1- yl)methyl]benzene were prepared. Reactions of ligandswith Cu2+ ions in 1:2 ratio gave discrete homodinuclear complexes,while 1:1 ligand-to-metal ratio lead to the formation of coordination polymers. Electrocatalytic activity of compounds in oxygen electroreduction reaction on the surface of modified carbon paste electrode was evaluated.
AB - New coordination copper(II) compounds containing bitopic bis(pyrazol-1-yl)methane ligands, namely 1,1,2,2- tetrakis(pyrazol-1-yl)ethane, 1,4-bis[bis(pyrazol-1-yl)methyl]benzene and 1,4-bis[bis(3,5-dimethylpyrazol-1- yl)methyl]benzene were prepared. Reactions of ligandswith Cu2+ ions in 1:2 ratio gave discrete homodinuclear complexes,while 1:1 ligand-to-metal ratio lead to the formation of coordination polymers. Electrocatalytic activity of compounds in oxygen electroreduction reaction on the surface of modified carbon paste electrode was evaluated.
KW - Bis(pyrazol-1-yl)methane
KW - Bitopic ligands
KW - Coordination polymers
KW - Copper(II)
KW - Crystal structure
KW - Electrocatalytic activity
UR - http://www.scopus.com/inward/record.url?scp=84921328235&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2015.01.024
DO - 10.1016/j.inoche.2015.01.024
M3 - Article
AN - SCOPUS:84921328235
VL - 53
SP - 72
EP - 75
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -
ID: 25398863