Research output: Contribution to journal › Article › peer-review
Synthesis and studies of structured support Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl. / Rogozhnikov, V. N.; Salanov, A. N.; Potemkin, D. I. et al.
In: Materials Letters, Vol. 283, 128855, 15.01.2021.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis and studies of structured support Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl
AU - Rogozhnikov, V. N.
AU - Salanov, A. N.
AU - Potemkin, D. I.
AU - Glotov, A. P.
AU - Boev, S. V.
AU - Snytnikov, P. V.
N1 - The reported study was financially supported by Russian Foundation for Basic Research project. 19-33-60057 Perspektiva (Rogozhnikov V.N.). Samples characterization was conducted within the framework of budget project AAAA-A17-117041710088-0 for Boreskov Institute of Catalysis.
PY - 2021/1/15
Y1 - 2021/1/15
N2 - The procedure for preparing a structured composite system Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl, which is used as a support for complete oxidation catalysts and catalysts for the conversion of liquid and gaseous hydrocarbons into synthesis gas, has been improved. The method for the synthesis of Ce0.75Zr0.25O2 powder has been optimized to facilitate its depositing on a FeCrAl mesh pre-coated by protective θ-Al2O3 layer. It has been shown by X-ray diffraction that the model powder sample and the cerium-zirconium mixed oxide coating on the alumina-precoated FeCrAl mesh have the same phase compositions. The protective layer of θ-Al2O3 on FeCrAl mesh possesses excellent adhesion properties that ensures high mechanical strength of the Ce0.75Zr0.25O2 coating under repeated heating–cooling cycles. The use of metal substrate as a component of the composite support provides high thermal conductivity, and thus reduces the formation of local hot spots under conditions of highly exothermic catalytic processes.
AB - The procedure for preparing a structured composite system Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl, which is used as a support for complete oxidation catalysts and catalysts for the conversion of liquid and gaseous hydrocarbons into synthesis gas, has been improved. The method for the synthesis of Ce0.75Zr0.25O2 powder has been optimized to facilitate its depositing on a FeCrAl mesh pre-coated by protective θ-Al2O3 layer. It has been shown by X-ray diffraction that the model powder sample and the cerium-zirconium mixed oxide coating on the alumina-precoated FeCrAl mesh have the same phase compositions. The protective layer of θ-Al2O3 on FeCrAl mesh possesses excellent adhesion properties that ensures high mechanical strength of the Ce0.75Zr0.25O2 coating under repeated heating–cooling cycles. The use of metal substrate as a component of the composite support provides high thermal conductivity, and thus reduces the formation of local hot spots under conditions of highly exothermic catalytic processes.
KW - Adhesion
KW - Alumina
KW - Ce-Zr mixed oxide
KW - Deposition
KW - FeCrAlloy wire mesh
KW - Structured catalysts
UR - http://www.scopus.com/inward/record.url?scp=85093933978&partnerID=8YFLogxK
U2 - 10.1016/j.matlet.2020.128855
DO - 10.1016/j.matlet.2020.128855
M3 - Article
AN - SCOPUS:85093933978
VL - 283
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
M1 - 128855
ER -
ID: 25850736