Synthesis and Structure of Terbium(III) Metal–Organic Frameworks Based on trans-1,4-Cyclohexanedicarboxylic Acid and Borneol-Substituted Phenanthroline

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Synthesis and Structure of Terbium(III) Metal–Organic Frameworks Based on trans-1,4-Cyclohexanedicarboxylic Acid and Borneol-Substituted Phenanthroline. / Ovchinnikova, A. A.; Demakov, P. A.; Agafontsev, A. M. et al.

In: Journal of Structural Chemistry, Vol. 66, No. 11, 05.12.2025, p. 2309-2320.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{26a124650c084d45966a6a63e2b62b98,

title = "Synthesis and Structure of Terbium(III) Metal–Organic Frameworks Based on trans-1,4-Cyclohexanedicarboxylic Acid and Borneol-Substituted Phenanthroline",

abstract = "The first example of a metal-organic framework containing 4,7-di((–)-borneol)-1,10-phenanthroline (L) is prepared. The [Tb2(L)2Cl2(chdc)2]·8DMF·H2O (1) and [Tb2(L)2Cl2(chdc)2]·4DMA·2.115H2O (2) (chdc2– = = trans-1,4-cyclohexanedicarboxylate, DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide) compounds are structurally characterized. Compound 1 crystallizes in the chiral space group. Both MOFs have a similar structure of coordination layers with the sql topology, but different 3D packing of the layers. The volume fraction available for the solvent in the pores of 1 and 2 is 27% and 33%, respectively.",

keywords = "(–)-borneol, MOF, crystal structure, metal–organic framework, phenanthroline, terbium(III), terbium(III), phenanthroline, (–)-borneol, MOF, metal–organic framework, crystal structure",

author = "Ovchinnikova, {A. A.} and Demakov, {P. A.} and Agafontsev, {A. M.} and Tkachev, {A. V.} and Fedin, {V. P.} and Dybtsev, {D. N.}",

note = "Ovchinnikova, A.A., Demakov, P.A., Agafontsev, A.M. et al. Synthesis and Structure of Terbium(III) Metal–Organic Frameworks Based on trans-1,4-Cyclohexanedicarboxylic Acid and Borneol-Substituted Phenanthroline. J. Struct. Chem. 66, 2309–2320 (2025). https://doi.org/10.1134/S0022476625110058 This work was funded by the Russian Science Foundation (project No. 23-13-00310).",

year = "2025",

month = dec,

day = "5",

doi = "10.1134/S0022476625110058",

language = "English",

volume = "66",

pages = "2309--2320",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer",

number = "11",

}

RIS

TY - JOUR

T1 - Synthesis and Structure of Terbium(III) Metal–Organic Frameworks Based on trans-1,4-Cyclohexanedicarboxylic Acid and Borneol-Substituted Phenanthroline

AU - Ovchinnikova, A. A.

AU - Demakov, P. A.

AU - Agafontsev, A. M.

AU - Tkachev, A. V.

AU - Fedin, V. P.

AU - Dybtsev, D. N.

N1 - Ovchinnikova, A.A., Demakov, P.A., Agafontsev, A.M. et al. Synthesis and Structure of Terbium(III) Metal–Organic Frameworks Based on trans-1,4-Cyclohexanedicarboxylic Acid and Borneol-Substituted Phenanthroline. J. Struct. Chem. 66, 2309–2320 (2025). https://doi.org/10.1134/S0022476625110058 This work was funded by the Russian Science Foundation (project No. 23-13-00310).

PY - 2025/12/5

Y1 - 2025/12/5

N2 - The first example of a metal-organic framework containing 4,7-di((–)-borneol)-1,10-phenanthroline (L) is prepared. The [Tb2(L)2Cl2(chdc)2]·8DMF·H2O (1) and [Tb2(L)2Cl2(chdc)2]·4DMA·2.115H2O (2) (chdc2– = = trans-1,4-cyclohexanedicarboxylate, DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide) compounds are structurally characterized. Compound 1 crystallizes in the chiral space group. Both MOFs have a similar structure of coordination layers with the sql topology, but different 3D packing of the layers. The volume fraction available for the solvent in the pores of 1 and 2 is 27% and 33%, respectively.

AB - The first example of a metal-organic framework containing 4,7-di((–)-borneol)-1,10-phenanthroline (L) is prepared. The [Tb2(L)2Cl2(chdc)2]·8DMF·H2O (1) and [Tb2(L)2Cl2(chdc)2]·4DMA·2.115H2O (2) (chdc2– = = trans-1,4-cyclohexanedicarboxylate, DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide) compounds are structurally characterized. Compound 1 crystallizes in the chiral space group. Both MOFs have a similar structure of coordination layers with the sql topology, but different 3D packing of the layers. The volume fraction available for the solvent in the pores of 1 and 2 is 27% and 33%, respectively.

KW - (–)-borneol

KW - MOF

KW - crystal structure

KW - metal–organic framework

KW - phenanthroline

KW - terbium(III)

KW - phenanthroline

KW - (–)-borneol

KW - MOF

KW - metal–organic framework

KW - crystal structure

UR - https://www.scopus.com/pages/publications/105024118381

UR - https://elibrary.ru/item.asp?id=83257179

UR - https://www.mendeley.com/catalogue/da040d7f-6ebc-3434-82a0-3a42f8063ab6/

U2 - 10.1134/S0022476625110058

DO - 10.1134/S0022476625110058

M3 - Article

VL - 66

SP - 2309

EP - 2320

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 72577823