Synthesis and structure of new Er(III) complex with N,N′-1,3-BIS(2,6-diisopropylphenyl)triazenide

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Synthesis and structure of new Er(III) complex with N,N′-1,3-BIS(2,6-diisopropylphenyl)triazenide. / Kolybalov, D. S.; Sukhikh, T. S.; Bashirov, D. A. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 2, 02.2021, p. 277-284.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{1475a38d8c7a4a77b1a6016ac42fa892,

title = "Synthesis and structure of new Er(III) complex with N,N′-1,3-BIS(2,6-diisopropylphenyl)triazenide",

abstract = "By the interaction of [Er(N(SiMe3)2)3] with HN3Dipp ((N3Dipp)– = N,N′-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N3Dipp)(N(SiMe3)2)2] (1) and [Er(N3Dipp)2(N(SiMe3)2)] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N3Dipp)2(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal Xray diffraction of the following solid phases: 1, 2·C6H6, and 3.",

keywords = "coordination compounds, crystal structure, erbium, lanthanides, synthesis, triazenes",

author = "Kolybalov, {D. S.} and Sukhikh, {T. S.} and Bashirov, {D. A.} and Konchenko, {S. N.}",

note = "Funding Information: The work was supported by the Russian Science Foundation (grant No. 16-13-10294). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = feb,

doi = "10.1134/S0022476621020128",

language = "English",

volume = "62",

pages = "277--284",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

}

RIS

TY - JOUR

T1 - Synthesis and structure of new Er(III) complex with N,N′-1,3-BIS(2,6-diisopropylphenyl)triazenide

AU - Kolybalov, D. S.

AU - Sukhikh, T. S.

AU - Bashirov, D. A.

AU - Konchenko, S. N.

PY - 2021/2

Y1 - 2021/2

N2 - By the interaction of [Er(N(SiMe3)2)3] with HN3Dipp ((N3Dipp)– = N,N′-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N3Dipp)(N(SiMe3)2)2] (1) and [Er(N3Dipp)2(N(SiMe3)2)] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N3Dipp)2(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal Xray diffraction of the following solid phases: 1, 2·C6H6, and 3.

AB - By the interaction of [Er(N(SiMe3)2)3] with HN3Dipp ((N3Dipp)– = N,N′-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N3Dipp)(N(SiMe3)2)2] (1) and [Er(N3Dipp)2(N(SiMe3)2)] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N3Dipp)2(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal Xray diffraction of the following solid phases: 1, 2·C6H6, and 3.

KW - coordination compounds

KW - crystal structure

KW - erbium

KW - lanthanides

KW - synthesis

KW - triazenes

UR - http://www.scopus.com/inward/record.url?scp=85106245779&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/9ccea524-f0b2-31ca-83fc-fd625e8797fd/

U2 - 10.1134/S0022476621020128

DO - 10.1134/S0022476621020128

M3 - Article

AN - SCOPUS:85106245779

VL - 62

SP - 277

EP - 284

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 34125191