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Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes. / Bashirov, D. A.; Lashchenko, D. I.; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 65, No. 3, 03.2024, p. 534-545.

Research output: Contribution to journal › Article › peer-review

Harvard

Bashirov, DA, Lashchenko, DI, Sukhikh, TS & Konchenko, SN 2024, 'Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes', Journal of Structural Chemistry, vol. 65, no. 3, pp. 534-545. https://doi.org/10.1134/S0022476624030090

APA

Bashirov, D. A., Lashchenko, D. I., Sukhikh, T. S., & Konchenko, S. N. (2024). Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes. Journal of Structural Chemistry, 65(3), 534-545. https://doi.org/10.1134/S0022476624030090

Vancouver

Bashirov DA, Lashchenko DI, Sukhikh TS, Konchenko SN. Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes. Journal of Structural Chemistry. 2024 Mar;65(3):534-545. doi: 10.1134/S0022476624030090

Author

Bashirov, D. A. ; Lashchenko, D. I. ; Sukhikh, T. S. et al. / Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes. In: Journal of Structural Chemistry. 2024 ; Vol. 65, No. 3. pp. 534-545.

BibTeX

@article{62daccf80bd94b47bf8a4d35d994af74,
title = "Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes",
abstract = "Abstract: New silanediamide complexes of rare-earth elements are synthesized: [{Dy(Me2Si(NMes)2)(THF)2}2(μ-Cl)2] (Dy1), [{Ln(Me2Si(NMes)2)(THF)2}2(μ-BH4)2] (Ln2, Ln = Y, Dy), and [{Ln(Me2Si(NMes)2)(THF)2}2 (μ-SPh)2] (Ln3, Ln = Y, Tb, Dy), Mes = 2,4,6-(CH3)C6H2=mesityl. The compounds are isolated as crystalline phases Dy1, Ln2 (Ln = Y, Dy), Y3·2THF, Tb3·2C7H8, Dy3·2THF, and Dy3·2C7H8 and characterized by single crystal X-ray diffraction. All complexes have a binuclear structure; a silanediamide ligand is chelated to each Ln atom, and Cl–,, or SPh– act as bridges. By photoluminescence spectroscopy of the solutions of Tb and Dy complexes in THF it is shown that (Me2Si(NMes)2)2– is an effective ligand antenna, which sensitizes metal-centered emission of these lanthanides.",
keywords = "coordination compounds, crystal structure, dysprosium, luminescence, rare-earth elements, silanediamides, synthesis, terbium, yttrium",
author = "Bashirov, {D. A.} and Lashchenko, {D. I.} and Sukhikh, {T. S.} and Konchenko, {S. N.}",
note = "The authors are grateful to the Ministry of Science and Higher Education of the Russian Federation (121031700321-3, 121031700313-8). The study was supported by the Russian Science Foundation (grant No. 21-13-00287).",
year = "2024",
month = mar,
doi = "10.1134/S0022476624030090",
language = "English",
volume = "65",
pages = "534--545",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Synthesis and Structure of [{Ln(Me2Si(NMes)2)(THF)2}2(μ-L)2] (L =, Ln = Y, Dy; L = PhS–, Ln = Y, Tb, Dy) Complexes

AU - Bashirov, D. A.

AU - Lashchenko, D. I.

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

N1 - The authors are grateful to the Ministry of Science and Higher Education of the Russian Federation (121031700321-3, 121031700313-8). The study was supported by the Russian Science Foundation (grant No. 21-13-00287).

PY - 2024/3

Y1 - 2024/3

N2 - Abstract: New silanediamide complexes of rare-earth elements are synthesized: [{Dy(Me2Si(NMes)2)(THF)2}2(μ-Cl)2] (Dy1), [{Ln(Me2Si(NMes)2)(THF)2}2(μ-BH4)2] (Ln2, Ln = Y, Dy), and [{Ln(Me2Si(NMes)2)(THF)2}2 (μ-SPh)2] (Ln3, Ln = Y, Tb, Dy), Mes = 2,4,6-(CH3)C6H2=mesityl. The compounds are isolated as crystalline phases Dy1, Ln2 (Ln = Y, Dy), Y3·2THF, Tb3·2C7H8, Dy3·2THF, and Dy3·2C7H8 and characterized by single crystal X-ray diffraction. All complexes have a binuclear structure; a silanediamide ligand is chelated to each Ln atom, and Cl–,, or SPh– act as bridges. By photoluminescence spectroscopy of the solutions of Tb and Dy complexes in THF it is shown that (Me2Si(NMes)2)2– is an effective ligand antenna, which sensitizes metal-centered emission of these lanthanides.

AB - Abstract: New silanediamide complexes of rare-earth elements are synthesized: [{Dy(Me2Si(NMes)2)(THF)2}2(μ-Cl)2] (Dy1), [{Ln(Me2Si(NMes)2)(THF)2}2(μ-BH4)2] (Ln2, Ln = Y, Dy), and [{Ln(Me2Si(NMes)2)(THF)2}2 (μ-SPh)2] (Ln3, Ln = Y, Tb, Dy), Mes = 2,4,6-(CH3)C6H2=mesityl. The compounds are isolated as crystalline phases Dy1, Ln2 (Ln = Y, Dy), Y3·2THF, Tb3·2C7H8, Dy3·2THF, and Dy3·2C7H8 and characterized by single crystal X-ray diffraction. All complexes have a binuclear structure; a silanediamide ligand is chelated to each Ln atom, and Cl–,, or SPh– act as bridges. By photoluminescence spectroscopy of the solutions of Tb and Dy complexes in THF it is shown that (Me2Si(NMes)2)2– is an effective ligand antenna, which sensitizes metal-centered emission of these lanthanides.

KW - coordination compounds

KW - crystal structure

KW - dysprosium

KW - luminescence

KW - rare-earth elements

KW - silanediamides

KW - synthesis

KW - terbium

KW - yttrium

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85191777556&origin=inward&txGid=833feb186d77df98b5647f191aad626f

UR - https://www.mendeley.com/catalogue/711573ed-bb9a-3962-b440-66c3a3dcbdc3/

U2 - 10.1134/S0022476624030090

DO - 10.1134/S0022476624030090

M3 - Article

VL - 65

SP - 534

EP - 545

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 61124231