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Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones. / Vikulova, E. S.; Sukhikh, T. S.; Barysheva, A. C. et al.

In: Journal of Structural Chemistry, Vol. 65, No. 11, 18, 11.2024, p. 2327-2344.

Research output: Contribution to journal › Article › peer-review

Harvard

Vikulova, ES, Sukhikh, TS, Barysheva, AC, Varvarinskaya, SE, Ilyin, IY, Shakirova, OG & Morozova, NB 2024, 'Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones', Journal of Structural Chemistry, vol. 65, no. 11, 18, pp. 2327-2344. https://doi.org/10.1134/S0022476624110180

APA

Vikulova, E. S., Sukhikh, T. S., Barysheva, A. C., Varvarinskaya, S. E., Ilyin, I. Y., Shakirova, O. G., & Morozova, N. B. (2024). Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones. Journal of Structural Chemistry, 65(11), 2327-2344. [18]. https://doi.org/10.1134/S0022476624110180

Vancouver

Vikulova ES, Sukhikh TS, Barysheva AC, Varvarinskaya SE, Ilyin IY, Shakirova OG et al. Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones. Journal of Structural Chemistry. 2024 Nov;65(11):2327-2344. 18. doi: 10.1134/S0022476624110180

Author

Vikulova, E. S. ; Sukhikh, T. S. ; Barysheva, A. C. et al. / Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones. In: Journal of Structural Chemistry. 2024 ; Vol. 65, No. 11. pp. 2327-2344.

BibTeX

@article{841946be922c44b894445b9ae182827f,
title = "Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones",
abstract = "The possibility of forming molecular Ag(I) complexes with tris(3,5-dimethylpyrazol-1-yl)methane (HC(3,5-Me2pz)3) and fluorinated β-diketones (hexafluoroacetylacetone (Hhfac) and trifluoroacetylacetone (Htfac)) is tested to expand the library of potential precursors for the chemical vapor deposition of Ag containing materials. It is established that the interaction of HC(3,5-Me2pz)3 with silver β-diketonates leads to the formation of [Ag{HC(3,5-Me2pz)3}2]+ cationic complexes. At the same time, a stable desired product [Ag{HC(3,5-Me2pz)3}hfac] (L = hfac) was isolated and characterized. The structures of [Ag{HC(3,5-Me2pz)3}2](tfac) and as series of solvates [Ag{HC(3,5-Me2pz)3}(hfac)]·½THF and [Ag{HC(3,5-Me2pz)3}2](L)Solvx (L = hfac, Solv = Et2O (x = ¼), C7H8 (x = ½), CHCl3 (x = 1); L = tfac, Solv = THF (x = 1)) are determined by XRD. Structures of the cationic and molecular complexes are compared with those of related compounds.",
keywords = "XRD, silver, tris(3,5-dimethylpyrazol-1-yl)methane, β-diketonate",
author = "Vikulova, {E. S.} and Sukhikh, {T. S.} and Barysheva, {A. C.} and Varvarinskaya, {S. E.} and Ilyin, {I. Y.} and Shakirova, {O. G.} and Morozova, {N. B.}",
note = "This work was funded by the Russian Science Foundation (project 20-15-00222-P).",
year = "2024",
month = nov,
doi = "10.1134/S0022476624110180",
language = "English",
volume = "65",
pages = "2327--2344",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "11",

}

RIS

TY - JOUR

T1 - Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones

AU - Vikulova, E. S.

AU - Sukhikh, T. S.

AU - Barysheva, A. C.

AU - Varvarinskaya, S. E.

AU - Ilyin, I. Y.

AU - Shakirova, O. G.

AU - Morozova, N. B.

N1 - This work was funded by the Russian Science Foundation (project 20-15-00222-P).

PY - 2024/11

Y1 - 2024/11

N2 - The possibility of forming molecular Ag(I) complexes with tris(3,5-dimethylpyrazol-1-yl)methane (HC(3,5-Me2pz)3) and fluorinated β-diketones (hexafluoroacetylacetone (Hhfac) and trifluoroacetylacetone (Htfac)) is tested to expand the library of potential precursors for the chemical vapor deposition of Ag containing materials. It is established that the interaction of HC(3,5-Me2pz)3 with silver β-diketonates leads to the formation of [Ag{HC(3,5-Me2pz)3}2]+ cationic complexes. At the same time, a stable desired product [Ag{HC(3,5-Me2pz)3}hfac] (L = hfac) was isolated and characterized. The structures of [Ag{HC(3,5-Me2pz)3}2](tfac) and as series of solvates [Ag{HC(3,5-Me2pz)3}(hfac)]·½THF and [Ag{HC(3,5-Me2pz)3}2](L)Solvx (L = hfac, Solv = Et2O (x = ¼), C7H8 (x = ½), CHCl3 (x = 1); L = tfac, Solv = THF (x = 1)) are determined by XRD. Structures of the cationic and molecular complexes are compared with those of related compounds.

AB - The possibility of forming molecular Ag(I) complexes with tris(3,5-dimethylpyrazol-1-yl)methane (HC(3,5-Me2pz)3) and fluorinated β-diketones (hexafluoroacetylacetone (Hhfac) and trifluoroacetylacetone (Htfac)) is tested to expand the library of potential precursors for the chemical vapor deposition of Ag containing materials. It is established that the interaction of HC(3,5-Me2pz)3 with silver β-diketonates leads to the formation of [Ag{HC(3,5-Me2pz)3}2]+ cationic complexes. At the same time, a stable desired product [Ag{HC(3,5-Me2pz)3}hfac] (L = hfac) was isolated and characterized. The structures of [Ag{HC(3,5-Me2pz)3}2](tfac) and as series of solvates [Ag{HC(3,5-Me2pz)3}(hfac)]·½THF and [Ag{HC(3,5-Me2pz)3}2](L)Solvx (L = hfac, Solv = Et2O (x = ¼), C7H8 (x = ½), CHCl3 (x = 1); L = tfac, Solv = THF (x = 1)) are determined by XRD. Structures of the cationic and molecular complexes are compared with those of related compounds.

KW - XRD

KW - silver

KW - tris(3,5-dimethylpyrazol-1-yl)methane

KW - β-diketonate

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85211159362&origin=inward&txGid=e038f8821927c5b816a4e5dd36f87c69

UR - https://elibrary.ru/item.asp?id=75143238

UR - https://www.mendeley.com/catalogue/71d7c1ce-a243-3403-9211-23429aa6901a/

U2 - 10.1134/S0022476624110180

DO - 10.1134/S0022476624110180

M3 - Article

VL - 65

SP - 2327

EP - 2344

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

M1 - 18

ER -

ID: 61285171