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Synthesis and structure of a new binuclear Pd(II) chloranilate complex. / Romashev, N. F.; Bakaev, I. V.; Komlyagina, V. I. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 10, 12, 10.2021, p. 1573-1579.

Research output: Contribution to journal › Article › peer-review

Harvard

Romashev, NF, Bakaev, IV, Komlyagina, VI, Fomenko, IS, Laricheva, YA, Petrov, PA & Gushchin, AL 2021, 'Synthesis and structure of a new binuclear Pd(II) chloranilate complex', Journal of Structural Chemistry, vol. 62, no. 10, 12, pp. 1573-1579. https://doi.org/10.1134/S0022476621100127

APA

Romashev, N. F., Bakaev, I. V., Komlyagina, V. I., Fomenko, I. S., Laricheva, Y. A., Petrov, P. A., & Gushchin, A. L. (2021). Synthesis and structure of a new binuclear Pd(II) chloranilate complex. Journal of Structural Chemistry, 62(10), 1573-1579. [12]. https://doi.org/10.1134/S0022476621100127

Vancouver

Romashev NF, Bakaev IV, Komlyagina VI, Fomenko IS, Laricheva YA, Petrov PA et al. Synthesis and structure of a new binuclear Pd(II) chloranilate complex. Journal of Structural Chemistry. 2021 Oct;62(10):1573-1579. 12. doi: 10.1134/S0022476621100127

Author

Romashev, N. F. ; Bakaev, I. V. ; Komlyagina, V. I. et al. / Synthesis and structure of a new binuclear Pd(II) chloranilate complex. In: Journal of Structural Chemistry. 2021 ; Vol. 62, No. 10. pp. 1573-1579.

BibTeX

@article{1997cf7b425b4fe3a8a75820212e699d,
title = "Synthesis and structure of a new binuclear Pd(II) chloranilate complex",
abstract = "A binuclear complex of palladium (Et3NH)2[Pd2(ca)2(μ-Cl)2]·2CH3CN is synthesized by ligand-exchange reaction between [PdCl2(PhCN)2] and (Et3NH)2ca (ca2– = chloranilate) taken in a 1:1 molar ratio. Its crystal structure is determined. Chloranilate ca2– dianion is coordinated to Pd(II) as C-donor bidentate ligand. Using cyclic voltammetry (CV) of the complex in CH3CN, non-reversible oxidation at Ea = 1.58 V and quasi-reversible reduction with Eb = –0.80 V and Ea = –0.54 V (relative to Ag/AgCl) is found. The electron structure of the complex is examined.",
keywords = "chloranilate, complex, crystal structure, cyclic voltammetry, DFT calculations, palladium",
author = "Romashev, {N. F.} and Bakaev, {I. V.} and Komlyagina, {V. I.} and Fomenko, {I. S.} and Laricheva, {Yu A.} and Petrov, {P. A.} and Gushchin, {A. L.}",
note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = oct,
doi = "10.1134/S0022476621100127",
language = "English",
volume = "62",
pages = "1573--1579",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis and structure of a new binuclear Pd(II) chloranilate complex

AU - Romashev, N. F.

AU - Bakaev, I. V.

AU - Komlyagina, V. I.

AU - Fomenko, I. S.

AU - Laricheva, Yu A.

AU - Petrov, P. A.

AU - Gushchin, A. L.

N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/10

Y1 - 2021/10

N2 - A binuclear complex of palladium (Et3NH)2[Pd2(ca)2(μ-Cl)2]·2CH3CN is synthesized by ligand-exchange reaction between [PdCl2(PhCN)2] and (Et3NH)2ca (ca2– = chloranilate) taken in a 1:1 molar ratio. Its crystal structure is determined. Chloranilate ca2– dianion is coordinated to Pd(II) as C-donor bidentate ligand. Using cyclic voltammetry (CV) of the complex in CH3CN, non-reversible oxidation at Ea = 1.58 V and quasi-reversible reduction with Eb = –0.80 V and Ea = –0.54 V (relative to Ag/AgCl) is found. The electron structure of the complex is examined.

AB - A binuclear complex of palladium (Et3NH)2[Pd2(ca)2(μ-Cl)2]·2CH3CN is synthesized by ligand-exchange reaction between [PdCl2(PhCN)2] and (Et3NH)2ca (ca2– = chloranilate) taken in a 1:1 molar ratio. Its crystal structure is determined. Chloranilate ca2– dianion is coordinated to Pd(II) as C-donor bidentate ligand. Using cyclic voltammetry (CV) of the complex in CH3CN, non-reversible oxidation at Ea = 1.58 V and quasi-reversible reduction with Eb = –0.80 V and Ea = –0.54 V (relative to Ag/AgCl) is found. The electron structure of the complex is examined.

KW - chloranilate

KW - complex

KW - crystal structure

KW - cyclic voltammetry

KW - DFT calculations

KW - palladium

UR - http://www.scopus.com/inward/record.url?scp=85119135945&partnerID=8YFLogxK

U2 - 10.1134/S0022476621100127

DO - 10.1134/S0022476621100127

M3 - Article

AN - SCOPUS:85119135945

VL - 62

SP - 1573

EP - 1579

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

M1 - 12

ER -

ID: 34707641