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Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine. / Lavrenova, L. G.; Mishchenko, A. A.; Oleynik, I. V. et al.

In: Russian Journal of General Chemistry, Vol. 91, No. 11, 6, 11.2021, p. 2167-2175.

Research output: Contribution to journal › Article › peer-review

Harvard

Lavrenova, LG, Mishchenko, AA, Oleynik, IV, Korotaev, EV, Lavrov, AN, Grebenkina, MA, Sheludyakova, LA, Klyushova, LS & Oleynik, II 2021, 'Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine', Russian Journal of General Chemistry, vol. 91, no. 11, 6, pp. 2167-2175. https://doi.org/10.1134/S1070363221110062

APA

Lavrenova, L. G., Mishchenko, A. A., Oleynik, I. V., Korotaev, E. V., Lavrov, A. N., Grebenkina, M. A., Sheludyakova, L. A., Klyushova, L. S., & Oleynik, I. I. (2021). Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine. Russian Journal of General Chemistry, 91(11), 2167-2175. [6]. https://doi.org/10.1134/S1070363221110062

Vancouver

Lavrenova LG, Mishchenko AA, Oleynik IV, Korotaev EV, Lavrov AN, Grebenkina MA et al. Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine. Russian Journal of General Chemistry. 2021 Nov;91(11):2167-2175. 6. doi: 10.1134/S1070363221110062

Author

Lavrenova, L. G. ; Mishchenko, A. A. ; Oleynik, I. V. et al. / Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine. In: Russian Journal of General Chemistry. 2021 ; Vol. 91, No. 11. pp. 2167-2175.

BibTeX

@article{6820cdc924ed4535b6b9f5793e2842f2,
title = "Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine",
abstract = "New iron(II) and copper(II) coordination compounds with 2,6-bis[1-(phenylimino)ethyl]pyridine (L1), Fe(L1)2SO4·H2O, Fe(L1)2(ClO4)2, Cu(L1)Cl2, and Cu(L1)2Br2·2H2O, were synthesized. The compounds were identified and investigated using CHN analysis and electronic spectroscopy (diffuse reflectance spectroscopy), IR spectroscopy, XRD, and static magnetic susceptibility. Antiferromagnetic exchange interactions between paramagnetic centers are observed in all iron and copper complexes in the ranges 80–420 and 1.77–300 K, respectively. Evaluation of the cytotoxic activity of copper(II) complexes showed that the Cu(L1)2Br2 complex (IC50 26.7 μmol/L) exhibits the highest activity against the human breast adenocarcinoma cell line (MCF-7).",
keywords = "2,6-bis[1-(phenylimino)ethyl]pyridine, complexes, copper(II), iron(II), magnetic and cytotoxic activity",
author = "Lavrenova, {L. G.} and Mishchenko, {A. A.} and Oleynik, {I. V.} and Korotaev, {E. V.} and Lavrov, {A. N.} and Grebenkina, {M. A.} and Sheludyakova, {L. A.} and Klyushova, {L. S.} and Oleynik, {I. I.}",
note = "Funding Information: This work was supported by the Russian science foundation (grant no. 20-63-46026) and the Ministry of science and higher education of the Russian Federation (projects nos. 121031700313-8, 121031700314-5, and 121011490013-7). Experiments on the analysis of cytotoxicity were carried out using the equipment of the Center for collective use “Proteomic analysis” with the support of the Ministry of education and science of Russia (agreement no. 075-15-2021-691). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = nov,
doi = "10.1134/S1070363221110062",
language = "English",
volume = "91",
pages = "2167--2175",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "11",

}

RIS

TY - JOUR

T1 - Synthesis and Properties of Iron(II) and Copper(II) Coordination Compounds with 2,6-Bis[1-(phenylimino)ethyl]pyridine

AU - Lavrenova, L. G.

AU - Mishchenko, A. A.

AU - Oleynik, I. V.

AU - Korotaev, E. V.

AU - Lavrov, A. N.

AU - Grebenkina, M. A.

AU - Sheludyakova, L. A.

AU - Klyushova, L. S.

AU - Oleynik, I. I.

N1 - Funding Information: This work was supported by the Russian science foundation (grant no. 20-63-46026) and the Ministry of science and higher education of the Russian Federation (projects nos. 121031700313-8, 121031700314-5, and 121011490013-7). Experiments on the analysis of cytotoxicity were carried out using the equipment of the Center for collective use “Proteomic analysis” with the support of the Ministry of education and science of Russia (agreement no. 075-15-2021-691). Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/11

Y1 - 2021/11

N2 - New iron(II) and copper(II) coordination compounds with 2,6-bis[1-(phenylimino)ethyl]pyridine (L1), Fe(L1)2SO4·H2O, Fe(L1)2(ClO4)2, Cu(L1)Cl2, and Cu(L1)2Br2·2H2O, were synthesized. The compounds were identified and investigated using CHN analysis and electronic spectroscopy (diffuse reflectance spectroscopy), IR spectroscopy, XRD, and static magnetic susceptibility. Antiferromagnetic exchange interactions between paramagnetic centers are observed in all iron and copper complexes in the ranges 80–420 and 1.77–300 K, respectively. Evaluation of the cytotoxic activity of copper(II) complexes showed that the Cu(L1)2Br2 complex (IC50 26.7 μmol/L) exhibits the highest activity against the human breast adenocarcinoma cell line (MCF-7).

AB - New iron(II) and copper(II) coordination compounds with 2,6-bis[1-(phenylimino)ethyl]pyridine (L1), Fe(L1)2SO4·H2O, Fe(L1)2(ClO4)2, Cu(L1)Cl2, and Cu(L1)2Br2·2H2O, were synthesized. The compounds were identified and investigated using CHN analysis and electronic spectroscopy (diffuse reflectance spectroscopy), IR spectroscopy, XRD, and static magnetic susceptibility. Antiferromagnetic exchange interactions between paramagnetic centers are observed in all iron and copper complexes in the ranges 80–420 and 1.77–300 K, respectively. Evaluation of the cytotoxic activity of copper(II) complexes showed that the Cu(L1)2Br2 complex (IC50 26.7 μmol/L) exhibits the highest activity against the human breast adenocarcinoma cell line (MCF-7).

KW - 2,6-bis[1-(phenylimino)ethyl]pyridine

KW - complexes

KW - copper(II)

KW - iron(II)

KW - magnetic and cytotoxic activity

UR - http://www.scopus.com/inward/record.url?scp=85121453593&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/9b4d64c4-e5cb-3e91-811d-dd767f760e9f/

U2 - 10.1134/S1070363221110062

DO - 10.1134/S1070363221110062

M3 - Article

AN - SCOPUS:85121453593

VL - 91

SP - 2167

EP - 2175

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 11

M1 - 6

ER -

ID: 35261038