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Synthesis and physico-chemical characterization of Beta zeolite catalysts : Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol. / Zaykovskaya, Anna O.; Kumar, Narendra; Kholkina, Ekaterina A. et al.

In: Microporous and Mesoporous Materials, Vol. 302, 110236, 01.08.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Zaykovskaya, AO, Kumar, N, Kholkina, EA, Li-Zhulanov, NS, Mäki-Arvela, P, Aho, A, Peltonen, J, Peurla, M, Heinmaa, I, Kusema, BT, Streiff, S & Murzin, DY 2020, 'Synthesis and physico-chemical characterization of Beta zeolite catalysts: Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol', Microporous and Mesoporous Materials, vol. 302, 110236. https://doi.org/10.1016/j.micromeso.2020.110236

APA

Zaykovskaya, A. O., Kumar, N., Kholkina, E. A., Li-Zhulanov, N. S., Mäki-Arvela, P., Aho, A., Peltonen, J., Peurla, M., Heinmaa, I., Kusema, B. T., Streiff, S., & Murzin, D. Y. (2020). Synthesis and physico-chemical characterization of Beta zeolite catalysts: Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol. Microporous and Mesoporous Materials, 302, [110236]. https://doi.org/10.1016/j.micromeso.2020.110236

Vancouver

Zaykovskaya AO, Kumar N, Kholkina EA, Li-Zhulanov NS, Mäki-Arvela P, Aho A et al. Synthesis and physico-chemical characterization of Beta zeolite catalysts: Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol. Microporous and Mesoporous Materials. 2020 Aug 1;302:110236. doi: 10.1016/j.micromeso.2020.110236

Author

Zaykovskaya, Anna O. ; Kumar, Narendra ; Kholkina, Ekaterina A. et al. / Synthesis and physico-chemical characterization of Beta zeolite catalysts : Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol. In: Microporous and Mesoporous Materials. 2020 ; Vol. 302.

BibTeX

@article{27d6f2f1b12f492787de4284be2a2cdf,
title = "Synthesis and physico-chemical characterization of Beta zeolite catalysts: Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol",
abstract = "Synthesis of Beta zeolite catalysts was carried out using two different methods. The influence of such parameters as synthesis time and temperature, gel composition and gel ripening on the physico-chemical and catalytic properties of Beta zeolite catalysts was studied. A range of analytical methods was applied in this work including scanning and transmission electron microscopies, energy dispersive X-ray spectroscopy, X-ray powder diffraction, nuclear magnetic resonance spectroscopy – 27A1-MAS-NMR and 29Si-MAS-NMR, nitrogen physisorption, Fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectrometry. The sodium forms of Beta zeolites were transformed to the proton forms H-Beta by ion-exchange using aqueous solutions of NH4NO3 and thereafter evaluated in Prins cyclization of (−)-isopulegol with benzaldehyde. The best catalyst synthesized at 150 °C in the rotation mode for 17 h possessing an optimal combination of morphological and structural properties as well as concentration of acid sites demonstrated high (−)-isopulegol conversion (93%) along with high selectivity to the desired product (79%).",
keywords = "Beta zeolites, Catalyst synthesis, Catalytic materials, Characterization, Prins cyclization, BENZALDEHYDE, ZSM-5, CHEMISTRY, ISOPULEGOL, MODIFIED HALLOYSITE NANOTUBES, ANALGESIC ACTIVITY, HYDROTHERMAL SYNTHESIS",
author = "Zaykovskaya, {Anna O.} and Narendra Kumar and Kholkina, {Ekaterina A.} and Li-Zhulanov, {Nikolai S.} and P{\"a}ivi M{\"a}ki-Arvela and Atte Aho and Janne Peltonen and Markus Peurla and Ivo Heinmaa and Kusema, {Bright T.} and St{\'e}phane Streiff and Murzin, {Dmitry Yu}",
year = "2020",
month = aug,
day = "1",
doi = "10.1016/j.micromeso.2020.110236",
language = "English",
volume = "302",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis and physico-chemical characterization of Beta zeolite catalysts

T2 - Evaluation of catalytic properties in Prins cyclization of (−)-isopulegol

AU - Zaykovskaya, Anna O.

AU - Kumar, Narendra

AU - Kholkina, Ekaterina A.

AU - Li-Zhulanov, Nikolai S.

AU - Mäki-Arvela, Päivi

AU - Aho, Atte

AU - Peltonen, Janne

AU - Peurla, Markus

AU - Heinmaa, Ivo

AU - Kusema, Bright T.

AU - Streiff, Stéphane

AU - Murzin, Dmitry Yu

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Synthesis of Beta zeolite catalysts was carried out using two different methods. The influence of such parameters as synthesis time and temperature, gel composition and gel ripening on the physico-chemical and catalytic properties of Beta zeolite catalysts was studied. A range of analytical methods was applied in this work including scanning and transmission electron microscopies, energy dispersive X-ray spectroscopy, X-ray powder diffraction, nuclear magnetic resonance spectroscopy – 27A1-MAS-NMR and 29Si-MAS-NMR, nitrogen physisorption, Fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectrometry. The sodium forms of Beta zeolites were transformed to the proton forms H-Beta by ion-exchange using aqueous solutions of NH4NO3 and thereafter evaluated in Prins cyclization of (−)-isopulegol with benzaldehyde. The best catalyst synthesized at 150 °C in the rotation mode for 17 h possessing an optimal combination of morphological and structural properties as well as concentration of acid sites demonstrated high (−)-isopulegol conversion (93%) along with high selectivity to the desired product (79%).

AB - Synthesis of Beta zeolite catalysts was carried out using two different methods. The influence of such parameters as synthesis time and temperature, gel composition and gel ripening on the physico-chemical and catalytic properties of Beta zeolite catalysts was studied. A range of analytical methods was applied in this work including scanning and transmission electron microscopies, energy dispersive X-ray spectroscopy, X-ray powder diffraction, nuclear magnetic resonance spectroscopy – 27A1-MAS-NMR and 29Si-MAS-NMR, nitrogen physisorption, Fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectrometry. The sodium forms of Beta zeolites were transformed to the proton forms H-Beta by ion-exchange using aqueous solutions of NH4NO3 and thereafter evaluated in Prins cyclization of (−)-isopulegol with benzaldehyde. The best catalyst synthesized at 150 °C in the rotation mode for 17 h possessing an optimal combination of morphological and structural properties as well as concentration of acid sites demonstrated high (−)-isopulegol conversion (93%) along with high selectivity to the desired product (79%).

KW - Beta zeolites

KW - Catalyst synthesis

KW - Catalytic materials

KW - Characterization

KW - Prins cyclization

KW - BENZALDEHYDE

KW - ZSM-5

KW - CHEMISTRY

KW - ISOPULEGOL

KW - MODIFIED HALLOYSITE NANOTUBES

KW - ANALGESIC ACTIVITY

KW - HYDROTHERMAL SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85083739851&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2020.110236

DO - 10.1016/j.micromeso.2020.110236

M3 - Article

AN - SCOPUS:85083739851

VL - 302

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

SN - 1387-1811

M1 - 110236

ER -

ID: 24163232