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Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy). / Park, S. Ch; Kuratieva, N. V.; Pomelova, T. A. et al.

In: Journal of Structural Chemistry, Vol. 63, No. 6, 06.2022, p. 868-873.

Research output: Contribution to journal › Article › peer-review

Harvard

Park, SC, Kuratieva, NV, Pomelova, TA & Naumov, NG 2022, 'Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy)', Journal of Structural Chemistry, vol. 63, no. 6, pp. 868-873. https://doi.org/10.1134/S0022476622060038

APA

Park, S. C., Kuratieva, N. V., Pomelova, T. A., & Naumov, N. G. (2022). Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy). Journal of Structural Chemistry, 63(6), 868-873. https://doi.org/10.1134/S0022476622060038

Vancouver

Park SC, Kuratieva NV, Pomelova TA, Naumov NG. Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy). Journal of Structural Chemistry. 2022 Jun;63(6):868-873. doi: 10.1134/S0022476622060038

Author

Park, S. Ch ; Kuratieva, N. V. ; Pomelova, T. A. et al. / Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy). In: Journal of Structural Chemistry. 2022 ; Vol. 63, No. 6. pp. 868-873.

BibTeX

@article{b52fbd1b869349019963f7f0fde7a0f5,
title = "Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy)",
abstract = "CsLnZnS3 (Ln = Gd, Dy) crystals are obtained by the interaction of metal sulfides in the cesium iodide melt. It is found that these compounds are isostructural, belong to the KCuZrS3 structure type, and crystallize in the space group Cmcm with the parameters a = 4.010(5) {\AA}, b = 15.32(3) {\AA}, c = 10.542(19) {\AA} for CsGdZnS3 and a = 4.0106(3) {\AA}, b = 15.2493(12) {\AA}, c = 10.5978(8) {\AA} for CsDyZnS3. The structures of these compounds consist of {LnS6} octahedra and {ZnS4} tetrahedra, which by sharing edges, form charged 2∞{LnZnS3}– layers separated by Cs+ ions. Band gaps of these compounds are determined as 3.70 eV and 3.84 eV for CsGdZnS3 and CsDyZnS3 respectively.",
keywords = "chalcogenides, crystal structure, dysprosium, gadolinium, lanthanides, synthesis",
author = "Park, {S. Ch} and Kuratieva, {N. V.} and Pomelova, {T. A.} and Naumov, {N. G.}",
note = "Funding Information: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8). Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",
year = "2022",
month = jun,
doi = "10.1134/S0022476622060038",
language = "English",
volume = "63",
pages = "868--873",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Synthesis and crystal structure of CsLnZnS3 (Ln = Gd, Dy)

AU - Park, S. Ch

AU - Kuratieva, N. V.

AU - Pomelova, T. A.

AU - Naumov, N. G.

N1 - Funding Information: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8). Publisher Copyright: © 2022, Pleiades Publishing, Ltd.

PY - 2022/6

Y1 - 2022/6

N2 - CsLnZnS3 (Ln = Gd, Dy) crystals are obtained by the interaction of metal sulfides in the cesium iodide melt. It is found that these compounds are isostructural, belong to the KCuZrS3 structure type, and crystallize in the space group Cmcm with the parameters a = 4.010(5) Å, b = 15.32(3) Å, c = 10.542(19) Å for CsGdZnS3 and a = 4.0106(3) Å, b = 15.2493(12) Å, c = 10.5978(8) Å for CsDyZnS3. The structures of these compounds consist of {LnS6} octahedra and {ZnS4} tetrahedra, which by sharing edges, form charged 2∞{LnZnS3}– layers separated by Cs+ ions. Band gaps of these compounds are determined as 3.70 eV and 3.84 eV for CsGdZnS3 and CsDyZnS3 respectively.

AB - CsLnZnS3 (Ln = Gd, Dy) crystals are obtained by the interaction of metal sulfides in the cesium iodide melt. It is found that these compounds are isostructural, belong to the KCuZrS3 structure type, and crystallize in the space group Cmcm with the parameters a = 4.010(5) Å, b = 15.32(3) Å, c = 10.542(19) Å for CsGdZnS3 and a = 4.0106(3) Å, b = 15.2493(12) Å, c = 10.5978(8) Å for CsDyZnS3. The structures of these compounds consist of {LnS6} octahedra and {ZnS4} tetrahedra, which by sharing edges, form charged 2∞{LnZnS3}– layers separated by Cs+ ions. Band gaps of these compounds are determined as 3.70 eV and 3.84 eV for CsGdZnS3 and CsDyZnS3 respectively.

KW - chalcogenides

KW - crystal structure

KW - dysprosium

KW - gadolinium

KW - lanthanides

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85133124442&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/314c2e16-dbca-308d-bc86-0aaf4e035fa1/

U2 - 10.1134/S0022476622060038

DO - 10.1134/S0022476622060038

M3 - Article

AN - SCOPUS:85133124442

VL - 63

SP - 868

EP - 873

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 36511122