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Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole. / Pavlov, D. I.; Poklonova, V. V.; Ryadun, A. A. et al.

In: Russian Chemical Bulletin, Vol. 71, No. 5, 05.2022, p. 974-979.

Research output: Contribution to journal › Article › peer-review

Harvard

Pavlov, DI, Poklonova, VV, Ryadun, AA, Samsonenko, DG, Dorovatovskii, PV, Lazarenko, VA, Fedin, VP & Potapov, AS 2022, 'Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole', Russian Chemical Bulletin, vol. 71, no. 5, pp. 974-979. https://doi.org/10.1007/s11172-022-3499-x

APA

Pavlov, D. I., Poklonova, V. V., Ryadun, A. A., Samsonenko, D. G., Dorovatovskii, P. V., Lazarenko, V. A., Fedin, V. P., & Potapov, A. S. (2022). Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole. Russian Chemical Bulletin, 71(5), 974-979. https://doi.org/10.1007/s11172-022-3499-x

Vancouver

Pavlov DI, Poklonova VV, Ryadun AA, Samsonenko DG, Dorovatovskii PV, Lazarenko VA et al. Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole. Russian Chemical Bulletin. 2022 May;71(5):974-979. doi: 10.1007/s11172-022-3499-x

Author

Pavlov, D. I. ; Poklonova, V. V. ; Ryadun, A. A. et al. / Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole. In: Russian Chemical Bulletin. 2022 ; Vol. 71, No. 5. pp. 974-979.

BibTeX

@article{b47c7bf660084ce9b15ca1ff3189472a,
title = "Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole",
abstract = "A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 {\AA}2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.",
keywords = "2,1,3-benzoxadiazole, coordination polymers, di(imidazol-1-yl)-methane, luminescence, metal-organic framework, X-ray diffraction, zinc",
author = "Pavlov, {D. I.} and Poklonova, {V. V.} and Ryadun, {A. A.} and Samsonenko, {D. G.} and Dorovatovskii, {P. V.} and Lazarenko, {V. A.} and Fedin, {V. P.} and Potapov, {A. S.}",
note = "Funding Information: This study was financially supported by the Russian Science Foundation (Project No. 19-73-20087). Physicochemical studies of the synthesized compounds were performed at the Center of Shared Use of the A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, with the financial support from the Ministry of Science and Higher Education of the Russian Federation (Project Nos 121031700321-3 and 121031700313-8). Publisher Copyright: {\textcopyright} 2022, Springer Science+Business Media LLC.",
year = "2022",
month = may,
doi = "10.1007/s11172-022-3499-x",
language = "English",
volume = "71",
pages = "974--979",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "5",

}

RIS

TY - JOUR

T1 - Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole

AU - Pavlov, D. I.

AU - Poklonova, V. V.

AU - Ryadun, A. A.

AU - Samsonenko, D. G.

AU - Dorovatovskii, P. V.

AU - Lazarenko, V. A.

AU - Fedin, V. P.

AU - Potapov, A. S.

N1 - Funding Information: This study was financially supported by the Russian Science Foundation (Project No. 19-73-20087). Physicochemical studies of the synthesized compounds were performed at the Center of Shared Use of the A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, with the financial support from the Ministry of Science and Higher Education of the Russian Federation (Project Nos 121031700321-3 and 121031700313-8). Publisher Copyright: © 2022, Springer Science+Business Media LLC.

PY - 2022/5

Y1 - 2022/5

N2 - A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 Å2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.

AB - A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 Å2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.

KW - 2,1,3-benzoxadiazole

KW - coordination polymers

KW - di(imidazol-1-yl)-methane

KW - luminescence

KW - metal-organic framework

KW - X-ray diffraction

KW - zinc

UR - http://www.scopus.com/inward/record.url?scp=85130331375&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/0706f901-1781-3697-8c6a-7f843630b5b9/

U2 - 10.1007/s11172-022-3499-x

DO - 10.1007/s11172-022-3499-x

M3 - Article

AN - SCOPUS:85130331375

VL - 71

SP - 974

EP - 979

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 5

ER -

ID: 36169718